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Manures and the principles of manuring

Chapter 27: CHAPTER IV. NITRIFICATION.
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About This Book

The work combines a historical survey and a practical, chemical account of soil fertility and manuring. It traces theories and experiments about plant nutrition, describing how plants obtain carbon, water, mineral nutrients and nitrogen, and discusses ash constituents, nitrification, and soil retention. It examines physical properties of soils, water and heat relations, and methods to increase absorptive power. Different manures—farmyard, artificial, and chemical fertilisers—are analysed for composition and action, and experimental methods such as water-culture and field trials are explained. Technical appendices and tables present experimental data and practical guidance for managing soil fertility.

[81] See Appendix, Note V., p. 158.

[82] See Historical Introduction, pp. 40-45.

[83] The evidence demonstrating this is to be found in the fact that the amount of carbon found in different soils rises or falls in proportion to the nitrogen. See p. 126.

[84] See Chapter IV. on Nitrification.

[85] Diffusion as well as capillary attraction is a means of bringing nitrates again to the surface-soil after rain.

[86] See Appendix, Note VI., p. 158, and Note VIII., p. 160; also p. 154.

[87] See Appendix, Note VII., p. 159.

[88] See following Chapter on Nitrification, p. 178.

[89] According to the Agricultural Returns for 1888, the number of cows in milk in Great Britain amounted to 2,450,444. If we multiply this number by 22 the result is 54,000,000 lb., or in tons 24,107. This quantity represents 154,067 tons of ordinary commercial nitrate of soda.

[90] For 1878 (p. 146 et seq.) The reader interested in the subject is referred to the paper itself.

[91] In tons 4464, and represents 28,530 tons of nitrate of soda.

[92] This in tons 162,946, which represents 1,041,384 tons of nitrate of soda.

[93] This in tons 40,625, which represents 259,633 tons of nitrate of soda. See paper in 'Journal of Science' already referred to.

[94] Europe's total production may be stated at 200,000 tons.

[95] 10,500 tons of which were as guano.

[96] Mr Warington estimates this at about 8 lb. See p. 141.







APPENDIX TO CHAPTER III.


NOTE I. (p. 119).

Determinations of the Quantity of Nitrogen supplied by Rain, as Ammonia and Nitric Acid, to an Acre of Land, during One Year.

(From Dr Fream's 'Soils and their Properties,' p. 62.)

           
      Nitrogen per  
      million, as Total
        Nitric Nitrogen
  Year. Rainfall. Ammonia. Acid. per acre.
          lb.
Kuschen 1864-65 11.85 0.54 0.16   1.86
Kuschen 1865-66 17.70 0.44 0.16   2.50
Insterburg 1864-65 27.55 0.55 0.30   5.49
Insterburg 1865-66 23.79 0.76 0.49   6.81
Dahme 1865 17.09 1.42 0.30   6.66
Regenwalde 1864-65 23.48 2.03 0.80 15.09
Regenwalde 1865-66 19.31 1.88 0.48 10.38
Regenwalde 1866-67 25.37 2.28 0.56 16.44
Ida-Marienhütte,          
    mean of six years 1865-70 22.65   9.92
Proskau 1864-65 17.81 3.21 1.73 20.91
Florence 1870 36.55 1.17 0.44 13.36
Florence 1871 42.48 0.81 0.22   9.89
Florence 1872 50.82 0.82 0.26 12.51
Vallombrosa 1872 79.83 0.42 0.15 10.38
Montsouris, Paris 1877-78 23.62 1.91 0.24 11.54
Montsouris, Paris 1878-79 25.79 1.20 0.70 11.16
Montsouris, Paris 1879-80 15.70 1.36 1.60 10.52
  Mean of        
22 years 27.63 10.23


NOTE II. (p. 122).

Nitrogen in Soils at Various Depths.

(1) Rothamsted Soils.

         
Depth. Arable soil. Old pasture soil.
  per cent. lb. per acre. per cent. lb. per acre.
  1st 9 inches 0.120   3,015 0.245   5,351
  2d 9 inches 0.068   1,629 0.082   2,313
  3d 9 inches 0.059   1,461 0.053   1,580
  4th 9 inches 0.051   1,228 0.046   1,412
  5th 9 inches 0.045   1,090 0.042   1,301
  6th 9 inches 0.044   1,131 0.039   1,186
Total, 54 inches   9,554 13,143
  7th 9 inches 0.042   1,049
  8th 9 inches 0.041   1,095
  9th 9 inches 0.044   1,173
10th 9 inches 0.043   1,076
11th 9 inches 0.043   1,112
12th 9 inches 0.045   1,198
Total, 9 feet 16,257


(2) Manitoba Soils.

         
Depth. Brandon. Niverville. Winnipeg. Selkirk.
  per cent. per cent. per cent. per cent.
1st foot 0.187 0.261 0.428 0.618
2d foot 0.109 0.169 0.327 0.264
3d foot 0.072 0.069 0.158 0.076
4th foot 0.019 0.038 0.107 0.042


NOTE III. (p. 130).

