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A Text-book of Paper-making

Chapter 112: Ferric Oxide Causticising Process.
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About This Book

This work provides a comprehensive examination of the principles and processes involved in paper-making, emphasizing the scientific understanding necessary for effective practice. It covers the chemical properties of cellulose, the physical structure of fibers, and the analysis of plant substances, detailing methods for isolating cellulose from various raw materials. The text discusses specialized treatments for different fibers, bleaching, and the mechanical processes involved in paper production. Additionally, it addresses the testing and quality control of paper, along with considerations for site selection and water purification in paper mills. The authors aim to enhance the reader's grasp of the scientific foundations essential for modern paper-making.

Ferric Oxide Causticising Process.

The principle of this process is the expulsion of the carbonic acid from sodium carbonate by ferric oxide at high temperatures; this oxide playing the part of a weak acid, entering into a loose combination with the soda, which is overcome by water in the subsequent lixiviation process, the ferric oxide being regenerated and a solution of caustic soda obtained.

The ferric oxide is therefore continuously available. The main features of the process, disregarding the question of commercial economy, are (1) that it leaves no by-products to be disposed of, (2) that it enables the manufacturer to produce directly, without evaporation, a highly concentrated caustic lye.

This process has been worked out under the auspices of Messrs. Brunner, Mond, & Co., and there is every reason to expect an extensive application of so simple a method.