Human Foods and Their Nutritive Value

13. Fat.—Fat is found mainly in the seeds of plants, but to some extent in the leaves and stems. It differs from starch in containing more carbon and less oxygen. In starch there is about 44 per cent of carbon, while in fat there is 75 per cent. Hence it is that when fat is burned or undergoes combustion, it yields a larger amount of the products of combustion—carbon dioxid and water—than does starch. A gram of fat produces 2¼ times as much heat as a gram of starch. Fat is the most concentrated non-nitrogenous nutrient. As found in food materials, it is a mechanical mixture of various fats, among which are stearin, palmitin, and olein. Stearin and palmitin are hard fats, crystalline in structure, and with a high melting point, while olein is a liquid. In addition to these three, there are also small amounts of other fats, as butyrin in butter, which give character or individuality to materials. There are a number of vegetable fats or oils which are used for food purposes and, when properly prepared and refined, have a high nutritive value. Occasionally one fat of cheaper origin but not necessarily of lower nutritive value is substituted for another. The fats have definite physical and chemical properties which enable them to be readily distinguished, as iodine number, specific gravity, index of refraction, and heat of combustion. By iodine number is meant the percentage of iodine that will unite chemically with the fat. Wheat oil has an iodine number of about 100, meaning that one pound of wheat oil will unite chemically with one pound of iodine. Fats have a lower specific gravity than water, usually ranging from .89 to .94, the specific gravity of a fat being fairly constant. All fats can be separated into glycerol and a fatty acid, glycerol or glycerine being common constituents, while each fat yields its own characteristic acid, as stearin, stearic acid; palmitin, palmitic acid; and olein, oleic acid. The fats are soluble in ether, chloroform, and benzine. In the chemical analysis of foods, they are separated with ether, and along with the fat, variable amounts of other substances are extracted, these extractive products usually being called "ether extract" or "crude fat."^[5] The ether extract of plant tissue contains in addition to fat appreciable amounts of cellulose, gums, coloring, and other materials. From cereal products the ether extract is largely fat, but in some instances lecithin and other nitrogenous fatty substances are present, while in animal food products, as milk and meat, the ether extract is nearly pure fat.

14. Organic Acids.—Many vegetable foods contain small amounts of organic acids, as malic acid found in apples, citric in lemons, and tartaric in grapes. These give characteristic taste to foods, but have no direct nutritive value. They do not yield heat and energy as do starch, fat, and protein; they are, however, useful for imparting flavor and palatability, and it is believed they promote to some extent the digestion of foods with which they are combined by encouraging the secretion of the digestive fluids. Many fruits and vegetables owe their dietetic value to the organic acids which they contain. In plants they are usually in chemical combination with the minerals, forming compounds as salts, or with the organic compounds, producing materials as acid proteins. In the plant economy they take an essential part in promoting growth and aiding the plant to secure by osmotic action its mineral food from the soil. Organic acids are found to some extent in animal foods, as the various lactic acids of meat and milk. They are also formed in food materials as the result of ferment action. When seeds germinate, small amounts of carbohydrates are converted into organic acids. In general the organic acids are not to be considered as nutrients, but as food adjuncts, increasing palatability and promoting digestion.

15. Essential Oils.—Essential or volatile oils differ from fats, or fixed oils, in chemical composition and physical properties.^[6] The essential oils are readily volatilized, leaving no permanent residue, while the fixed fats are practically non-volatile. Various essential oils are present in small amounts in nearly all vegetable food materials, and the characteristic flavor of many fruits is due to them. It is these compounds which are used for flavoring purposes, as discussed in Chapter IV. The amount in a food material is very small, usually only a few hundredths of a per cent. The essential oils have no direct food value, but indirectly, like the organic acids, they assist in promoting favorable digestive action, and are also valuable because they impart a pleasant taste. Through poor methods of cooking and preparation, the essential oils are readily lost from some foods.

16. Mixed Compounds.—Food materials frequently contain compounds which do not naturally fall into the five groups mentioned,—carbohydrates, pectose substances, fats, organic acids, and essential oils. The amount of such compounds is small, and they are classed as miscellaneous or mixed non-nitrogenous compounds. Some of them may impart a negative value to the food, and there are others which have all the characteristics, as far as general composition is concerned, of the non-nitrogenous compounds, but contain nitrogen, although as a secondary rather than an essential constituent.