Nitrogen as Nitrates in Cropped Soils receiving no Nitrogenous Manure, in Lb. per Acre (Rothamsted Soils).

             
  Wheat.        
  After After Bokhara     White
  fallow, clover, clover, Vetches, Lucern, clover,
Depth. 1883. 1883. 1882. 1883. 1885. 1885.
  lb. lb. lb. lb. lb. lb.
  1st 9 inches 3.4 6.1 3.4 10.2 8.9 11.5
  2d 9 inches 3.1 4.4 1.0   2.7 1.1   1.4
  3d 9 inches 0.8 1.6 0.6   1.1 0.8   0.9
  4th 9 inches 1.0 1.3 1.0   1.5 0.8   1.9
  5th 9 inches 0.8 1.5 0.8   2.5 1.0   7.1
  6th 9 inches 0.6 0.8 1.7   4.4 0.9 11.3
  7th 9 inches 0.8 2.2   4.5 0.6 13.1
  8th 9 inches 0.9 1.7   4.9 0.8 12.6
  9th 9 inches 0.7 2.4   4.8 0.7 11.2
10th 9 inches 2.0 2.1   5.1 0.6 10.7
11th 9 inches 1.5 2.1   6.4 0.4 11.1
12th 9 inches 3.8 2.8   6.5 0.4 10.0


NOTE IV. (p. 124 and p. 131).

Nitrogen as Nitrates in Wheat-soils variously manured, October 1881, in Lb. per Acre (Rothamsted Soils).

             
            Excess
          Total over
    1st 9 2nd 9 3rd 9 27 plots
Plot. Manuring. inches. inches. inches. inches. 3 and 4.
    lb. lb. lb. lb. lb.
  3 No manure, 38 years   9.7   5.3   2.8 17.8
  4 No manure, 30 years   9.2   4.0   1.8 15.0
16a No manure, 17 years 10.6   5.0   2.3 17.9   1.5
  5a Ash constituents, 30 years 12.6   7.1   4.6 24.3   7.9
17a Ash constituents, 1 year 10.3   7.5   3.4 21.2   4.8
  6a Ash and ammonium salts, 200 lb. 16.5   7.5   4.7 28.7 12.3
  7a Ash and ammonium salts, 400 lb. 22.8 11.3   5.7 39.8 23.4
  8a Ash and ammonium salts, 600 lb. 21.1 13.9   7.8 42.8 26.4
  9a Ash and sodium nitrate, 550 lb. 19.7 10.0   8.2 37.9 21.5
  9b Sodium nitrate, 550 lb. 16.3 20.1 17.7 54.1 37.7
10a Ammonium salts, 400 lb. 14.2 11.9   7.3 33.4 17.0
11a Superphosphate and ammonium salts, 400 lb. 17.9   9.3   3.6 30.8 14.4
19 Rape-cake, 1700 lb. 14.1 13.0   7.1 34.2 17.8
  2 Farmyard manure, 14 tons—38years 30.0 15.4   6.8 52.2 35.8


Nitrogen as Nitrates in Barley-soils variously manured, March 1892, in Lb. per Acre (Rothamsted Soils).

             
            Excess
          Total over
     1st 9  2d 9  3d 9 27 plot
Plot. Manuring. inches. inches. inches. inches. 10
    lb. lb. lb. lb. lb.
10 No manure   5.9   4.7   5.1 15.1
20-40 Ash constituents (mean)   6.7   7.0   6.4 20.1   4.4
1A Ammonium salts, 200 lb.   6.1   8.3   7.0 21.4   5.7
2A-4A Ammonium and ash constituents (mean)   7.7   7.8   7.6 23.1   7.4
1AA Sodium nitrate, 275 lb.   9.7   6.8   9.0 25.5   9.8
2AA-4AA Sodium nitrate and ash constituents (mean)   8.3   7.4   7.5 23.2   7.5
1C Rape-cake, 1000 lb. 10.6 13.7   7.9 32.2 16.5
2C-4C Rape-cake and ash constituents (mean)   8.8 11.9   8.7 29.4 13.7
7-1 No manure, 10 years—formerly dung 14.8 11.8 10.9 37.5 21.8
7-2 Farmyard manure, 14 tons 18.6 14.6 10.9 44.1 28.4


NOTE V. (p. 134).

Examples of Increase of Nitrogen in Rothamsted Soils laid down in Pasture.

  Age of Nitrogen in
  pasture. 1st 9 inches.
  Years. Per cent.
Arable land 0.140
Barn-field pasture   8 0.151
Apple-tree pasture 18 0.174
Dr Gilbert's meadow 21 0.204
Dr Gilbert's meadow 30 0.241


NOTE VI. (p. 141).

In connection with the loss by drainage of nitrogen in the form of nitrates, it may be mentioned that the water of many of the famous rivers contains large quantities of nitrates. Thus the water of the Seine has been found to contain fifteen parts of nitrates per million of water, and the Rhine eight parts per million. Some idea of what this amounts to per annum may be obtained by the statement that "the Rhine discharges daily 220 tons of saltpetre into the ocean, the river Seine 270, and the Nile 1100 tons."—(Storer's Agric. Chem., vol. i. p. 318.)



