¶ x. Convection, or carrying discharge.

1562. The last kind of discharge which I have to consider is that effected by the motion of charged particles from place to place. It is apparently very different in its nature to any of the former modes of discharge (1319.), but, as the result is the same, may be of great importance in illustrating, not merely the nature of discharge itself, but also of what we call the electric current. It often, as before observed, in cases of brush and glow (1440. 1535.), joins its effect to that of disruptive discharge, to complete the act of neutralization amongst the electric forces.

1563. The particles which being charged, then travel, may be either of insulating or conducting matter, large or small. The consideration in the first place of a large particle of conducting matter may perhaps help our conceptions.

1564. A copper boiler 3 feet in diameter was insulated and electrified, but so feebly, that dissipation by brushes or disruptive discharge did not occur at its edges or projecting parts in a sensible degree. A brass ball, 2 inches in diameter, suspended by a clean white silk thread, was brought towards it, and it was found that, if the ball was held for a second or two near any part of the charged surface of the boiler, at such distance (two inches more or less) as not to receive any direct charge from it, it became itself charged, although insulated the whole time; and its electricity was the reverse of that of the boiler.

1565. This effect was the strongest opposite the edges and projecting parts of the boiler, and weaker opposite the sides, or those extended portions of the surface which, according to Coulomb's results, have the weakest charge. It was very strong opposite a rod projecting a little way from the boiler. It occurred when the copper was charged negatively as well as positively: it was produced also with small balls down to 0.2 of an inch and less in diameter, and also with smaller charged conductors than the copper. It is, indeed, hardly possible in some cases to carry an insulated ball within an inch or two of a charged plane or convex surface without its receiving a charge of the contrary kind to that of the surface.

1566. This effect is one of induction between the bodies, not of communication. The ball, when related to the positive charged surface by the intervening dielectric, has its opposite sides brought into contrary states, that side towards the boiler being negative and the outer side positive. More inductric action is directed towards it than would have passed across the same place if the ball had not been there, for several reasons; amongst others, because, being a conductor, the resistance of the particles of the dielectric, which otherwise would have been there, is removed (1298.); and also, because the reacting positive surface of the ball being projected further out from the boiler than when there is no introduction of conducting matter, is more free therefore to act through the rest of the dielectric towards surrounding conductors, and so favours the exaltation of that inductric polarity which is directed in its course. It is, as to the exaltation of force upon its outer surface beyond that upon the inductric surface of the boiler, as if the latter were itself protuberant in that direction. Thus it acquires a state like, but higher than, that of the surface of the boiler which causes it; and sufficiently exalted to discharge at its positive surface to the air, or to affect small particles, as it is itself affected by the boiler, and they flying to it, take a charge and pass off; and so the ball, as a whole, is brought into the contrary inducteous state. The consequence is, that, if free to move, its tendency, under the influence of all the forces, to approach the boiler is increased, whilst it at the same time becomes more and more exalted in its condition, both of polarity and charge, until, at a certain distance, discharge takes place, it acquires the same state as the boiler, is repelled, and passing to that conductor most favourably circumstanced to discharge it, there resumes its first indifferent condition.

1567. It seems to me, that the manner in which inductric bodies affect uncharged floating or moveable conductors near them, is very frequently of this nature, and generally so when it ends in a carrying operation (1562. 1602.). The manner in which, whilst the dominant inductric body cannot give off its electricity to the air, the inducteous body can effect the discharge of the same kind of force, is curious, and, in the case of elongated or irregularly shaped conductors, such as filaments or particles of dust, the effect will often be very ready, and the consequent attraction immediate.

1568. The effect described is also probably influential in causing those variations in spark discharge referred to in the last series (1386. 1390. 1391.): for if a particle of dust were drawn towards the axis of induction between the balls, it would tend, whilst at some distance from that axis, to commence discharge at itself, in the manner described (1566.), and that commencement might so far facilitate the act (1417. 1420.) as to make the complete discharge, as spark, pass through the particle, though it might not be the shortest course from ball to ball. So also, with equal balls at equal distances, as in the experiments of comparison already described (1493. 1506.), a particle being between one pair of balls would cause discharge there in preference; or even if a particle were between each, difference of size or shape would give one for the time a predominance over the other.

