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Conversations on Chemistry, V. 1-2 / In Which the Elements of that Science Are Familiarly Explained and Illustrated by Experiments

Chapter 6: PREFACE.
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A conversational primer presents chemical principles through dialogues between an instructor and pupils, using repeated experiments to make abstract ideas tangible. It treats heat (free and combined), electricity, gases and their constituents, and individual elements and groups including oxygen, hydrogen, nitrogen, sulfur, phosphorus, carbon, metals, acids, alkalies, earths, and salts, then considers their combinations and applications. The arrangement moves from simpler bodies to more complex compounds, interweaving laboratory practice, recent discoveries of the era such as gas illumination, and pedagogical remarks that favor progressive study over isolated consultation.

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Title: Conversations on Chemistry, V. 1-2

Author: Mrs. Marcet

Release date: October 13, 2008 [eBook #26908]
Most recently updated: November 11, 2023

Language: English

Credits: Produced by Louise Hope

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The original book was published in two volumes. The format is reproduced for this e-text, except that the author’s preface (originally in Volume I) and the combined index (Volume II) are in this introductory file.

See the end of this file for notes on scientific terminology, spelling, Plates and chapter numbering.

CONVERSATIONS

ON

CHEMISTRY;

IN WHICH

THE ELEMENTS OF THAT SCIENCE

ARE

FAMILIARLY EXPLAINED

AND

ILLUSTRATED BY EXPERIMENTS.



IN TWO VOLUMES.



The Fifth Edition, revised, corrected, and considerably enlarged.
 

LONDON:

PRINTED FOR LONGMAN, HURST, REES, ORME, AND BROWN,
PATERNOSTER-ROW.

1817.

Printed by A. Strahan,
Printers-Street, London.

ADVERTISEMENT.



The Author, in this fifth edition, has endeavoured to give an account of the principal discoveries which have been made within the last four years in Chemical Science, and of the various important applications, such as the gas-lights, and the miner’s-lamp, to which they have given rise. But in regard to doctrines or principles, the work has undergone no material alteration.

London, July, 1817.

PREFACE.



In venturing to offer to the public, and more particularly to the female sex, an Introduction to Chemistry, the author, herself a woman, conceives that some explanation may be required; and she feels it the more necessary to apologise for the present undertaking, as her knowledge of the subject is but recent, and as she can have no real claims to the title of chemist.

On attending for the first time experimental lectures, the author found it almost impossible to derive any clear or satisfactory information from the rapid demonstrations which are usually, and perhaps necessarily, crowded into popular courses of this kind. But frequent opportunities having afterwards occurred of conversing with a friend on the subject of chemistry, and of repeating a variety of experiments, she became better acquainted with the principles of that science, and began to feel highly interested in its pursuit. It was then that she perceived, in attending the excellent lectures delivered at the Royal Institution, by the present Professor of Chemistry, the great advantage which her previous knowledge of the subject, slight as it was, gave her over others who had not enjoyed the same means of private instruction. Every fact or experiment attracted her attention, and served to explain some theory to which she was not a total stranger; and she had the gratification to find that the numerous and elegant illustrations, for which that school is so much distinguished, seldom failed to produce on her mind the effect for which they were intended.

Hence it was natural to infer, that familiar conversation was, in studies of this kind, a most useful auxiliary source of information; and more especially to the female sex, whose education is seldom calculated to prepare their minds for abstract ideas, or scientific language.

As, however, there are but few women who have access to this mode of instruction; and as the author was not acquainted with any book that could prove a substitute for it, she thought that it might be useful for beginners, as well as satisfactory to herself, to trace the steps by which she had acquired her little stock of chemical knowledge, and to record, in the form of dialogue, those ideas which she had first derived from conversation.

But to do this with sufficient method, and to fix upon a mode of arrangement, was an object of some difficulty. After much hesitation, and a degree of embarrassment, which, probably, the most competent chemical writers have often felt in common with the most superficial, a mode of division was adopted, which, though the most natural, does not always admit of being strictly pursued—it is that of treating first of the simplest bodies, and then gradually rising to the most intricate compounds.

