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Perfumes and their preparation

Chapter 602: Eau Lenticuleuse.
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About This Book

The work surveys the development and principles of perfumery, reviews aromatic substances from plant and animal sources and their chemical counterparts, and explains methods for extracting, testing, and identifying adulteration. It presents classifications of perfumes and detailed recipes for handkerchief waters, dry sachets, fumigants, and ammoniacal or acid scents, followed by practical instructions for producing essences and extracts. Later sections cover hygienic and cosmetic perfumery with formulas for skin, hair, and mouth preparations, hair dyes and depilatories, colorants, and manufacturing utensils, offering guidance on material selection and wholesale production.

Talcum 4 lb.
Oil of lemon 75 grains.
Oil of bergamot 75 grains.

The talcum must be reduced to the finest powder, levigated, dried, and then perfumed. Owing to its unctuous nature, it readily adheres to the skin, and as it has no effect on it and does not change color, it is the best of all powders.

Liquid Bismuth White; Pearl White (Blanc Perlé Liquide).

Subnitrate of bismuth 1 lb.
Rose water 1 qt.
Orange-flower water 1 qt.

When standing at rest, the subnitrate of bismuth sinks to the bottom, while the supernatant fluid becomes quite clear. The bottle must therefore be vigorously shaken immediately before use. When this preparation remains on the skin for some length of time, it loses its pure white color and becomes yellow, or darker, through the gradual formation of a black sulphur compound.

Venetian Chalk (Craie Venétienne).

is made exactly like the French white, above; the only difference between the two preparations is that the talcum for the latter is brought to a red heat, which, however, causes it in part to lose the power of adhering to the skin.

B. Red Skin Cosmetics (Rouges).

Rouge Végetal Rose Liquide.

Ammonia water 2 oz.
Carmine 1¼ oz.
Essence of rose (triple) 2½ oz.
Rose water 2 qts.

This superior preparation, which serves mainly for coloring the lips, is made as follows: Reduce the carmine to powder; macerate it in the ammonia in a three or four pint bottle for several days, add the other ingredients, and let it stand for a week under oft-repeated agitation. At the end of that time the bottle is left undisturbed until the contents have become quite clear, when they are carefully decanted and filled into bottles for sale.

In order to obtain this preparation in proper form, only the finest carmine should be used. That known in the market as “No. 40” is the best. This alone will produce a cosmetic that, when brought in contact with the skin, will give a vivid red color.

In place of carmine, which requires the presence of ammonia if it is to remain in solution, the anilin color known as eosine may be used. Of this, very minute amounts will be sufficient to impart the proper tint. It is impracticable to give exact proportions, as these must be determined in each case by experiment. It is necessary to avoid an excess. The tint of a liquid colored by eosine may not appear deep, and yet when it is applied to the skin a decidedly deeper stain than was desired may be produced. Hence each addition of fresh coloring matter must be carefully controlled by a practical test.

Rouge en Feuilles.

Cut from thick, highly calendered paper circular disks about 2½ inches in diameter, and cover them with a layer of carmine containing just enough gum acacia to make it adhere to the paper. For use, the leaf is breathed on, a pledget of fine cotton is rubbed over it, and the adhering color is transferred to the skin.

Rouge en Pâte.

Carmine 1 oz.
Talcum 21 oz.
Gum acacia 1¾ oz.

The ingredients in finest powder are mixed in a mortar by prolonged trituration, then water is added in small portions to form a doughy mass to be filled into shallow porcelain dishes about the diameter of a dollar. If the rouge is desired darker for the use of actors and dark-complexioned persons, the proportion of carmine should be increased.

Rouge en Tasses.

Carthamin 1 oz.
Talcum powder 1 lb.
Gum acacia 1½ oz.
Oil of rose 15 grains.

This rouge, when dry, has a greenish metallic lustre; it is prepared and sold like rouge en pâte.

Bleu Végetal pour les Veines.