1569. The power of particles of dust to carry off electricity in cases of high tension is well known, and I have already mentioned some instances of the kind in the use of the inductive apparatus (1201.). The general operation is very well shown by large light objects, as the toy called the electrical spider; or, if smaller ones are wanted for philosophical investigation, by the smoke of a glowing green wax taper, which, presenting a successive stream of such particles, makes their course visible.

1570. On using oil of turpentine as the dielectric, the action and course of small conducting carrying particles in it can be well observed. A few short pieces of thread will supply the place of carriers, and their progressive action is exceedingly interesting.

1571. A very striking effect was produced on oil of turpentine, which, whether it was due to the carrying power of the particles in it, or to any other action of them, is perhaps as yet doubtful. A portion of that fluid in a glass vessel had a large uninsulated silver dish at the bottom, and an electrified metal rod with a round termination dipping into it at the top. The insulation was very good, and the attraction and other phenomena striking. The rod end, with a drop of gum water attached to it, was then electrified in the fluid; the gum water soon spun off in fine threads, and was quickly dissipated through the oil of turpentine. By the time that four drops had in this way been commingled with a pint of the dielectric, the latter had lost by far the greatest portion of its insulating power; no sparks could be obtained in the fluid; and all the phenomena dependent upon insulation had sunk to a low degree. The fluid was very slightly turbid. Upon being filtered through paper only, it resumed its first clearness, and now insulated as well as before. The water, therefore, was merely diffused through the oil of turpentine, not combined with or dissolved in it: but whether the minute particles acted as carriers, or whether they were not rather gathered together in the line of highest inductive tension (1350.), and there, being drawn into elongated forms by the electric forces, combined their effects to produce a band of matter having considerable conducting power, as compared with the oil of turpentine, is as yet questionable.

1572. The analogy between the action of solid conducting carrying particles and that of the charged particles of fluid insulating substances, acting as dielectrics, is very evident and simple; but in the latter case the result is, necessarily, currents in the mobile media. Particles are brought by inductric action into a polar state; and the latter, after rising to a certain tension (1370.), is followed by the communication of a part of the force originally on the conductor; the particles consequently become charged, and then, under the joint influence of the repellent and attractive forces, are urged towards a discharging place, or to that spot where these inductric forces are most easily compensated by the contrary inducteous forces.

1573. Why a point should be so exceedingly favourable to the production of currents in a fluid insulating dielectric, as air, is very evident. It is at the extremity of the point that the intensity necessary to charge the air is first acquired (1374.); it is from thence that the charged particle recedes; and the mechanical force which it impresses on the air to form a current is in every way favoured by the shape and position of the rod, of which the point forms the termination. At the same time, the point, having become the origin of an active mechanical force, does, by the very act of causing that force, namely, by discharge, prevent any other part of the rod from acquiring the same necessary condition, and so preserves and sustains its own predominance.

1574. The very varied and beautiful phenomena produced by sheltering or enclosing the point, illustrate the production of the current exceedingly well, and justify the same conclusions; it being remembered that in such cases the effect upon the discharge is of two kinds. For the current may be interfered with by stopping the access of fresh uncharged air, or retarding the removal of that which has been charged, as when a point is electrified in a tube of insulating matter closed at one extremity; or the electric condition of the point itself may be altered by the relation of other parts in its neighbourhood, also rendered electric, as when the point is in a metal tube, by the metal itself, or when it is in the glass tube, by a similar action of the charged parts of the glass, or even by the surrounding air which has been charged, and which cannot escape.

