[81] See Appendix, Note V., p. 158.
[82] See Historical Introduction, pp. 40-45.
[83] The evidence demonstrating this is to be found in the fact that the amount of carbon found in different soils rises or falls in proportion to the nitrogen. See p. 126.
[84] See Chapter IV. on Nitrification.
[85] Diffusion as well as capillary attraction is a means of bringing nitrates again to the surface-soil after rain.
[86] See Appendix, Note VI., p. 158, and Note VIII., p. 160; also p. 154.
[87] See Appendix, Note VII., p. 159.
[88] See following Chapter on Nitrification, p. 178.
[89] According to the Agricultural Returns for 1888, the number of cows in milk in Great Britain amounted to 2,450,444. If we multiply this number by 22 the result is 54,000,000 lb., or in tons 24,107. This quantity represents 154,067 tons of ordinary commercial nitrate of soda.
[90] For 1878 (p. 146 et seq.) The reader interested in the subject is referred to the paper itself.
[91] In tons 4464, and represents 28,530 tons of nitrate of soda.
[92] This in tons 162,946, which represents 1,041,384 tons of nitrate of soda.
[93] This in tons 40,625, which represents 259,633 tons of nitrate of soda. See paper in 'Journal of Science' already referred to.
[94] Europe's total production may be stated at 200,000 tons.
[95] 10,500 tons of which were as guano.
[96] Mr Warington estimates this at about 8 lb. See p. 141.
APPENDIX TO CHAPTER III.
NOTE I. (p. 119).
Determinations of the Quantity of Nitrogen supplied by Rain, as Ammonia and Nitric Acid, to an Acre of Land, during One Year.
(From Dr Fream's 'Soils and their Properties,' p. 62.)
| Nitrogen per | |||||
| million, as | Total | ||||
| Nitric | Nitrogen | ||||
| Year. | Rainfall. | Ammonia. | Acid. | per acre. | |
| lb. | |||||
| Kuschen | 1864-65 | 11.85 | 0.54 | 0.16 | 1.86 |
| Kuschen | 1865-66 | 17.70 | 0.44 | 0.16 | 2.50 |
| Insterburg | 1864-65 | 27.55 | 0.55 | 0.30 | 5.49 |
| Insterburg | 1865-66 | 23.79 | 0.76 | 0.49 | 6.81 |
| Dahme | 1865 | 17.09 | 1.42 | 0.30 | 6.66 |
| Regenwalde | 1864-65 | 23.48 | 2.03 | 0.80 | 15.09 |
| Regenwalde | 1865-66 | 19.31 | 1.88 | 0.48 | 10.38 |
| Regenwalde | 1866-67 | 25.37 | 2.28 | 0.56 | 16.44 |
| Ida-Marienhütte, | |||||
| mean of six years | 1865-70 | 22.65 | — | — | 9.92 |
| Proskau | 1864-65 | 17.81 | 3.21 | 1.73 | 20.91 |
| Florence | 1870 | 36.55 | 1.17 | 0.44 | 13.36 |
| Florence | 1871 | 42.48 | 0.81 | 0.22 | 9.89 |
| Florence | 1872 | 50.82 | 0.82 | 0.26 | 12.51 |
| Vallombrosa | 1872 | 79.83 | 0.42 | 0.15 | 10.38 |
| Montsouris, Paris | 1877-78 | 23.62 | 1.91 | 0.24 | 11.54 |
| Montsouris, Paris | 1878-79 | 25.79 | 1.20 | 0.70 | 11.16 |
| Montsouris, Paris | 1879-80 | 15.70 | 1.36 | 1.60 | 10.52 |
| Mean of | |||||
| 22 years | 27.63 | — | — | 10.23 | |
Nitrogen in Soils at Various Depths.
(1) Rothamsted Soils.
| Depth. | Arable soil. | Old pasture soil. | ||
| per cent. | lb. per acre. | per cent. | lb. per acre. | |
| 1st 9 inches | 0.120 | 3,015 | 0.245 | 5,351 |
| 2d 9 inches | 0.068 | 1,629 | 0.082 | 2,313 |
| 3d 9 inches | 0.059 | 1,461 | 0.053 | 1,580 |
| 4th 9 inches | 0.051 | 1,228 | 0.046 | 1,412 |
| 5th 9 inches | 0.045 | 1,090 | 0.042 | 1,301 |
| 6th 9 inches | 0.044 | 1,131 | 0.039 | 1,186 |
| Total, 54 inches | — | 9,554 | — | 13,143 |
| 7th 9 inches | 0.042 | 1,049 | — | — |
| 8th 9 inches | 0.041 | 1,095 | — | — |
| 9th 9 inches | 0.044 | 1,173 | — | — |
| 10th 9 inches | 0.043 | 1,076 | — | — |
| 11th 9 inches | 0.043 | 1,112 | — | — |
| 12th 9 inches | 0.045 | 1,198 | — | — |
| Total, 9 feet | — | 16,257 | — | — |
(2) Manitoba Soils.