Venetian chalk 1 lb.
Berlin blue 1¾ oz.
Gum acacia 1 oz.

To the powdered solids add sufficient water to form a mass to be rolled into sticks. For use, a pencil is breathed on, rubbed against the rough side of a piece of white glove leather, and the veins are marked with the adhering color on the skin coated with pearl white. Of course, some dexterity is required to make the veins appear natural by the use of this blue color.

Rouge Alloxane (Alloxan Red; Murexide Paint).

Cold cream 1 lb.
Alloxan 75 grains.

Dissolve the alloxan in a little water and mix it intimately with any desired cold-cream. The mixture is white, but when transferred to the skin gradually becomes red. The preparation sold in Austria, etc., under the name of “Schnuda” is identical with this alloxan paint.

C. Face Lotions.

The skin often contains spots with marked color which are more or less unsightly; for instance, freckles, liver spots, mother’s marks (nævi), etc. Unfortunately we know of no remedy which radically removes them; even chemical preparations with the most energetic effects, which of course must never be employed owing to their destructive action on the skin, cannot entirely do away with these dark spots which have their seat in the lower layers of the skin. But the public demands preparations for the removal of freckles, liver spots, etc., and—obtains them. We subjoin the formulas for several of such secret remedies, but declare emphatically that none of them will completely effect the desired result.

Freckle Milk (Lait Antéphelique).

Camphor 1¾ oz.
Ammonium chloride ¾ oz.
Corrosive sublimate 150 grains.
Albumen 3½ oz.
Rose water 2 lb.

We call attention to the fact that the sublimate (bichloride of mercury) is very poisonous and must be used with the greatest care.

Freckle Lotion.

Angelica root 1¾ oz.
Black hellebore root 1¾ oz.
Storax ¾ oz.
Oil of bergamot 150 grains.
Oil of citron 150 grains.
Alcohol 2 qts.

Macerate for a week and filter.

Eau Lenticuleuse.

Potassium carbonate 7 oz.
Sugar ¾ oz.
Orange-flower water 2 qts.
Alcohol 7 oz.

Lilionese I.

Potassium carbonate 14 oz.
Water 4 lb.
Rose water 14 oz.
Alcohol 7 oz.
Oil of rose 150 grains.
Oil of cinnamon 75 grains.

Lilionese II.

Rose water 2 qts.
Orange-flower water 1 qt.
Glycerin 1 lb.
Potassium carbonate 3½ oz.
Tincture of benzoin ¾ to 1¾ oz.

Add only enough of the alcoholic tincture of benzoin to render the liquid slightly opalescent or milky.

Lotion for Chapped Skin.

Glycerin 4 lb.
Water 1 qt.
Rose water 1 qt.

Color pale red with cochineal.

Eau de Perles.

White soap 1 lb.
Dissolved in: Water 4 qts.
Glycerin 2 lb.
Add: Rose water 1 qt.
Tincture of musk 150 grains.

To be colored bluish with some indigo-carmin.

Teint de Venus.

Alcoholic soap solution 2 qts.
Carbonate of potassium 3½ oz.
Extract of orange flower 3½ oz.

The soap solution is made as concentrated as possible, and the entire fluid colored with cochineal; in place of the extract of orange flower, other essences or extracts may also be employed. For use, some of the liquid is poured into the wash water.

Pulchérine.

Carbonate of potassium 14 oz.
Water 4 lb.
Orange-flower water 2 lb.
Alcohol 3½ oz.
Oil of neroli 150 grains.
Tincture of vanilla ¾ oz.

The preceding preparations owe their activity merely to the presence of carbonate of potassium which forms an emulsion with the fat of the skin and thus resembles in its effects a mild soap. The other ingredients only serve to render the composition fragrant.