17. Nutritive Value of Non-nitrogenous Compounds.—The non-nitrogenous compounds, taken as a class, are incapable alone of sustaining life, because they do not contain any nitrogen, and this is necessary for producing proteid material in the animal body. They are valuable for the production of heat and energy, and when associated with the nitrogenous compounds, are capable of forming non-nitrogenous reserve tissue. It is equally impossible to sustain life for any prolonged period with the nitrogenous compounds alone. It is when these two classes are properly blended and naturally united in food materials that their main value is secured. For nutrition purposes they are mutually related and dependent. Some food materials contain the nitrogenous and non-nitrogenous compounds blended in such proportion as to enable one food alone to practically sustain life, while in other cases it is necessary, in order to secure the best results in the feeding of animals and men, to combine different foods varying in their content of these two classes of compounds.^[7]

NITROGENOUS COMPOUNDS

18. General Composition.—The nitrogenous compounds are more complex in composition than the non-nitrogenous. They are composed of a larger number of elements, united in different ways so as to form a much more complex molecular structure. Foods contain numerous nitrogenous organic compounds, which, for purposes of study, are divided into four divisions,—proteids, albuminoids, amids, and alkaloids. In addition to these, there are other nitrogenous compounds which do not naturally fall into any one of the four divisions.

Fig. 4.—Apparatus used for Determining Total Nitrogen and Crude Protein in Foods.

The material is digested in the flask (3) with sulphuric acid and the organic nitrogen converted into ammonium sulphate, which is later liberated and distilled at 1, and the ammonia neutralized with standard acid (2).]

Also in some foods there are small amounts of nitrogen in mineral forms, as nitrates and nitrites.

19. Protein.—The term "protein" is applied to a large class of nitrogenous compounds resembling each other in general composition, but differing widely in structural composition. As a class, the proteins contain about 16 per cent of nitrogen, 52 per cent of carbon, from 6 to 7 per cent of hydrogen, 22 per cent of oxygen, and less than 2 per cent of sulphur. These elements are combined in a great variety of ways, forming various groups or radicals. In studying the protein molecule a large number of derivative products have been observed, as amid radicals, various hydrocarbons, fatty acids, and carbohydrate-like bodies.^[8] It would appear that in the chemical composition of the proteins there are all the constituents, or simpler products, of the non-nitrogenous compounds, and these are in chemical combination with amid radicals and nitrogen in various forms. The nitrogen of many proteids appears to be present in more than one form or radical. The proteids take an important part in life processes. They are found more extensively in animal than in plant bodies. The protoplasm of both the plant and animal cell is composed mainly of protein.

Proteids are divided into various subdivisions, as albumins, globulins, albuminates, proteoses and peptones, and insoluble proteids. In plant and animal foods a large amount of the protein is present as insoluble proteids; that is, they are not dissolved by solvents, as water and dilute salt solution. The albumins are soluble in water and coagulated by heat at a temperature of 157° to 161° F. Whenever a food material is soaked in water, the albumin is removed and can then be coagulated by the action of heat, or of chemicals, as tannic acid, lead acetate, and salts of mercury. The globulins are proteids extracted from food materials by dilute salt solution after the removal of the albumins. Globulins also are coagulated by heat and precipitated by chemicals. The amount of globulins in vegetable foods is small. In animal foods myosin in meat and vitellin, found in the yolk of the egg, and some of the proteids of the blood, are examples of globulins. Albuminates are casein-like proteids found in both animal and vegetable foods. They are supposed to be proteins that are in feeble chemical combination with acid and alkaline compounds, and they are sometimes called acid and alkali proteids. Some are precipitated from their solutions by acids and others by alkalies. Peas and beans contain quite large amounts of a casein-like proteid called legumin. Proteoses and peptones are proteins soluble in water, but not coagulated by heat. They are produced from other proteids by ferment action during the digestion of food and the germination of seeds, and are often due to the changes resulting from the action of the natural ferments or enzymes inherent in the food materials. As previously stated, the insoluble proteids are present in far the largest amount of any of the nitrogenous materials of foods. Lean meat and the gluten of wheat and other grains are examples of the insoluble proteids. The various insoluble proteids from different food materials each has its own composition and distinctive chemical and physical properties, and from each a different class and percentage amount of derivative products are obtained.^[1] While in general it is held that the various proteins have practically the same nutritive value, it is possible that because differences in structural composition and the products formed during digestion there may exist notable differences in nutritive value. During digestion the insoluble proteids undergo an extended series of chemical changes. They are partially oxidized, and the nitrogenous portion of the molecule is eliminated mainly in the form of amids, as urea. The insoluble proteins constitute the main source of the nitrogenous food supply of both humans and animals.