| Depth. | Brandon. | Niverville. | Winnipeg. | Selkirk. |
| per cent. | per cent. | per cent. | per cent. | |
| 1st foot | 0.187 | 0.261 | 0.428 | 0.618 |
| 2d foot | 0.109 | 0.169 | 0.327 | 0.264 |
| 3d foot | 0.072 | 0.069 | 0.158 | 0.076 |
| 4th foot | 0.019 | 0.038 | 0.107 | 0.042 |
Nitrogen as Nitrates in Cropped Soils receiving no Nitrogenous Manure, in Lb. per Acre (Rothamsted Soils).
| Wheat. | ||||||
| After | After | Bokhara | White | |||
| fallow, | clover, | clover, | Vetches, | Lucern, | clover, | |
| Depth. | 1883. | 1883. | 1882. | 1883. | 1885. | 1885. |
| lb. | lb. | lb. | lb. | lb. | lb. | |
| 1st 9 inches | 3.4 | 6.1 | 3.4 | 10.2 | 8.9 | 11.5 |
| 2d 9 inches | 3.1 | 4.4 | 1.0 | 2.7 | 1.1 | 1.4 |
| 3d 9 inches | 0.8 | 1.6 | 0.6 | 1.1 | 0.8 | 0.9 |
| 4th 9 inches | 1.0 | 1.3 | 1.0 | 1.5 | 0.8 | 1.9 |
| 5th 9 inches | 0.8 | 1.5 | 0.8 | 2.5 | 1.0 | 7.1 |
| 6th 9 inches | 0.6 | 0.8 | 1.7 | 4.4 | 0.9 | 11.3 |
| 7th 9 inches | 0.8 | 2.2 | — | 4.5 | 0.6 | 13.1 |
| 8th 9 inches | 0.9 | 1.7 | — | 4.9 | 0.8 | 12.6 |
| 9th 9 inches | 0.7 | 2.4 | — | 4.8 | 0.7 | 11.2 |
| 10th 9 inches | 2.0 | 2.1 | — | 5.1 | 0.6 | 10.7 |
| 11th 9 inches | 1.5 | 2.1 | — | 6.4 | 0.4 | 11.1 |
| 12th 9 inches | 3.8 | 2.8 | — | 6.5 | 0.4 | 10.0 |
NOTE IV. (p. 124 and p. 131).
Nitrogen as Nitrates in Wheat-soils variously manured, October 1881, in Lb. per Acre (Rothamsted Soils).
| Excess | ||||||
| Total | over | |||||
| 1st 9 | 2nd 9 | 3rd 9 | 27 | plots | ||
| Plot. | Manuring. | inches. | inches. | inches. | inches. | 3 and 4. |
| lb. | lb. | lb. | lb. | lb. | ||
| 3 | No manure, 38 years | 9.7 | 5.3 | 2.8 | 17.8 | — |
| 4 | No manure, 30 years | 9.2 | 4.0 | 1.8 | 15.0 | — |
| 16a | No manure, 17 years | 10.6 | 5.0 | 2.3 | 17.9 | 1.5 |
| 5a | Ash constituents, 30 years | 12.6 | 7.1 | 4.6 | 24.3 | 7.9 |
| 17a | Ash constituents, 1 year | 10.3 | 7.5 | 3.4 | 21.2 | 4.8 |
| 6a | Ash and ammonium salts, 200 lb. | 16.5 | 7.5 | 4.7 | 28.7 | 12.3 |
| 7a | Ash and ammonium salts, 400 lb. | 22.8 | 11.3 | 5.7 | 39.8 | 23.4 |
| 8a | Ash and ammonium salts, 600 lb. | 21.1 | 13.9 | 7.8 | 42.8 | 26.4 |
| 9a | Ash and sodium nitrate, 550 lb. | 19.7 | 10.0 | 8.2 | 37.9 | 21.5 |
| 9b | Sodium nitrate, 550 lb. | 16.3 | 20.1 | 17.7 | 54.1 | 37.7 |
| 10a | Ammonium salts, 400 lb. | 14.2 | 11.9 | 7.3 | 33.4 | 17.0 |
| 11a | Superphosphate and ammonium salts, 400 lb. | 17.9 | 9.3 | 3.6 | 30.8 | 14.4 |
| 19 | Rape-cake, 1700 lb. | 14.1 | 13.0 | 7.1 | 34.2 | 17.8 |
| 2 | Farmyard manure, 14 tons—38years | 30.0 | 15.4 | 6.8 | 52.2 | 35.8 |
Nitrogen as Nitrates in Barley-soils variously manured, March 1892, in Lb. per Acre (Rothamsted Soils).