D. Toilet Powders.

Toilet powders are used to impart whiteness and smoothness to the skin; hence they are merely a kind of dry cosmetic which are applied by means of a powder puff or a hare’s foot. Their main ingredients are starch and talcum powders, perfumed and sometimes tinted a rose-red color. It is immaterial what kind of starch is used; rice, wheat, and potato starch are equally effective, provided they are clear white and in the finest powder. In some cases the bitter-almond bran remaining after the expression of the fixed oil and the preparation of the oil of bitter almond is likewise used for toilet powders. The more thoroughly these powders are rubbed into the skin, the whiter the latter becomes and the less easily can they be detected.

White Toilet Powder.

Fine levigated zinc white 1¾ oz.
Venetian talcum 1¾ oz.
Carbonate of magnesia 1¾ oz.
Oil of rose 20 drops.
Oil of orris 20 drops.

Mix intimately.

Pink Toilet Powder.

White toilet powder (see above) 5½ oz.
Carmine 8 grains.

Poudre de Pistaches.

Pistachio meal 10 lb.
Talcum 10 lb.
Oil of lavender ¾ oz.
Oil of rose ½ oz.
Oil of cinnamon 75 grains.

The oil must have been completely extracted from the pistachio meal, which is to be reduced to the finest powder.

Poudre à la Rose.

Starch powder 20 lb.
Carmine ¾ oz.
Oil of rose ½ oz.
Oil of santal ½ oz.
Oil of vetiver 150 grains.

Poudre à la Violette.

Starch powder 20 lb.
Orris root, in fine powder 10 lb.
Oil of bergamot ¾ oz.
Oil of lemon ¾ oz.
Oil of clove 150 grains.
Oil of neroli 150 grains.

Poudre Blanche Surfine (Poudre de Riz).

Starch powder 20 lb.
Subnitrate of bismuth 2 lb.
Oil of lemon ¾ oz.
Oil of rose 150 grains.

Blanc de Perles Sec (Dry Pearl White).

Venetian chalk 20 lb.
Subnitrate of bismuth 42 oz.
Zinc white 42 oz.
Oil of lemon 1½ oz.

Anti-Odorin.

Starch powder 1 lb.
Salicylic acid 150 grains.

This mixture, which is best left unperfumed, does excellent service when used to prevent an offensive odor in stockings or shoes. The inside of the stockings is dusted with the powder, and every week a teaspoonful is sprinkled into the shoes.

Skin Gloss.

Carbonate of potassium 1¾ oz.
Powdered spermaceti 1¾ oz.
Starch powder 1 lb.
Benzoin ¾ oz.
Oil of bitter almond 150 grains.

Mix intimately and preserve in well-closed boxes. For use, stir some into water.

Kaloderm.

Wheat flour 4 lb.
Almond bran 1 lb.
Orris root, in fine powder 1 lb.
Extract of rose 1 pint.
Glycerin 6 fl. oz.

Form into a dough which is thinned with water and painted on the skin.

Musk Paste (for Washing the Hands).

Powdered white soap 2 lb.
Orris root, in fine powder ½ lb.
Starch powder 1½ oz.
Oil of lemon ¾ oz.
Oil of neroli 150 grains.
Tincture of musk 1½ fl. oz.
Glycerin 12 fl. oz.

Rub the starch with the glycerin in a mortar until they are thoroughly mixed. Then transfer the mixture to a porcelain capsule and apply a heat gradually raised to 284° F. (and not exceeding 290° F.), stirring constantly, until the starch granules are completely dissolved, and a translucent jelly is formed. Then gradually incorporate with it the powdered soap and orris root, and lastly the oils and tincture.


CHAPTER XXVII.
HAIR COSMETICS.

The number of preparations used for the care of the hair and beard is considerable. Unfortunately we are forced to admit that the majority of them, especially those said to strengthen the scalp and to stimulate the growth of the hair, are utterly inert. Thus far we know too little of the natural conditions of growth of the hair to enable us to compound remedies which would actively aid the efforts of nature in this direction.