1575. Whenever it is intended to observe such inductive phenomena in a fluid dielectric as have a direct relation to, and dependence upon, the fluidity of the medium, such, for instance, as discharge from points, or attractions and repulsions, &c., then the mass of the fluid should be great, and in such proportion to the distance between the inductric and inducteous surfaces as to include all the lines of inductive force (1369.) between them; otherwise, the effects of currents, attraction, &c., which are the resultants of all these forces, cannot be obtained. The phenomena, which occur in the open air, or in the middle of a globe filled with oil of turpentine, will not take place in the same media if confined in tubes of glass, shell-lac, sulphur, or other such substances, though they be excellent insulating dielectrics; nor can they be expected: for in such cases, the polar forces, instead of being all dispersed amongst fluid particles, which tend to move under their influence, are now associated in many parts with particles that, notwithstanding their tendency to motion, are constrained by their solidity to remain quiescent.

1576. The varied circumstances under which, with conductors differently formed and constituted, currents can occur, all illustrate the same simplicity of production. A ball, if the intensity be raised sufficiently on its surface, and that intensity be greatest on a part consistent with the production of a current of air up to and off from it, will produce the effect like a point (1537); such is the case whenever the glow occurs upon a ball, the current being essential to that phenomenon. If as large a sphere as can well be employed with the production of glow be used, the glow will appear at the place where the current leaves the ball, and that will be the part directly opposite to the connection of the ball and rod which supports it; but by increasing the tension elsewhere, so as to raise it above the tension upon that spot, which can easily be effected inductively, then the place of the glow and the direction of the current will also change, and pass to that spot which for the time is most favourable for their production (1591.).

1577. For instance, approaching the hand towards the ball will tend to cause brush (1539.), but by increasing the supply of electricity the condition of glow may be preserved; then on moving the hand about from side to side the position of the glow will very evidently move with it.

1578. A point brought towards a glowing ball would at twelve or fourteen inches distance make the glow break into brush, but when still nearer, glow was reproduced, probably dependent upon the discharge of wind or air passing from the point to the ball, and this glow was very obedient to the motion of the point, following it in every direction.

1579. Even a current of wind could affect the place of the glow; for a varnished glass tube being directed sideways towards the ball, air was sometimes blown through it at the ball and sometimes not. In the former case, the place of the glow was changed a little, as if it were blown away by the current, and this is just the result which might have been anticipated. All these effects illustrate beautifully the general causes and relations, both of the glow and the current of air accompanying it (1574.).

1580. Flame facilitates the production of a current in the dielectric surrounding it. Thus, if a ball which would not occasion a current in the air have a flame, whether large or small, formed on its surface, the current is produced with the greatest ease; but not the least difficulty can occur in comprehending the effective action of the flame in this case, if its relation, as part of the surrounding dielectric, to the electrified ball, be but for a moment considered (1375. 1380.).

1581. Conducting fluid terminations, instead of rigid points, illustrate in a very beautiful manner the formation of the currents, with their effects and influence in exalting the conditions under which they were commenced. Let the rounded end of a brass rod, 0.3 of an inch or thereabouts in diameter, point downwards in free air; let it be amalgamated, and have a drop of mercury suspended from it; and then let it be powerfully electrized. The mercury will present the phenomenon of glow; a current of air will rush along the rod, and set off from the mercury directly downwards; and the form of the metallic drop will be slightly affected, the convexity at a small part near the middle and lower part becoming greater, whilst it diminishes all round at places a little removed from this spot. The change is from the form of a (fig. 135.) to that of b, and is due almost, if not entirely, to the mechanical force of the current of air sweeping over its surface.

1582. As a comparative observation, let it be noticed, that a ball gradually brought towards it converts the glow into brushes, and ultimately sparks pass from the most projecting part of the mercury. A point does the same, but at much smaller distances.

1583. Take next a drop of strong solution of muriate of lime; being electrified, a part will probably be dissipated, but a considerable portion, if the electricity be not too powerful, will remain, forming a conical drop (fig. 136.), accompanied by a strong current. If glow be produced, the drop will be smooth on the surface. If a short low brush is formed, a minute tremulous motion of the liquid will be visible; but both effects coincide with the principal one to be observed, namely, the regular and successive charge of air, the formation of a wind or current, and the form given by that current to the fluid drop, if a discharge ball be gradually brought toward the cone, sparks will at last pass, and these will be from the apex of the cone to the approached ball, indicating a considerable degree of conducting power in this fluid.