20. Crude Protein.—In the analysis of foods, the term "crude protein" is used to designate the total nitrogenous compounds considered collectively; it is composed largely of protein, but also includes the amids, alkaloids, and albuminoids. "Crude protein" and "total nitrogenous compounds" are practically synonymous terms. The various proteins all contain about 16 per cent of nitrogen; that is, one part of nitrogen is equivalent to 6.25 parts of protein. In analyzing a food material, the total organic nitrogen is determined and the amount multiplied by 6.25 to obtain the crude protein. In some food materials, as cereals, the crude protein is largely pure protein, while in others, as potatoes, it is less than half pure protein, the larger portion being amids and other compounds. In comparing the crude protein content of one food with that of another, the nature of both proteids should be considered and also the amounts of non-proteid constituents. The factor 6.25 for calculating the protein equivalent of foods is not strictly applicable to all foods. For example, the proteids of wheat—gliadin and glutenin—contain over 18 per cent of nitrogen, making the nitrogen factor about 5.68 instead of 6.25. If wheat contains 2 per cent of nitrogen, it is equivalent to 12.5 per cent of crude protein, using the factor 6.25; or to 11.4, using the factor 5.7. The nitrogen content of foods is absolute; the protein content is only relative.^[9]

21. Food Value of Protein.—Because of its complexity in composition, protein is capable of being used by the body in a greater variety of ways than starch, sugar, or fat. In addition to producing heat and energy, protein serves the unique function of furnishing material for the construction of new muscular tissue and the repair of that which is worn out. It is distinctly a tissue-building nutrient. It also enters into the composition of all the vital fluids of the body, as the blood, chyme, chyle, and the various digestive fluids. Hence it is that protein is required as a nutrient by the animal body, and it cannot be produced from non-nitrogenous compounds. In vegetable bodies, the protein can be produced synthetically from amids, which in turn are formed from ammonium compounds. While protein is necessary in the ration, an excessive amount should be avoided. When there is more than is needed for functional purposes, it is used for heat and energy, and as foods rich in protein are usually the most expensive, an excess adds unnecessarily to the cost of the ration. Excess of protein in the ration may also result in a diseased condition, due to imperfect elimination of the protein residual products from the body.^[10]

22. Albuminoids differ from proteids in general composition and, to some extent, in nutritive value. They are found in animal bodies mainly in the connective tissue and in the skin, hair, and nails. Some of the albuminoids, as nuclein, are equal in food value to protein, while others have a lower food value. In general, albuminoids are capable of conserving the protein of the body, and hence are called "protein sparers," but they cannot in every way enter into the composition of the body, as do the true proteins.

23. Amids and Amines.—These are nitrogenous compounds of simpler structure than the proteins and albuminoids. They are sometimes called compound ammonia in that they are derived from ammonia by the replacement of one of the hydrogen atoms with an organic radical. In plants, amids are intermediate compounds in the production of the proteids, and in some vegetables a large portion of the nitrogen is amids. In animal bodies amids are formed during oxidation, digestion, and disintegration of proteids. It is not definitely known whether or not a protein in the animal body when broken down into amid form can again be reconstructed into protein. The amids have a lower food value than the proteids and albuminoids. It is generally held that, to a certain extent, they are capable, when combined with proteids, of preventing rapid conversion of the body proteid into soluble form. When they are used in large amounts in a ration, they tend to hasten oxidation rather than conservation of the proteids.