| Excess | ||||||
| Total | over | |||||
| 1st 9 | 2d 9 | 3d 9 | 27 | plot | ||
| Plot. | Manuring. | inches. | inches. | inches. | inches. | 10 |
| lb. | lb. | lb. | lb. | lb. | ||
| 10 | No manure | 5.9 | 4.7 | 5.1 | 15.1 | — |
| 20-40 | Ash constituents (mean) | 6.7 | 7.0 | 6.4 | 20.1 | 4.4 |
| 1A | Ammonium salts, 200 lb. | 6.1 | 8.3 | 7.0 | 21.4 | 5.7 |
| 2A-4A | Ammonium and ash constituents (mean) | 7.7 | 7.8 | 7.6 | 23.1 | 7.4 |
| 1AA | Sodium nitrate, 275 lb. | 9.7 | 6.8 | 9.0 | 25.5 | 9.8 |
| 2AA-4AA | Sodium nitrate and ash constituents (mean) | 8.3 | 7.4 | 7.5 | 23.2 | 7.5 |
| 1C | Rape-cake, 1000 lb. | 10.6 | 13.7 | 7.9 | 32.2 | 16.5 |
| 2C-4C | Rape-cake and ash constituents (mean) | 8.8 | 11.9 | 8.7 | 29.4 | 13.7 |
| 7-1 | No manure, 10 years—formerly dung | 14.8 | 11.8 | 10.9 | 37.5 | 21.8 |
| 7-2 | Farmyard manure, 14 tons | 18.6 | 14.6 | 10.9 | 44.1 | 28.4 |
NOTE V. (p. 134).
Examples of Increase of Nitrogen in Rothamsted Soils laid down in Pasture.
| Age of | Nitrogen in | |
| pasture. | 1st 9 inches. | |
| Years. | Per cent. | |
| Arable land | — | 0.140 |
| Barn-field pasture | 8 | 0.151 |
| Apple-tree pasture | 18 | 0.174 |
| Dr Gilbert's meadow | 21 | 0.204 |
| Dr Gilbert's meadow | 30 | 0.241 |
NOTE VI. (p. 141).
In connection with the loss by drainage of nitrogen in the form of nitrates, it may be mentioned that the water of many of the famous rivers contains large quantities of nitrates. Thus the water of the Seine has been found to contain fifteen parts of nitrates per million of water, and the Rhine eight parts per million. Some idea of what this amounts to per annum may be obtained by the statement that "the Rhine discharges daily 220 tons of saltpetre into the ocean, the river Seine 270, and the Nile 1100 tons."—(Storer's Agric. Chem., vol. i. p. 318.)
NOTE VII. (p. 142).
Examples of Decrease of Nitrogen in Rothamsted Soils.
| Nitrogen in | |
| 1st 9 inches. | |
| Per cent. | |
| Old pasture | 0.250 |
| Arable land in ordinary culture | 0.140 |
| Wheat unmanured, 38 years | 0.105 |
| Wheat and fallow unmanured, 31 years | 0.096 |
| Barley unmanured, 30 years | 0.093 |
| Turnips unmanured, 25 years | 0.085 |
Manuring, Produce of Wheat, and Alteration in the Composition of the Soil in Broadbalk Field, Rothamsted, from 1865 to 1881.