NOTE VII. (p. 142).

Examples of Decrease of Nitrogen in Rothamsted Soils.

  Nitrogen in
  1st 9 inches.
  Per cent.
Old pasture 0.250
Arable land in ordinary culture 0.140
Wheat unmanured, 38 years 0.105
Wheat and fallow unmanured, 31 years 0.096
Barley unmanured, 30 years 0.093
Turnips unmanured, 25 years 0.085


Manuring, Produce of Wheat, and Alteration in the Composition of the Soil in Broadbalk Field, Rothamsted, from 1865 to 1881.

    Average Nitrogen per acre
    produce in 1st 9 inches
    per acre. of soil.
            Gain or
  Manures per acre, annually Dressed Total     loss in
Plot. applied, 16 years, 1865-81. grain. produce. 1865. 1881. 16 years.
    bush. lb. lb. lb. lb.
  3 Unmanured 11-7/8 1715 2507 2404 - 103
  5a Mixed mineral manure 12-3/4 1963 2574 2328 - 246
10a Ammonium salts, 400 lb. 17-7/8 2881 2548 2471 -   77
11a Ammonium salts, with superphosphate 23-1/4 3856 2693 2676 -   17
  7a Ammonium salts, with mixed mineral manure 28        4993 2829 2908 +   79
  9a Nitrate of soda, 550 lb., and mixed mineral manure 36        6949 2834 2883 +   49
16a Unmanured* 13-1/2 2194 2907 2557 - 350
  2 Farmyard manure, 14 tons 31-1/2 5356 4329 4502 + 173
* During 1852-64 received annually ammonium salts, 800 lb., with mixed mineral manure, and yielded an average product of 39-1/2 bushels of grain and 46-5/8 cwt. of straw.


NOTE VIII. (p. 141).

Amount of Drainage and Nitrogen as Nitrates in Drainage-water from unmanured Bare Soil, 20 and 60 inches deep—average of Thirteen Years.

      Nitrogen per acre
    Amount of Per million  
    drainage of water Per acre.
    20-inch 60-inch 20-inch 60-inch 20-inch 60-inch
  Rainfall. gauge. gauge. gauge. gauge. gauge. gauge.
  Inches. Inches. Inches.     lb. lb.
March   1.70   0.85   0.94   7.3   8.9   1.41   1.89
April   2.25   0.72   0.79   8.3   9.0   1.35   1.61
May   2.48   0.80   0.79   8.4   9.1   1.53   1.63
June   2.59   0.78   0.78   9.2   9.1   1.62   1.60
July   2.85   0.68   0.62 13.5 11.8   2.08   1.66
August   2.69   0.84   0.76 15.1 13.3   2.87   2.28
September   2.70   0.97   0.82 17.7 13.4   3.86   2.50
October   3.12   1.86   1.68 13.8 11.9   5.83   4.53
November   3.20   2.44   2.32 11.8 11.4   6.50   5.98
December   2.34   1.88   1.88   9.5 10.6   4.06   4.51
January   2.13   1.79   1.93   7.4   8.9   2.99   3.88
February   2.16   1.84   1.74   7.7   9.1   3.19   3.57
March-June   9.02   3.15   3.30   8.3   9.0   5.91   6.73
July-September   8.24   2.49   2.20 15.6 13.0   8.81   6.44
October-Feb. 12.95   9.81   9.55 10.2 10.4 22.57 22.47
Whole year 30.21 15.45 15.05 10.7 10.5 37.29 35.64






CHAPTER IV.

NITRIFICATION.


The most important compound of nitrogen for the plant is nitric acid. It is as nitrates that most plants absorb the nitrogen they require to build up their tissue. In nature the nitrogen, present in the soil as ammonia and different organic forms, is constantly being converted into nitric acid. This conversion of nitrogen into nitrates, known as nitrification, is a process of very great importance, and, as has been already pointed out in the Introductory Chapter, is effected through the agency of micro-organisms (ferments).[97] The process of nitrification, as well as the nature of the other changes taking place in the soil between the various compounds of nitrogen, are as yet but most imperfectly understood, but much light has been thrown on this most interesting department of agricultural research during the last few years; and it cannot be doubted that the increased attention which it is receiving from different investigators, both on the Continent and in this country, will be fraught with most important results for practical agriculture.


Occurrence of Nitrates in the Soil.

The occurrence of nitre,[98] or potassium nitrate, in soils has been long known, although it is only within the last few years that we have obtained any precise knowledge with regard to the mode of its production. While its amount in most soils, especially in this country,[99] is very minute, there are certain parts of the world where nitrates are found in large quantities. The nitrate fields of Chili and Peru are the chief natural sources of nitrates, and they are referred to in the chapter on Nitrate of Soda. We have other parts of the world, however (in China and India), where soils rich in nitre occur, and which in the past have formed a source of the commercial article.[100]