24. Alkaloids.—In some plant bodies there are small amounts of nitrogenous compounds called alkaloids. They are not found to any appreciable extent in food plants. The alkaloids, like ammonia, are basic in character and unite with acids to form salts. Many medicinal plants owe their value to the alkaloids which they contain. In animal bodies alkaloids are formed when the tissue undergoes fermentation changes, and also during disease, the products being known as ptomaines. Alkaloids have no food value, but act physiologically as irritants on the nerve centers, making them useful from a medicinal rather than from a nutritive point of view. To medical and pharmaceutical students the alkaloids form a very important group of compounds.

Fig. 5.—Graphic Composition of Flour.

1, flour; 2, starch; 3, gluten; 4, water; 5, fat; 6, ash.

25. General Relationship of the Nitrogenous Compounds.—Among the various subdivisions of the nitrogenous compounds there exists a relationship similar to that among the non-nitrogenous compounds. From proteids, amids and alkaloids may be formed, just as invert sugars and their products are formed from sucrose. Although glucose products are derived from sucrose, it is not possible to reverse the process and obtain sucrose or cane sugar from starch. So it is with proteins, while the amid may be obtained from the proteid in animal nutrition, as far as known the process cannot be reversed and proteids be obtained from amids. In the construction of the protein molecule of plants, nitrogen is absorbed from the soil in soluble forms, as compounds of nitrates and nitrites and ammonium salts. These are converted, first, into amids and then into proteids. In the animal body just the reverse of this process takes place,—the protein of the food undergoes a series of changes, and is finally eliminated from the body as an amid, which in turn undergoes oxidation and nitrification, and is converted into nitrites, nitrates, and ammonium salts. These forms of nitrogen are then ready to begin again in plant and animal bodies the same cycle of changes. Thus it is that nitrogen may enter a number of times into the composition of plant and animal tissues. Nature is very economical in her use of this element.^[5]

CHAPTER II

27. Chemical Changes during Cooking.—Each of the chemical compounds of which foods are composed is influenced to a greater or less extent by heat and modified in composition. The chemistry of cooking is mainly a study of the chemical changes that take place when compounds, as cellulose, starch, sugar, pectin, fat, and the various proteids, are subjected to the joint action of heat, moisture, air, and ferments. The changes which affect the cellulose are physical rather than chemical. A slight hydration of the cellular tissue, however, does take place. In human foods cellulose is not found to any appreciable extent. Many vegetables, as potatoes, which are apparently composed of cellular substances, contain but little true cellulose. Starch, as previously stated, undergoes hydration in the presence of water, and, at a temperature of 120° C., is converted into dextrine. At a higher temperature disintegration of the starch molecule takes place, with the formation of carbon monoxid, carbon dioxid, and water, and the production of a residue richer in carbon than is starch. On account of the moisture, the temperature in many cooking operations is not sufficiently high for changes other than hydration and preliminary dextrinizing. In Chapter XI is given a more extended account of the changes affecting starch which occur in bread making.

During the cooking process sugars undergo inversion to a slight extent. That is, sucrose is converted into levulose and dextrose sugars. At a higher temperature, sugar is broken up into its constituents—water and carbon dioxide. The organic acids which many fruits and vegetables contain hasten the process of inversion. When sugar is subjected to dry heat, it becomes a brown, caramel-like material sometimes called barley sugar. During cooking, sugars are not altered in solubility or digestibility; starches, however, are changed to a more soluble form, and pectin—a jelly-like substance—is converted from a less to a more soluble condition, as stated in Chapter I. Changes incident to the cooking of fruits and vegetables rich in pectin, as in the making of jellies, are similar to those which take place in the last stages of ripening.

The fats are acted upon to a considerable extent by heat. Some of the vegetable oils undergo slight oxidation, resulting in decreased solubility in ether, but since there is no volatilization of the fatty matter, it is a change that does not materially affect the total fuel value of the food.^[11]

There is a general tendency for the proteids to become less soluble by the action of heat, particularly the albumins and globulins. The protein molecule dissociates at a high temperature, with formation of volatile products, and therefore foods rich in protein should not be subjected to extreme heat, as losses of food value may result. During cooking, proteids undergo hydration, which is necessary and preliminary to digestion, and the heating need be carried only to this point, and not to the splitting up of the molecule. Prolonged high temperature in the cooking of proteids and starches is unnecessary in order to induce the desired chemical changes. When these nutrients are hydrated, they are in a condition to undergo digestion, without the body being compelled to expend unnecessary energy in bringing about this preliminary change. Hence it is that, while proper cooking does not materially affect the total digestibility of proteids or starches, it influences ease of digestion, as well as conserves available energy, thereby making more economical use of these nutrients.