1584. With a drop of water, the effects were of the same kind, and were best obtained when a portion of gum water or of syrup hung from a ball (fig. 137.). When the machine was worked slowly, a fine large quiet conical drop, with concave lateral outline, and a small rounded end, was produced, on which the glow appeared, whilst a steady wind issued, in a direction from the point of the cone, of sufficient force to depress the surface of uninsulated water held opposite to the termination. When the machine was worked more rapidly some of the water was driven off; the smaller pointed portion left was roughish on the surface, and the sound of successive brush discharges was heard. With still more electricity, more water was dispersed; that which remained was elongated and contracted, with an alternating motion; a stronger brush discharge was heard, and the vibrations of the water and the successive discharges of the individual brushes were simultaneous. When water from beneath was brought towards the drop, it did not indicate the same regular strong contracted current of air as before; and when the distance was such that sparks passed, the water beneath was attracted rather than driven away, and the current of air ceased.

1585. When the discharging ball was brought near the drop in its first quiet glowing state (1582.), it converted that glow into brushes, and caused the vibrating motion of the drop. When still nearer, sparks passed, but they were always from the metal of the rod, over the surface of the water, to the point, and then across the air to the ball. This is a natural consequence of the deficient conducting power of the fluid (1584. 1585.).

1586. Why the drop vibrated, changing its form between the periods of discharging brushes, so as to be more or less acute at particular instants, to be most acute when the brush issued forth, and to be isochronous in its action, and how the quiet glowing liquid drop, on assuming the conical form, facilitated, as it were, the first action, are points, as to theory, so evident, that I will not stop to speak of them. The principal thing to observe at present is, the formation of the carrying current of air, and the manner in which it exhibits its existence and influence by giving form to the drop.

1587. That the drop, when of water, or a better conductor than water, is formed into a cone principally by the current of air, is shown amongst other ways (1594.) thus. A sharp point being held opposite the conical drop, the latter soon lost its pointed form; was retraced and became round; the current of air from it ceased, and was replaced by one from the point beneath, which, if the latter were held near enough to the drop, actually blew it aside, and rendered it concave in form.

1588. It is hardly necessary to say what happened with still worse conductors than water, as oil, or oil of turpentine; the fluid itself was then spun out into threads and carried off, not only because the air rushing over its surface helped to sweep it away, but also because its insulating particles assumed the same charged state as the particles of air, and, not being able to discharge to them in a much greater decree than the air particles themselves could do, were carried off by the same causes which urged those in their course. A similar effect with melted sealing-wax on a metal point forms an old and well-known experiment.

1589. A drop of gum water in the exhausted receiver of the air-pump was not sensibly affected in its form when electrified. When air was let in, it begun to show change of shape when the pressure was ten inches of mercury. At the pressure of fourteen or fifteen inches the change was more sensible, and as the air increased in density the effects increased, until they were the same as those in the open atmosphere. The diminished effect in the rare air I refer to the relative diminished energy of its current; that diminution depending, in the first place, on the lower electric condition of the electrified ball in the rarefied medium, and in the next, on the attenuated condition of the dielectric, the cohesive force of water in relation to rarefied air being something like that of mercury to dense air (1581.), whilst that of water in dense air may be compared to that of mercury in oil of turpentine (1597.).

1590. When a ball is covered with a thick conducting fluid, as treacle or syrup, it is easy by inductive action to determine the wind from almost any part of it (1577.); the experiment, which before was of rather difficult performance, being rendered facile in consequence of the fluid enabling that part, which at first was feeble in its action, to rise into an exalted condition by assuming a pointed form.

1591. To produce the current, the electric intensity must rise and continue at one spot, namely, at the origin of the current, higher than elsewhere, and then, air having a uniform and ready access, the current is produced. If no current be allowed (1574.), then discharge may take place by brush or spark. But whether it be by brush or spark, or wind, it seems very probable that the initial intensity or tension at which a particle of a given gaseous dielectric charges, or commences discharge, is, under the conditions before expressed, always the same (1410.).