In like manner we cannot speak with approval of the preparations used to color the hair, either from a chemico-sanitary or from an æsthetic standpoint; many of them contain substances which positively injure the hair or impart to it an unnatural color which is detected at first sight. But a well-made cosmetic should never produce this effect, and nature must be faithfully imitated if the preparation is to deserve the name of a cosmetic.

With the so-called hair and beard elixirs almost incredible swindles are perpetrated; the practical perfumer, however, cannot advise against the use of such worthless preparations among his goods, as they are in daily demand. This is the reason why we furnish the formulas for some of these secret preparations; anybody at all familiar with the principles of chemistry and physiology will recognize their worthlessness from their composition. The only articles of practical value are those intended for cleansing the hair, for making it soft and glossy, some of the hair dyes, and the preparations for fixing the hair in certain positions.

A. Hair Washes.

Eau d’Athènes.

Carbonate of potassium 2½ oz.
Sassafras wood 8 oz.
Rose water 4 qts.
Orange-flower water 4 qts.
Alcohol 1 qt.

Macerate the ingredients for one month. The carbonate of potassium and the alcohol cleanse the hair and remove the fat. After using this wash and drying the hair, its fat and gloss should be restored by the application of a good pomade or hair oil.

Eau Glycerinée aux Cantharides.

Ammonia water 3½ oz.
Tincture of cantharides (see below) 3½ oz.
Rosemary water 8 qts.
Glycerin 10½ oz.
Oil of rose ¾ oz.

The tincture of cantharides is made by macerating 1¾ oz. of powdered Spanish flies (Lytta vesicatoria) in one quart of strong alcohol. The caustic ammonia has a similar cleansing effect as the carbonate of potassium; the glycerin makes the hair soft; the entire preparation is a happy combination, as it cleanses and softens the hair at the same time.

Eau de Fleurs; Extrait Végétal.

Extract of cassie 7 oz.
Extract of jasmine 7 oz.
Extract of orange flower 7 oz.
Tincture of tonka 3½ oz.
Extract of tuberose 7 oz.
Tincture of vanilla 3½ oz.
Rose water 2 qts.
Alcohol 2 qts.

Eau de Laurier.

Carbonate of ammonium. 5½ oz.
Borax 5½ oz.
Oil of sweet bay ½ oz.
Oil of rose 75 grains.
Rose water 5 qts.

Eau de Romarin.

Carbonate of potassium 1¾ oz.
Rosemary water 4 qts.
Essence of rose (triple) 1 qt.

Eau Saponique.

Rose water 5 qts.
Rondeletia perfume 10½ oz.
Saffron 75 grains.
Soap 1 oz.
Alcohol 10½ oz.

Boil the finely divided soap and the saffron with some distilled water until the soap is completely dissolved, add the other ingredients, mix intimately, and let stand for some days to allow the coarser particles of saffron to settle. This preparation has a particularly handsome appearance; in cut-glass bottles it shows a peculiar opalescence or iridescence; in transmitted light it represents an almost perfectly transparent, saffron-yellow liquid.

Eau Victoria.

Ammonia water 1 oz.
Expressed oil of almond 1 oz.
Oil of mace 75 grains.
Oil of nutmeg 75 grains.
Essence of rosemary 21 oz.
Rose water 4 lb.

Mix the ingredients, except the rose water, by vigorous agitation until a kind of emulsion results. Then add the rose water in small portions, shaking after each addition.

Eau de Roses.

Rose water 5 qts.
Oil of rose 75 grains.
Dissolve in
Alcohol 3½ oz.
And add
Tincture of vanilla 1¾ oz.
Tincture of civet 150 grains.

B. Hair Tonics.

Hair Restorer.

Tincture of cantharides (see above, page 281) 1¾ oz.
Tincture of nut-galls 1¾ oz.
Extract of musk 150 grains.
Carmine 75 grains.
Alcohol 3½ oz.
Rose water 1 qt.