28. Physical Changes.—The mechanical structure of foods is influenced by cooking to a greater extent than is the chemical composition. One of the chief objects of cooking is to bring the food into better mechanical condition for digestion.^[12] Heat and water cause partial disintegration of both animal and vegetable tissues. The cell-cementing materials are weakened, and a softening of the tissues results. Often the action extends still further in vegetable foods, resulting in disintegration of the individual starch granules. When foods are subjected to dry heat, the moisture they contain is converted into steam, which causes bursting of the tissues. A good example of this is the popping of corn. Heat may result, too, in mechanical removal of some of the nutrients, as the fats, which are liquefied at temperatures ranging from 100° to 200° F. Many foods which in the raw state contain quite large amounts of fat, lose a portion mechanically during cooking, as is the case with bacon when it is cut in thin slices and fried or baked until crisp. When foods are boiled, the natural juices being of somewhat different density from the water in which they are cooked, slight osmotic changes occur. There is a tendency toward equalization of the composition of the juices of the food and the water in which they are cooked. In order to achieve the best mechanical effects in cooking, high temperatures are not necessary, except at first for rupturing the tissues; softening of the tissues is best effected by prolonged and slow heat. At a higher temperature many of the volatile and essential oils are lost, while at lower temperatures these are retained and in some instances slightly developed. The cooking should be sufficiently prolonged and the temperature high enough to effectually disintegrate and soften all of the tissues, but not to cause extended chemical changes.

There is often an unnecessarily large amount of heat lost through faulty construction of stoves and lack of judicious use of fuels, which greatly enhances the cost of preparing foods. Ovens are frequently coated with deposits of soot; this causes the heat to be thrown out into the room or lost through the chimney, rather than utilized for heating the oven. In an ordinary cook stove it is estimated that less than 7 per cent of the heat and energy of the fuel is actually employed in bringing about physical and chemical changes incident to cooking.^[13]

29. Bacteriological Changes.—The bacterial organisms of foods are destroyed in the cooking, provided a temperature of 150° F. is reached and maintained for several minutes. The interior of foods rarely reaches a temperature above 200° F., because of the water they contain which is not completely removed below 212°. One of the chief objects in cooking food is to render it sterile. Not only do bacteria become innocuous through cooking, but various parasites, as trichina and tapeworm, are destroyed, although some organisms can live at a comparatively high temperature. Cooked foods are easily re-inoculated, in some cases more readily than fresh foods, because they are in a more disintegrated condition.

In many instances bacteria are of material assistance in the preparation of foods, as in bread making, butter making, curing of cheese, and ripening of meat. All the chemical compounds of which foods are composed are subject to fermentation, each compound being acted upon by its special ferment body. Those which convert the proteids into soluble form, as the peptonizing ferments, have no action upon the carbohydrates. A cycle of bacteriological changes often takes place in a food material, one class of ferments working until their products accumulate to such an extent as to prevent their further activity, and then the process is taken up by others, as they find the conditions favorable for development. This change of bacterial flora in food materials is akin to the changes in the vegetation occupying soils. In each case, there is a constant struggle for possession. Bacteria take a much more important part in the preparation of foods than is generally considered. As a result of their workings, various chemical products, as organic acids and aromatic compounds, are produced. The organic acids chemically unite with the nutrients of foods, changing their composition and physical properties. Man is, to a great extent, dependent upon bacterial action. Plant life also is dependent upon the bacterial changes which take place in the soil and in the plant tissues. The stirring of seeds into activity is apparently due to enzymes or soluble ferments which are inherent in the seed. A study of the bacteriological changes which foods undergo in their preparation and digestion more properly belongs to the subject of bacteriology, and in this work only brief mention is made of some of the more important parts which microörganisms take in the preparation of foods.