1592. It is not supposed that all the air which enters into motion is electrified; on the contrary, much that is not charged is carried on into the stream. The part which is really charged may be but a small proportion of that which is ultimately set in motion (1442.).

1593. When a drop of gum water (1584.) is made negative, it presents a larger cone than when made positive; less of the fluid is thrown off, and yet, when a ball is approached, sparks can hardly be obtained, so pointed is the cone, and so free the discharge. A point held opposite to it did not cause the retraction of the cone to such an extent as when it was positive. All the effects are so different from those presented by the positive cone, that I have no doubt such drops would present a very instructive method of investigating the difference of positive and negative discharge in air and other dielectrics (1480. 1501.).

1594. That I may not be misunderstood (1587.), I must observe here that I do not consider the cones produced as the result only of the current of air or other insulating dielectric over their surface. When the drop is of badly conducting matter, a part of the effect is due to the electrified state of the particles, and this part constitutes almost the whole when the matter is melted sealing-wax, oil of turpentine, and similar insulating bodies (1588.). But even when the drop is of good conducting matter, as water, solutions, or mercury, though the effect above spoken of will then be insensible (1607.), still it is not the mere current of air or other dielectric which produces all the change of form; for a part is due to those attractive forces by which the charged drop, if free to move, would travel along the line of strongest induction, and not being free to move, has its form elongated until the sum of the different forces tending to produce this form is balanced by the cohesive attraction of the fluid. The effect of the attractive forces are well shown when treacle, gum water, or syrup is used; for the long threads which spin out, at the same time that they form the axes of the currents of air, which may still be considered as determined at their points, are like flexible conductors, and show by their directions in what way the attractive forces draw them.

1595. When the phenomena of currents are observed in dense insulating dielectrics, they present us with extraordinary degrees of mechanical force. Thus, if a pint of well-rectified and filtered (1571.) oil of turpentine be put into a glass vessel, and two wires be dipped into it in different places, one leading to the electrical machine, and the other to the discharging train, on working the machine the fluid will be thrown into violent motion throughout its whole mass, whilst at the same time it will rise two, three or four inches up the machine wire, and dart off jets from it into the air.

1596. If very clean uninsulated mercury be at the bottom of the fluid, and the wire from the machine be terminated either by a ball or a point, and also pass through a glass tube extending both above and below the surface of the oil of turpentine, the currents can be better observed, and will be seen to rush down the wire, proceeding directly from it towards the mercury, and there, diverging in all directions, will ripple its surface strongly, and mounting up at the sides of the vessel, will return to re-enter upon their course.

1597. A drop of mercury being suspended from an amalgamated brass ball, preserved its form almost unchanged in air (1581.); but when immersed in the oil of turpentine it became very pointed, and even particles of the metal could be spun out and carried off by the currents of the dielectric. The form of the liquid metal was just like that of the syrup in air (1584.), the point of the cone being quite as fine, though not so long. By bringing a sharp uninsulated point towards it, it could also be effected in the same manner as the syrup drop in air (1587.), though not so readily, because of the density and limited quantity of the dielectric.

1598. If the mercury at the bottom of the fluid be connected with the electrical machine, whilst a rod is held in the hand terminating in a ball three quarters of an inch, less or more, in diameter, and the ball be dipped into the electrified fluid, very striking appearances ensue. When the ball is raised again so as to be at a level nearly out of the fluid, large portions of the latter will seem to cling to it (fig. 138.). If it be raised higher, a column of the oil of turpentine will still connect it with that in the basin below (fig. 139.). If the machine be excited into more powerful action, this will become more bulky, and may then also be raised higher, assuming the form (fig. 140); and all the time that these effects continue, currents and counter-currents, sometimes running very close together, may be observed in the raised column of fluid.