It is not the author’s intention to enter into a minute vindication of this plan. But whatever may be its advantages or inconveniences, the method adopted in this work is such, that a young pupil, who should occasionally recur to it, with a view to procure information on particular subjects, might often find it obscure or unintelligible; for its various parts are so connected with each other as to form an uninterrupted chain of facts and reasonings, which will appear sufficiently clear and consistent to those only who may have patience to go through the whole work, or have previously devoted some attention to the subject.

It will, no doubt, be observed, that in the course of these Conversations, remarks are often introduced, which appear much too acute for the young pupils, by whom they are supposed to be made. Of this fault the author is fully aware. But, in order to avoid it, it would have been necessary either to omit a variety of useful illustrations, or to submit to such minute explanations and frequent repetitions, as would have rendered the work tedious, and therefore less suited to its intended purpose.

In writing these pages, the author was more than once checked in her progress by the apprehension that such an attempt might be considered by some, either as unsuited to the ordinary pursuits of her sex, or ill-justified by her own recent and imperfect knowledge of the subject. But, on the one hand, she felt encouraged by the establishment of those public institutions, open to both sexes, for the dissemination of philosophical knowledge, which clearly prove that the general opinion no longer excludes women from an acquaintance with the elements of science; and, on the other, she flattered herself that whilst the impressions made upon her mind, by the wonders of Nature, studied in this new point of view, were still fresh and strong, she might perhaps succeed the better in communicating to others the sentiments she herself experienced.

The reader will soon perceive, in perusing this work, that he is often supposed to have previously acquired some slight knowledge of natural philosophy, a circumstance, indeed, which appears very desirable. The author’s original intention was to commence this work by a small tract, explaining, on a plan analogous to this, the most essential rudiments of that science. This idea she has since abandoned; but the manuscript was ready, and might, perhaps, have been printed at some future period, had not an elementary work of a similar description, under the tide of “Scientific Dialogues,” been pointed out to her, which, on a rapid perusal, she thought very ingenious, and well calculated to answer its intended object.

CONTENTS

Page numbers have been retained to give an idea of the relative length of each Conversation.

CONVERSATION I.
ON THE GENERAL PRINCIPLES OF CHEMISTRY. Page 1
CONVERSATION II.
ON LIGHT AND HEAT. 26
CONVERSATION III.
CONTINUATION OF THE SUBJECT. 70
CONVERSATION IV.
ON COMBINED CALORIC, COMPREHENDING SPECIFIC HEAT AND LATENT HEAT. 122
CONVERSATION V.
ON THE CHEMICAL AGENCIES OF ELECTRICITY. 160
CONVERSATION VI.
ON OXYGEN AND NITROGEN. 181
CONVERSATION VII.
ON HYDROGEN. 214
CONVERSATION VIII.
ON SULPHUR AND PHOSPHORUS. 256
CONVERSATION IX.
ON CARBON. 282
CONVERSATION X.
ON METALS. 314
CONVERSATION XIII.
ON THE ATTRACTION OF COMPOSITION. 1
CONVERSATION XIV.
ON ALKALIES. 19
CONVERSATION XV.
ON EARTHS. 44
CONVERSATION XVI.
ON ACIDS. 69
CONVERSATION XVII.

OF THE SULPHURIC AND PHOSPHORIC ACIDS: OR, THE COMBINATIONS OF OXYGEN WITH SULPHUR AND WITH PHOSPHORUS; AND OF THE SULPHATS AND PHOSPHATS.

80
CONVERSATION XVIII.

OF THE NITRIC AND CARBONIC ACIDS: OR THE COMBINATION OF OXYGEN WITH NITROGEN AND WITH CARBON; AND OF THE NITRATS AND CARBONATS.