Tincture of nut-galls is made by macerating 3½ oz. of powdered nut-galls in one quart of alcohol. The tincture of cinchona in the following formula is prepared in the same manner.

Tanno-Quinine Hair Restorer.

Tincture of cinchona 1¾ oz.
Tincture of nut-galls 1¾ oz.
Carmine 150 grains.
Oil of neroli 75 grains.
Oil of nutmeg 75 grains.
Alcohol 3½ oz.
Rose water 1 qt.
Orange-flower water 1 qt.

Baume de Milan pour les Cheveux.

Lard 1 lb.
Expressed oil of almond 1 lb.
Spermaceti 1¾ oz.
Carmine 150 grains.
Tincture of cantharides ¾ oz.
Tincture of storax 1 oz.
Tincture of tolu 1 oz.

Beard Producer.

Lard 1 lb.
Expressed oil of almond 1 lb.
Spermaceti ¾ oz.
Cantharides ¾ oz.
Carmine 150 grains.
Oil of bergamot 75 grains.
Oil of lavender 75 grains.
Oil of santal 75 grains.

Rub the cantharides with the carmine to the finest possible powder; add this with the essential oils to the other ingredients.

Formulas for similar hair tonics might be given to the number of several hundreds; but we repeat what we have said above—they do not produce the desired result.

While the well-known bay rum is used more as a face lotion or refreshing skin tonic, particularly after shaving, or when perspiring in hot weather, yet it is also often used as a wash for the scalp, and is popularly believed to stimulate the growth of hair, which is in reality not the case. We shall therefore give a formula for its preparation here:

Bay Rum.

Oil of bay (from Myrcia acris) 240 grains.
Oil of orange (bigarade) 16 grains.
Oil of Pimenta 16 grains.
Alcohol 1 qt.
Water 25 fl. oz.

Dissolve the oils in the alcohol and add the water. Mix the liquid with about 2 oz. of precipitated phosphate of lime, and filter. It will improve by age.

Genuine bay rum is imported from the West Indies (St. Thomas, etc.), where a crude kind of alcohol, obtained in connection with the manufacture of rum from molasses, is distilled with the fresh leaves of the bay-tree (Myrcia acris). The oil of bay obtained from this must not be confounded with the oil of sweet bay. The latter, as it appears in commerce, is a crude mixture of a fixed with a volatile oil.


CHAPTER XXVIII.
HAIR DYES AND DEPILATORIES.

The custom of dyeing the hair is universal in the Orient; in the Occident, however, hair dyes are also frequently used, namely, to hide the grayness of the hair, sometimes to give the hair a preferred color. Hair dyes, which are very numerous, may be divided into groups—those containing the dye-stuff ready formed, and those in which it is produced in the hair by some chemical process. Some hair dyes contain substances which in their nature are decidedly injurious to the hair; such articles, of course, must be dispensed with because, if frequently employed, they would certainly lead to baldness. We shall return to this subject in connection with the several preparations.

Regarding the use of hair dyes, especially those consisting of two separate portions, we may state that it is necessary to remove the fat from the hair before applying the dye, as the chemicals in question do not adhere well to fat. The hair should be thoroughly washed once or twice with soap, and dyed when nearly dry.

When dyeing the hair the preparations should first be diluted; if the color is not deep enough, the process is repeated. If the preparation is used at once in a concentrated form, a color may result which has no resemblance to any natural tint; hair meant to be black may assume a metallic bluish-black gloss.

A. Simple Hair Dyes.

Lead Hair Dye.

Oxide of lead 4 lb.
Quicklime 1 lb.
Calcined magnesia 1 lb.

The ingredients are rubbed to a very fine powder and for use are mixed with water, applied to the hair, and left there until the desired tint—light brown to black—is obtained, from four to twelve hours, when the powder is removed by washing. The lime by its caustic effect acts destructively on the horny substance of the hair. Moreover, all lead preparations without exception are very injurious to the organism; hence this hair dye is to be rejected, especially as there are harmless preparations which produce the same effect.