1599. It is very difficult to decide by sight the direction of the currents in such experiments as these. If particles of silk are introduced they cling about the conductors; but using drops of water and mercury the course of the fluid dielectric seems well indicated. Thus, if a drop of water be placed at the end of a rod (1571.) over the uninsulated mercury, it is soon swept away in particles streaming downwards towards the mercury. If another drop be placed on the mercury beneath the end of the rod, it is quickly dispersed in all directions in the form of streaming particles, the attractive forces drawing it into elongated portions, and the currents carrying them away. If a drop of mercury be hung from a ball used to raise a column of the fluid (1598.), then the shape of the drop seems to show currents travelling in the fluid in the direction indicated by the arrows (fig. 141.).

1600. A very remarkable effect is produced on these phenomena, connected with positive and negative charge and discharge, namely, that a ball charged positively raises a much higher and larger column of the oil of turpentine than when charged negatively. There can be no doubt that this is connected with the difference of positive and negative action already spoken of (1480. 1525.), and tends much to strengthen the idea that such difference is referable to the particles of the dielectric rather than to the charged conductors, and is dependent upon the mode in which these particles polarize (1503. 1523.).

1601. Whenever currents travel in insulating dielectrics they really effect discharge; and it is important to observe, though a very natural result, that it is indifferent which way the current or particles travel, as with reversed direction their state is reversed. The change is easily made, either in air or oil of turpentine, between two opposed rods, for an insulated ball being placed in connexion with either rod and brought near its extremity, will cause the current to set towards it from the opposite end.

1602. The two currents often occur at once, as when both terminations present brushes, and frequently when they exhibit the glow (1531.). In such cases, the charged particles, or many of them, meet and mutually discharge each other (1518. 1612.). If a smoking wax taper be held at the end of an insulating rod towards a charged prime conductor, it will very often happen that two currents will form, and be rendered visible by its vapour, one passing as a fine filament of smoky particles directly to the charged conductor, and the other passing as directly from the same taper wick outwards, and from the conductor: the principles of inductric action and charge, which were referred to in considering the relation of a carrier ball and a conductor (1566.), being here also called into play.

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1603. The general analogy and, I think I may say, identity of action found to exist as to insulation and conduction (1338. 1561.) when bodies, the best and the worst in the classes of insulators or conductors, were compared, led me to believe that the phenomena of convection in badly conducting media were not without their parallel amongst the best conductors, such even as the metals. Upon consideration, the cones produced by Davy296 in fluid metals, as mercury and tin, seemed to be cases in point, and probably also the elongation of the metallic medium through which a current of electricity was passing, described by Ampère (1113)297; for it is not difficult to conceive, that the diminution of convective effect, consequent upon the high conducting power of the metallic media used in these experiments, might be fully compensated for by the enormous quantity of electricity passing. In fact, it is impossible not to expect some effect, whether sensible or not, of the kind in question, when such a current is passing through a fluid offering a sensible resistance to the passage of the electricity, and, thereby, giving proof of a certain degree of insulating power (1328.).

1604. I endeavoured to connect the convective currents in air, oil of turpentine, &c. and those in metals, by intermediate cases, but found this not easy to do. On taking bodies, for instance, which, like water, adds, solutions, fused salts or chlorides, &c., have intermediate conducting powers, the minute quantity of electricity which the common machine can supply (371. 861.) is exhausted instantly, so that the cause of the phenomenon is kept either very low in intensity, or the instant of time during which the effect lasts is so small, that one cannot hope to observe the result sought for. If a voltaic battery be used, these bodies are all electrolytes, and the evolution of gas, or the production of other changes, interferes and prevents observation of the effect required.

1605. There are, nevertheless, some experiments which illustrate the connection. Two platina wires, forming the electrodes of a powerful voltaic battery, were placed side by side, near each other, in distilled water, hermetically sealed up in a strong glass tube, some minute vegetable fibres being present in the water. When, from the evolution of gas and the consequent increased pressure, the bubbles formed on the electrodes were so small as to produce but feebly ascending currents, then it could be observed that the filaments present were attracted and repelled between the two wires, as they would have been between two oppositely charged surfaces in air or oil of turpentine, moving so quickly as to displace and disturb the bubbles and the currents which these tended to form. Now I think it cannot be doubted, that under similar circumstances, and with an abundant supply of electricity, of sufficient tension also, convective currents might have been formed; the attractions and repulsions of the filaments were, in fact, the elements of such currents (1572.), and therefore water, though almost infinitely above air or oil of turpentine as a conductor, is a medium in which similar currents can take place.