100
CONVERSATION XIX.
ON THE BORACIC, FLUORIC, MURIATIC, AND OXYGENATED MURIATIC ACIDS; AND ON MURIATS. 131
CONVERSATION XX.
ON THE NATURE AND COMPOSITION OF VEGETABLES. 162
CONVERSATION XXI.
ON THE DECOMPOSITION OF VEGETABLES. 202
CONVERSATION XXII.
HISTORY OF VEGETATION. 243
CONVERSATION XXIII.
ON THE COMPOSITION OF ANIMALS. 276
CONVERSATION XXIV.
ON THE ANIMAL ECONOMY. 297
CONVERSATION XXV.
ON ANIMALISATION, NUTRITION, AND RESPIRATION. 314
CONVERSATION XXVI.
ON ANIMAL HEAT; AND OF VARIOUS ANIMAL PRODUCTS. 336
ERRATA.
Vol. I. page 56. last line but one, for “caloric,” read “calorific.”
179. Note, for “Plate XII.” r. “Plate XIII.”


CONVERSATIONS

ON

CHEMISTRY;

IN WHICH

THE ELEMENTS OF THAT SCIENCE

ARE

FAMILIARLY EXPLAINED

AND

ILLUSTRATED BY EXPERIMENTS.



IN TWO VOLUMES.



The Fifth Edition, revised, corrected, and considerably enlarged.
 

VOL. I.

ON SIMPLE BODIES.

LONDON:

PRINTED FOR LONGMAN, HURST, REES, ORME, AND BROWN,
PATERNOSTER-ROW.

1817.

 
 

CONTENTS

OF

THE FIRST VOLUME.



ON SIMPLE BODIES.



CONVERSATION I.
ON THE GENERAL PRINCIPLES OF CHEMISTRY. Page 1

Connexion between Chemistry and Natural Philosophy.—Improved State of modern Chemistry.—Its use in the Arts.—The general Objects of Chemistry.—Definition of Elementary Bodies.—Definition of Decomposition.—Integrant and Constituent Particles.—Distinction between Simple and Compound Bodies.—Classification of Simple Bodies.—Of Chemical Affinity, or Attraction of Composition.—Examples of Composition and Decomposition.

CONVERSATION II.
ON LIGHT AND HEAT. 26

Light and Heat capable of being separated.—Dr. Herschel’s Experiments.—Phosphorescence.—Of Caloric.—Its two Modifications.—Free Caloric.—Of the three different States of Bodies, solid, fluid, and aeriform.—Dilatation of solid Bodies.—Pyrometer.—Dilatation of Fluids.—Thermometer.—Dilatation of Elastic Fluids.—Air Thermometer.—Equal Diffusion of Caloric.—Cold a Negative Quality.—Professor Prevost’s Theory of the Radiation of Heat.—Professor Pictet’s Experiments on the Reflexion of Heat.—Mr. Leslie’s Experiments on the Radiation of Heat.

CONVERSATION III.
CONTINUATION OF THE SUBJECT. 70

Of the different Power of Bodies to conduct Heat.—Attempt to account for this Power.—Count Rumford’s Theory of the non-conducting Power of Fluids.—Phenomena of Boiling.—Of Solution in general.—Solvent Power of Water.—Difference between Solution and Mixture.—Solvent Power of Caloric.—Of Clouds, Rain, Dr. Wells’ theory of Dew, Evaporation, &c.—Influence of Atmospherical Pressure on Evaporation.—Ignition.

CONVERSATION IV.
ON COMBINED CALORIC, COMPREHENDING SPECIFIC HEAT AND LATENT HEAT. 122

Of Specific Heat.—Of the different Capacities of Bodies for Heat.—Specific Heat not perceptible by the Senses.—How to be ascertained.—Of Latent Heat.—Distinction between Latent and Specific Heat.—Phenomena attending the Melting of Ice and the Formation of Vapour.—Phenomena attending the Formation of Ice, and the Condensation of Elastic Fluids.—Instances of Condensation, and consequent Disengagement of Heat, produced by Mixtures, by the Slaking of Lime.—General Remarks on Latent Heat.—Explanation of the Phenomena of Ether boiling, and Water freezing, at the same Temperature.—Of the Production of Cold by Evaporation.—Calorimeter.—Meteorological Remarks.

CONVERSATION V.
ON THE CHEMICAL AGENCIES OF ELECTRICITY. 160

Of Positive and Negative Electricity.—Galvani’s Discoveries.—Voltaic Battery.—Electrical Machine.—Theory of Voltaic Excitement.