30. Insoluble Ferments.—Insoluble ferments are minute, plant-like bodies of definite form and structure, and can be studied only with the microscope.^[1] They are developed from spores or seeds, or from the splitting or budding of the parent cells. Under suitable conditions they multiply rapidly, deriving the energy for their life processes from the chemical changes which they induce. For example, in the souring of milk the milk sugar is changed by the lactic acid ferments into lactic acid. In causing chemical changes, the ferment gives none of its own material to the reacting substance. These ferment bodies undergo life processes similar to plants of a higher order.

All foods contain bacteria or ferments. In fact, it is impossible for a food stored and prepared under ordinary conditions, unless it has been specially treated, to be free from them. Some of them are useful, some are injurious, while others are capable of producing disease. The objectionable bacteria are usually destroyed by the joint action of sunlight, pure air, and water.

31. Soluble Ferments.—Many plant and animal cells have the power of secreting substances soluble in water and capable of producing fermentation changes; to these the term "soluble ferments," or "enzymes," is applied. These ferments have not a cell structure like the organized ferments. When germinated seed, as malted barley, is extracted, a soluble and highly nitrogenous substance, called the diastase ferment, is secured that changes starch into soluble forms. The soluble ferments induce chemical change by causing molecular disturbance or splitting up of the organic compounds, resulting in the production of derivative products. They take an important part in animal and plant nutrition, as by their action insoluble compounds are brought into a soluble condition so they can be utilized for nutritive purposes. In many instances ferment changes are due to the joint action of soluble and insoluble ferments. The insoluble ferment secretes an enzyme which induces a chemical change, modified by the further action of the soluble ferment. Many of the enzymes carry on their work at a low temperature, as in the curing of meat and cheese in cold storage.^[14]

32. General Relationship of Chemical, Physical, and Bacteriological Changes.—It cannot be said that the beneficial results derived from the cooking of foods are due to either chemical, physical, or bacteriological change alone, but to the joint action of the three. In order to secure a chemical change, a physical change must often precede, and a bacteriological change cannot take place without causing a change in chemical composition; the three are closely related and interdependent.

33. Esthetic Value of Foods.—Foods should be not only of good physical texture and contain the requisite nutrients, but they should also be pleasing to the eye and served in the most attractive manner. Some foods owe a part of their commercial value to color, and when they are lacking in natural color they are not consumed with a relish. There is no objection to the addition of coloring matter to foods, provided it is of a non-injurious character and does not affect the amount of nutrients, and that its presence and the kind of coloring material are made known. Some foods contain objectionable colors which are eliminated during the process of manufacture, as in the case of sugar and flour. As far as removal of coloring matter from foods during refining is concerned, there can be no objection, so long as no injurious reagents or chemicals are retained, as the removal of the color in no way affects the nutritive value or permits fraud, but necessitates higher purification and refining. The use of chemicals and reagents in the preparation and refining of foods is considered permissible in all cases where the reagents are removed by subsequent processes. In the food decisions of the United States Department of Agriculture, it is stated: "Not excluded under this provision are substances properly used in the preparation of food products for clarification or refining and eliminated in the further process of manufacture." ^[15]

CHAPTER III

35. Potatoes contain about 75 per cent of water and 25 per cent of dry matter, the larger portion being starch. There is but little nitrogenous material in the potato, only 2.25 per cent, of which about half is in the form of proteids. There are ten parts of non-nitrogenous substance to every one part of nitrogenous; or, in other words, the potato has a wide nutritive ratio, and as an article of diet needs to be supplemented with foods rich in protein. The mineral matter, cellular tissue, and fat in potatoes are small in amount, as are also the organic acids. Mechanically considered, the potato is composed of three parts,—outer skin, inner skin, and flesh. The layer immediately beneath the outer skin is slightly colored, and is designated the fibro-vascular layer. The outer and inner skins combined make up about 10 per cent of the weight of the potato.

A large portion of the protein of the potato is albumin, which is soluble in water. When potatoes are peeled, cut in small pieces, and soaked in water for several hours before boiling, 80 per cent of the crude protein, or total nitrogenous material, is extracted, rendering the product less valuable as food. When potatoes are placed directly in boiling water, the losses of nitrogenous compounds are reduced to about 7 per cent, and, when the skins are not removed, to 1 per cent. Digestion experiments show that 92 per cent of the starch and 72 per cent of the protein are digested.^[12] Compared with other foods, potatoes are often a cheap source of non-nitrogenous nutrients. If used in excessive amounts, however, they have a tendency to make the ration unbalanced and too bulky.