1606. I had an apparatus made (fig. 142.) in which a is a plate of shell-lac, b a fine platina wire passing through it, and having only the section of the wire exposed above; c a ring of bibulous paper resting on the shell-lac, and d distilled water retained by the paper in its place, and just sufficient in quantity to cover the end of the wire b; another wire, e, touched a piece of tinfoil lying in the water, and was also connected with a discharging train; in this way it was easy, by rendering b either positive or negative, to send a current of electricity by its extremity into the fluid, and so away by the wire e.

1607. On connecting b with the conductor of a powerful electrical machine, not the least disturbance of the level of the fluid over the end of the wire during the working of the machine could be observed; but at the same time there was not the smallest indication of electrical charge about the conductor of the machine, so complete was the discharge. I conclude that the quantity of electricity passed in a given time had been too small, when compared with the conducting power of the fluid to produce the desired effect.

1608. I then charged a large Leyden battery (291.), and discharged it through the wire b, interposing, however, a wet thread, two feet long, to prevent a spark in the water, and to reduce what would else have been a sudden violent discharge into one of more moderate character, enduring for a sensible length of time (334.). I now did obtain a very brief elevation of the water over the end of the wire; and though a few minute bubbles of gas were at the same time formed there, so as to prevent me from asserting that the effect was unequivocally the same as that obtained by DAVY in the metals, yet, according to my best judgement, it was partly, and I believe principally, of that nature.

1609. I employed a voltaic battery of 100 pair of four-inch plates for experiments of a similar nature with electrolytes. In these cases the shell-lac was cupped, and the wire b 0.2 of an inch in diameter. Sometimes I used a positive amalgamated zinc wire in contact with dilute sulphuric acid; at others, a negative copper wire in a solution of sulphate of copper; but, because of the evolution of gas, the precipitation of copper, &c., I was not able to obtain decided results. It is but right to mention, that when I made use of mercury, endeavouring to repeat DAVY's experiment, the battery of 100 pair was not sufficient to produce the elevations298.

1610. The latter experiments (1609.) may therefore be considered as failing to give the hoped-for proof, but I have much confidence in the former (1605. 1608.), and in the considerations (1603.) connected with them. If I have rightly viewed them, and we may be allowed to compare the currents at points and surfaces in such extremely different bodies as air and the metals, and admit that they are effects of the same kind, differing only in degree and in proportion to the insulating or conducting power of the dielectric used, what great additional argument we obtain in favour of that theory, which in the phenomena of insulation and conduction also, as in these, would link the same apparently dissimilar substances together (1336. 1561.); and how completely the general view, which refers all the phenomena to the direct action of the molecules of matter, seems to embrace the various isolated phenomena as they successively come under consideration!

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1611. The connection of this convective or carrying effect, which depends upon a certain degree of insulation, with conduction; i.e. the occurrence of both in so many of the substances referred to, as, for instance, the metals, water, air, &c., would lead to many very curious theoretical generalizations, which I must not indulge in here. One point, however, I shall venture to refer to. Conduction appears to be essentially an action of contiguous particles, and the considerations just stated, together with others formerly expressed (1326, 1336, &c.), lead to the conclusion, that all bodies conduct, and by the same process, air as well as metals; the only difference being in the necessary degree of force or tension between the particles which must exist before the act of conduction or transfer from one particle to another can take place.