CONVERSATION VI.
ON OXYGEN AND NITROGEN. 181

The Atmosphere composed of Oxygen and Nitrogen in the State of Gas.—Definition of Gas.—Distinction between Gas and Vapour.—Oxygen essential to Combustion and Respiration.—Decomposition of the Atmosphere by Combustion.—Nitrogen Gas obtained by this Process.—Of Oxygenation in general.—Of the Oxydation of Metals.—Oxygen Gas obtained from Oxyd of Manganese.—Description of a Water-Bath for collecting and preserving Gases.—Combustion of Iron Wire in Oxygen Gas.—Fixed and volatile Products of Combustion.—Patent Lamps.—Decomposition of the Atmosphere by Respiration.—Recomposition of the Atmosphere.

CONVERSATION VII.
ON HYDROGEN. 214

Of Hydrogen.—Of the Formation of Water by the Combustion of Hydrogen.—Of the Decomposition of Water. —Detonation of Hydrogen Gas.—Description of Lavoisier’s Apparatus for the formation of Water.—Hydrogen Gas essential to the Production of Flame.—Musical Tones produced by the Combustion of Hydrogen Gas within a Glass Tube.—Combustion of Candles explained.—Gas lights.—Detonation of Hydrogen Gas in Soap Bubbles.—Air Balloons.—Meteorological Phenomena ascribed to Hydrogen Gas.—Miner’s Lamp.

The final two pages of the Table of Contents for Volume I were missing from the available text; everything after “Decomposition of Water” was supplied from earlier and later editions, compared against the body text. The section marked “Diamond” (Conv. IX) was called “Diamond is Carbon(e) in a state of perfect purity” in the 4th edn., “Diamond” alone in later editions.

CONVERSATION VIII.
ON SULPHUR AND PHOSPHORUS. 256

Natural History of Sulphur.—Sublimation.—Alembic.—Combustion of Sulphur in Atmospheric Air.—Of Acidification in general.—Nomenclature of the Acids.—Combustion of Sulphur in Oxygen Gas.—Sulphuric Acid.—Sulphurous Acid.—Decomposition of Sulphur.—Sulphurated Hydrogen Gas.—Harrogate, or Hydro-sulphurated Waters.—Phosphorus.—History of its Discovery.—Its Combustion in Oxygen Gas.—Phosphoric Acid.—Phosphorus Acid.—Eudiometer.—Combination of Phosphorus with Sulphur.—Phosphorated Hydrogen Gas.—Nomenclature of Binary Compounds.—Phosphoret of Lime burning under Water.

CONVERSATION IX.
ON CARBON. 282

Method of obtaining pure Charcoal.—Method of making common Charcoal.—Pure Carbon not to be obtained by Art.—Diamond.—Properties of Carbon.—Combustion of Carbon.—Production of Carbonic Acid Gas.—Carbon susceptible of only one Degree of Acidification.—Gaseous Oxyd of Carbon.—Of Seltzer Water and other Mineral Waters.—Effervescence.—Decomposition of Water by Carbon.—Of Fixed and Essential Oils.—Of the Combustion of Lamps and Candles.—Vegetable Acids.—Of the Power of Carbon to revive Metals.

CONVERSATION X.
ON METALS. 314

Natural History of Metals.—Of Roasting, Smelting, &c.—Oxydation of metals by the Atmosphere.—Change of Colours produced by different degrees of Oxydation.—Combustion of Metals.—Perfect Metals burnt by Electricity only.—Some Metals revived by Carbon and other Combustibles.—Perfect Metals revived by Heat alone.—Of the Oxydation of certain Metals by the Decomposition of Water. Power of Acids to promote this Effect.—Oxydation of Metals by Acids.—Metallic Neutral Salts.—Previous oxydation of the Metal requisite.—Crystallisation.—Solution distinguished from Dissolution.—Five metals susceptible of acidification.—Meteoric Stones.—Alloys, Soldering, Plating, &c.—Of Arsenic, and of the caustic Effects of Oxygen.—Of Verdigris, Sympathetic Ink, &c.—Of the new Metals discovered by Sir H. Davy.

CONVERSATIONS

ON

CHEMISTRY.