Mechanical Composition of the Potato

Chemical Composition of the Potato

36. Sweet Potatoes contain more dry matter than white potatoes, the difference being due mainly to the presence of about 6 per cent of sugar. There is approximately the same starch content, but more fat, protein, and fiber. As a food, they supply a large amount of non-nitrogenous nutrients.

37. Carrots contain about half as much dry matter as potatoes, and half of the dry matter is sugar, nearly equally divided between sucrose and levulose, or fruit sugar. Like the potato, carrots have some organic acids and a relatively small amount of proteids. In carrots and milk there is practically the same per cent of water. The nutrients in each, however, differ both as to kind and proportion. Experiments with the cooking of carrots show that if a large amount of water is used, 30 per cent or more of the nutrients, particularly of the more soluble sugar and albumin, are extracted and lost in the drain waters.^[12] The color of the carrot is due to the non-nitrogenous compound carrotin, C₂₆H₃₈. Carrots are valuable in a ration not because of the nutrients they supply, but for the palatability and the mechanical action which the vegetable fiber exerts upon the process of digestion.

38. Parsnips contain more solid matter than beets or carrots, of which 3 to 4 per cent is starch. The starch grains are very small, being only about one twentieth the size of the potato starch grains. There is 3 per cent of sugar and an appreciable amount of fat, more than in any other of the vegetables of this class, and seven times as much as in the potato. The mineral matter is of somewhat different nature from that in potatoes; in parsnips one half is potash and one quarter phosphoric acid, while in potatoes three quarters are potash and one fifth phosphoric acid.

39. Cabbage contains very little dry matter, usually less than 10 per cent. It is proportionally richer in nitrogenous compounds than many vegetables, as about two of the ten parts of dry matter are crude protein, which makes the nutritive ratio one to five. During cooking 30 to 40 per cent of the nutrients are extracted. Cabbage imparts to the ration bulk but comparatively little nutritive material. It is a valuable food adjunct, particularly used raw, as in a salad, when it is easily digested and retains all of the nutrients.^[12]

40. Cauliflower has much the same general composition as cabbage, from which it differs mainly in mechanical structure.

41. Beets.—The garden beet contains a little more protein than carrots, but otherwise has about the same general composition, and the statements made in regard to the losses of nutrients in the cooking of carrots and to their use in the dietary apply also to beets.

42. Cucumbers contain about 4 per cent of dry matter. The amount of nutrients is so small as to scarcely allow them to be considered a food. They are, however, a valuable food adjunct, as they impart palatability.

43. Lettuce contains about 7 per cent of solids, of which 1.5 is protein and 2.5 starch and sugar. While low in nutrients, it is high in dietetic value, because of the chlorophyll which it contains. It has been suggested that it is valuable, too, for supplying iron in an organic form, as there is iron chemically combined with the chlorophyll.

44. Onions are aromatic bulbs, valuable for condimental rather than nutritive purposes. They contain essential and volatile oils, which impart characteristic odor and flavor. In the onion there are about 1.5 per cent of protein and 9.5 per cent of non-nitrogenous material. Onions are often useful in stimulating the digestive tract to action.

45. Spinach is a valuable food, not to be classed merely as a relish. Its composition is interesting; for, although there is 90 per cent water, and less than 10 per cent dry matter, it still possesses high food value. Spinach contains 2.1 per cent crude protein, or about one part to every four parts of carbohydrates. In potatoes, turnips, and beets there are ten or more parts of carbohydrates to every one part of protein.

46. Asparagus is composed largely of water, about 93 per cent. The dry matter, however, is richer in protein than that of many vegetables. Asparagus contains, too, an amid compound, asparagin, which gives some of the characteristics to the vegetable.

47. Melons.—Melons contain from 8 to 10 per cent of dry matter, the larger portion of which is sugar and allied carbohydrates. The flavor is due to small amounts of essential oils and to organic acids associated with the sugars. Melons possess condimental rather than nutritive value.