1612. The question then arises, what is this limiting condition which separates, as it were, conduction and insulation from each other? Does it consist in a difference between the two contiguous particles, or the contiguous poles of these particles, in the nature and amount of positive and negative force, no communication or discharge occurring unless that difference rises up to a certain degree, variable for different bodies, but always the same for the same body? Or is it true that, however small the difference between two such particles, if time be allowed, equalization of force will take place, even with the particles of such bodies as air, sulphur or lac? In the first case, insulating power in any particular body would be proportionate to the degree of the assumed necessary difference of force; in the second, to the time required to equalize equal degrees of difference in different bodies. With regard to airs, one is almost led to expect a permanent difference of force; but in all other bodies, time seems to be quite sufficient to ensure, ultimately, complete conduction. The difference in the modes by which insulation may be sustained, or conduction effected, is not a mere fanciful point, but one of great importance, as being essentially connected with the molecular theory of induction, and the manner in which the particles of bodies assume and retain their polarized state.

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¶ xi. Relation of a vacuum to electrical phenomena.

1613. It would seem strange, if a theory which refers all the phenomena of insulation and conduction, i.e. all electrical phenomena, to the action of contiguous particles, were to omit to notice the assumed possible case of a vacuum. Admitting that a vacuum can be produced, it would be a very curious matter indeed to know what its relation to electrical phenomena would be; and as shell-lac and metal are directly opposed to each other, whether a vacuum would be opposed to them both, and allow neither of induction or conduction across it. Mr. Morgan299 has said that a vacuum does not conduct. Sir H. Davy concluded from his investigations, that as perfect a vacuum as could be made300 did conduct, but does not consider the prepared spaces which he used as absolute vacua. In such experiments I think I have observed the luminous discharge to be principally on the inner surface of the glass; and it does not appear at all unlikely, that, if the vacuum refused to conduct, still the surface of glass next it might carry on that action.

1614. At one time, when I thought inductive force was exerted in right lines, I hoped to illustrate this important question by making experiments on induction with metallic mirrors (used only as conducting vessels) exposed towards a very clear sky at night time, and of such concavity that nothing but the firmament could be visible from the lowest part of the concave n, fig. 143. Such mirrors, when electrified, as by connexion with a Leyden jar, and examined by a carrier ball, readily gave electricity at the lowest part of their concavity if in a room; but I was in hopes of finding that, circumstanced as before stated, they would give little or none at the same spot, if the atmosphere above really terminated in a vacuum. I was disappointed in the conclusion, for I obtained as much electricity there as before; but on discovering the action of induction in curved lines (1231.), found a full and satisfactory explanation of the result.

1615. My theory, as far as I have ventured it, does not pretend to decide upon the consequences of a vacuum. It is not at present limited sufficiently, or rendered precise enough, either by experiments relating to spaces void of matter, or those of other kinds, to indicate what would happen in the vacuum case. I have only as yet endeavoured to establish, what all the facts seem to prove, that when electrical phenomena, as those of induction, conduction, insulation and discharge occur, they depend on, and are produced by the action of contiguous particles of matter, the next existing particle being considered as the contiguous one; and I have further assumed, that these particles are polarized; that each exhibits the two forces, or the force in two directions (1295. 1298.); and that they act at a distance, only by acting on the contiguous and intermediate particles.

1616. But assuming that a perfect vacuum were to intervene in the course of the lines of inductive action (1304.), it does not follow from this theory, that the particles on opposite sides of such a vacuum could not act on each other. Suppose it possible for a positively electrified particle to be in the centre of a vacuum an inch in diameter, nothing in my present views forbids that the particle should act at the distance of half an inch on all the particles forming the inner superficies of the bounding sphere, and with a force consistent with the well-known law of the squares of the distance. But suppose the sphere of an inch were full of insulating matter, the electrified particle would not then, according to my notion, act directly on the distant particles, but on those in immediate association with it, employing all its power in polarizing them; producing in them negative force equal in amount to its own positive force and directed towards the latter, and positive force of equal amount directed outwards and acting in the same manner upon the layer of particles next in succession. So that ultimately, those particles in the surface of a sphere of half an inch radius, which were acted on directly when that sphere was a vacuum, will now be acted on indirectly as respects the central particle or source of action, i.e. they will be polarized in the same way, and with the same amount of force.