| Average | Nitrogen per acre | |||||
| produce | in 1st 9 inches | |||||
| per acre. | of soil. | |||||
| Gain or | ||||||
| Manures per acre, annually | Dressed | Total | loss in | |||
| Plot. | applied, 16 years, 1865-81. | grain. | produce. | 1865. | 1881. | 16 years. |
| bush. | lb. | lb. | lb. | lb. | ||
| 3 | Unmanured | 11-7/8 | 1715 | 2507 | 2404 | - 103 |
| 5a | Mixed mineral manure | 12-3/4 | 1963 | 2574 | 2328 | - 246 |
| 10a | Ammonium salts, 400 lb. | 17-7/8 | 2881 | 2548 | 2471 | - 77 |
| 11a | Ammonium salts, with superphosphate | 23-1/4 | 3856 | 2693 | 2676 | - 17 |
| 7a | Ammonium salts, with mixed mineral manure | 28 | 4993 | 2829 | 2908 | + 79 |
| 9a | Nitrate of soda, 550 lb., and mixed mineral manure | 36 | 6949 | 2834 | 2883 | + 49 |
| 16a | Unmanured* | 13-1/2 | 2194 | 2907 | 2557 | - 350 |
| 2 | Farmyard manure, 14 tons | 31-1/2 | 5356 | 4329 | 4502 | + 173 |
| * During 1852-64 received annually ammonium salts, 800 lb., with mixed mineral manure, and yielded an average product of 39-1/2 bushels of grain and 46-5/8 cwt. of straw. | ||||||
Amount of Drainage and Nitrogen as Nitrates in Drainage-water from unmanured Bare Soil, 20 and 60 inches deep—average of Thirteen Years.
| Nitrogen per acre | |||||||
| Amount of | Per million | ||||||
| drainage | of water | Per acre. | |||||
| 20-inch | 60-inch | 20-inch | 60-inch | 20-inch | 60-inch | ||
| Rainfall. | gauge. | gauge. | gauge. | gauge. | gauge. | gauge. | |
| Inches. | Inches. | Inches. | lb. | lb. | |||
| March | 1.70 | 0.85 | 0.94 | 7.3 | 8.9 | 1.41 | 1.89 |
| April | 2.25 | 0.72 | 0.79 | 8.3 | 9.0 | 1.35 | 1.61 |
| May | 2.48 | 0.80 | 0.79 | 8.4 | 9.1 | 1.53 | 1.63 |
| June | 2.59 | 0.78 | 0.78 | 9.2 | 9.1 | 1.62 | 1.60 |
| July | 2.85 | 0.68 | 0.62 | 13.5 | 11.8 | 2.08 | 1.66 |
| August | 2.69 | 0.84 | 0.76 | 15.1 | 13.3 | 2.87 | 2.28 |
| September | 2.70 | 0.97 | 0.82 | 17.7 | 13.4 | 3.86 | 2.50 |
| October | 3.12 | 1.86 | 1.68 | 13.8 | 11.9 | 5.83 | 4.53 |
| November | 3.20 | 2.44 | 2.32 | 11.8 | 11.4 | 6.50 | 5.98 |
| December | 2.34 | 1.88 | 1.88 | 9.5 | 10.6 | 4.06 | 4.51 |
| January | 2.13 | 1.79 | 1.93 | 7.4 | 8.9 | 2.99 | 3.88 |
| February | 2.16 | 1.84 | 1.74 | 7.7 | 9.1 | 3.19 | 3.57 |
| March-June | 9.02 | 3.15 | 3.30 | 8.3 | 9.0 | 5.91 | 6.73 |
| July-September | 8.24 | 2.49 | 2.20 | 15.6 | 13.0 | 8.81 | 6.44 |
| October-Feb. | 12.95 | 9.81 | 9.55 | 10.2 | 10.4 | 22.57 | 22.47 |
| Whole year | 30.21 | 15.45 | 15.05 | 10.7 | 10.5 | 37.29 | 35.64 |
CHAPTER IV.
NITRIFICATION.
The most important compound of nitrogen for the plant is nitric acid. It is as nitrates that most plants absorb the nitrogen they require to build up their tissue. In nature the nitrogen, present in the soil as ammonia and different organic forms, is constantly being converted into nitric acid. This conversion of nitrogen into nitrates, known as nitrification, is a process of very great importance, and, as has been already pointed out in the Introductory Chapter, is effected through the agency of micro-organisms (ferments).[97] The process of nitrification, as well as the nature of the other changes taking place in the soil between the various compounds of nitrogen, are as yet but most imperfectly understood, but much light has been thrown on this most interesting department of agricultural research during the last few years; and it cannot be doubted that the increased attention which it is receiving from different investigators, both on the Continent and in this country, will be fraught with most important results for practical agriculture.
Occurrence of Nitrates in the Soil.
The occurrence of nitre,[98] or potassium nitrate, in soils has been long known, although it is only within the last few years that we have obtained any precise knowledge with regard to the mode of its production. While its amount in most soils, especially in this country,[99] is very minute, there are certain parts of the world where nitrates are found in large quantities. The nitrate fields of Chili and Peru are the chief natural sources of nitrates, and they are referred to in the chapter on Nitrate of Soda. We have other parts of the world, however (in China and India), where soils rich in nitre occur, and which in the past have formed a source of the commercial article.[100]