Karsi (Teinture Orientale).

Ambergris 75 grains.
Nut-galls 4 lb.
Iron filings 1¾ oz.
Copper filings 30 grains.
Musk 30 grains.

This preparation, which really comes from the Orient, is made as follows: Reduce the nut-galls to a very fine powder and roast them in an iron pan under continual stirring until they have become dark brown or almost black. This powder is triturated with the metals in fine powder and the aromatics, and preserved in a moist place. For use, some of the powder is moistened in the palm of the hand and vigorously rubbed into the hair; after a few days it assumes a deep black, natural color. The roasting changes the tannin bodies contained in the galls into gallic and pyrogallic acids which form deep black combinations with the metals, and themselves are easily transformed into brownish-black substances.

Kohol (Teinture Chinoise).

Gum arabic 1 oz.
India ink 1¾ oz.
Rose water 1 qt.

Powder the ink and the gum, and triturate small quantities of the powder with rose water until a uniform black liquid results, which must be free from granules. This liquid is placed in a bottle and the rest of the rose water added. Kohol can be used only by persons with black hair, and is employed particularly for dyeing the eyebrows. As the coloring matter of this preparation consists of carbon in a state of fine division, the dye is perfectly harmless.

Vegetable Dye.

Silver nitrate 2 oz.
Distilled water 1 qt.

This hair dye produces a deep black color, but cannot be recommended, as it is injurious to the hair. Its full effects appear only after the lapse of some hours.

Potassium Permanganate.

Potassium permanganate 5½ oz.
Distilled water 2 qts.

Crystalline potassium permanganate is soluble in water, forming a dark violet solution. When brought in contact with an organic substance—paper, linen, skin, horn, hair—it is rapidly decolored and imparts to the substances named a brown tint due to hydrated oxide of manganese. The hair is washed, as stated above, to remove the fat, and the dilute solution applied with a soft brush; the color is produced at once and according to the degree of dilution this innocuous preparation can be made to give any desired color from blond to very dark brown. Of course, this preparation can be used for the beard as well as the hair.

All the hair dyes here and elsewhere given stain the skin as well wherever they come in contact with it; hence care should be taken to protect the skin during their application.

B. Double Hair Dyes.

Silver Hair Dyes.

This and similar hair dyes consist of two preparations, preserved in bottles I. and II.; the latter, containing the silver solution, should be of dark amber-colored or black glass, as the silver salts are decomposed by light. It is utterly useless to employ blue glass for this purpose, as this admits the chemical rays of light as easily as flint glass. For use, some of the liquid from bottle I. is poured into a cup and the hair is moistened with it by means of a soft brush. The liquid from bottle II. is poured into a second cup and applied with another brush.

Brown Dye.

I. (In White Bottle.)

Sulphide of potassium 7 oz.
Alcohol 1 qt.

II. (In Dark Bottle.)

Silver nitrate 4¼ oz.
Distilled water 1 qt.

Black dye.

I. (In White Bottle.)

Sulphide of potassium ½ lb.
Alcohol 1 qt.

II. (In Dark Bottle.)

Silver nitrate 5½ oz.
Distilled water 1 qt.

The sulphide of potassium (liver of sulphur) appears in fragments of a liver-brown mass which readily dissolves in water. The solution must be filtered before being filled into bottles for sale, and, as it becomes turbid in the air, kept in well-closed vessels. When the two solutions are brought together, black sulphide of silver results and darkens the hair. After the use of this preparation a disagreeable odor of rotten eggs adheres to the hair, but can be easily removed by washing, especially with one of the previously mentioned hair washes.

The silver hair dye will be still better if the liquid contained in bottle II. is made by dropping into the solution, under continual stirring, ammonia water, until the precipitate first formed is again dissolved.

Melanogène.

I. (In Dark Bottle.)