OPTICAL SCHEME.
Introduction.
The scheme is designed to furnish the student with a practical method of recognizing the common minerals in rock sections.
The arrangement followed has been to group minerals having general optical characters in common, at the same time giving their specific characters so as to make it possible to distinguish one from another. In each rectangle the minerals are arranged in order of their indices of refraction.
A tabulation of the minerals, with a list of optical characters appended, is of aid to the skilled investigator, but of very little assistance to the beginner.
The more common minerals, or those which are important petrographically, are printed in heavy-faced type; the minerals of less importance in small capitals.
Abbreviations and Conventions Used.
A. = Amorphous.
I. = Isometric system.
T. = Tetragonal system.
O. = Orthorhombic system.
M. = Monoclinic system.
Tri. = Triclinic system.
H. = Hexagonal system.
M(H). = Monoclinic, with hexagonal form or characters, as in the case of biotite.
⟂ = At right angles to.
El. = Elongation.
Ex. = Extinction.
∥ Ex. = Parallel extinction, as when the crystals extinguish parallel to cleavage lines or crystal edges. Extinction which is symmetrical to intersecting cleavage lines is also included under this term.
The mean refractive indices are printed in heavy-faced type.
The term “grains” is used to describe not only minerals which occur in typically granular form, but also those which have coarser allotriomorphic form, as elæolite and sodalite in plutonic rocks, such as syenite, etc.
General Rules for Use of Scheme.
The division of the scheme into two vertical columns is based on the values of the mean refractive indices, as determined by the “relief” and appearance of the surface. When the refractive index is above 1.60, the relief is fairly well to distinctly marked and the surface rough to very rough, depending on the value of the index.
Most of the rock-forming minerals with indices below 1.60 show no relief and a smooth surface, except in the case of a few of the rarer minerals (mostly isometric), which have very low indices and hence rough surface.
Mistakes may easily be made in the case of minerals near the limit; but practice and the use of the Becke test should soon make possible the classification into the two groups suggested by the scheme, and the appended descriptions will help to check errors.
When an unknown mineral lies adjacent to one that is known, use the Becke test for obtaining the relative refractive index of the unknown mineral; focus sharply on the line of contact between the known and unknown minerals,[158] then raise the objective slightly and the “bright line” will appear on the side of the mineral having the higher index. The method of Schrœder van der Kolk may also be employed, see p. 22.
The horizontal divisions of the scheme depend on the relative strength of the double refraction based on the observed interference colors. These colors to be of use in classification must be correctly recognized. The lower and middle colors of the 1° order, from bluish-gray through white to yellow, are easily known. The bright red, blue, green, etc., colors of the 1°, 2° and 3° orders can also be differentiated without trouble from the very high order colors (4° and above), which are essentially white in tone with no decided color tint.
When confusion arises, the exact order of the color can be determined by a quartz wedge, as given on p. 35. Furthermore, a ¼ undulation mica plate serves to quickly distinguish between the 1° order white and the practically colorless, high order tint of calcite, titanite, etc.; as after the insertion of the test-plate the 1° order white suffers a marked change in color, while the very high order (practically white) tint shows no appreciable change.
In the determination of these interference colors care must be given to considerations of orientation and thickness. The section must give the maximum interference color of all the obtainable sections of the mineral in the rock section. Such sections will be parallel to the ć axis in the uniaxial minerals and to the axial plane in the biaxial minerals; and will, therefore, in convergent light never show the emergence of an optic axis or bisectrix. Crystal “form,” cleavage, pleochroism, etc., may at times aid in the selection of these sections. The thickness of the section must also be considered, and it is well in all cases to pick out some known mineral in the section, as quartz, and note its maximum interference color. Knowing how this varies from the color given by the scheme for a section 0.03 mm.[159] in thickness, due allowance can be made for a like variation in the colors given by the other minerals. In the case of minerals with strong absorption the interference colors may not be noticeable on account of the absorption of parts of the light.
Under the subhead of pleochroism, the vibration direction of the ray of a definite color is given and not the direction of transmission of that ray.
The interference figures in convergent light increase in clearness and distinctness with the strength of the double refraction. In uniaxial crystals sections at right angles to the optic axis, i. e., sections which remain dark during a revolution between crossed nicols, show the best interference figures. In biaxial crystals the most characteristic interference figures are shown by sections at right angles to the acute bisectrix.
Crystal sections which are too small do not give very satisfactory interference figures with convergent light.[160]
Any scheme, however designed, makes a more or less arbitrary classification of the minerals, and when in doubt it is always safer to look for the mineral on both sides of the scheme line.
The rarer minerals are not included in this scheme, so when the determination of a mineral is uncertain or not positive recourse should be had to more elaborate tables.