NOTE II. (p. 227).
Solid Excreta voided by Sheep, Oxen, and Cows.
To contrast with the analyses given by Stoeckhardt, it may be well to cite those based on Lawes and Gilbert's experiments, and quoted by Warington ('Chemistry of the Farm,' p. 138):—
| Solid Excrement. | ||
| Fresh. | Dry. | |
| Water | 66.2 | — |
| Organic matter | 30.3 | 89.6 |
| Ash | 3.5 | 10.4 |
| Nitrogen | .7 | 2.0 |
II.—Oxen (fed on clover-hay and oat-straw, with 8 lb. beans per day).
| Fresh. | Dry. | |
| Water | 86.3 | — |
| Organic matter | 12.3 | 89.7 |
| Ash | 1.4 | 10.3 |
| Nitrogen | .3 | 1.9 |
III.—Cows (fed on mangels and lucerne hay).
| Mangels. | Lucerne hay. | |
| Water | 83.00 | 79.70 |
| Nitrogen | .33 | .34 |
| Phosphoric acid | .24 | .16 |
| Potash | .14 | .23 |
NOTE III. (p. 232).
Urine voided by Sheep, Oxen, and Cows.
The following are the results for urine, the animals being fed as in Note II.:—
| Sheep. | Oxen. | |||
| Fresh. | Dry. | Fresh. | Dry | |
| Water | 85.7 | — | 94.1 | — |
| Organic matter | 8.7 | 61.0 | 3.7 | 63.0 |
| Ash | 5.6 | 39.0 | 2.2 | 37.0 |
| Nitrogen | 1.4 | 9.6 | 1.2 | 20.6 |
| Cows. | ||
| Mangels. | Lucerne hay. | |
| Water | 95.94 | 88.25 |
| Nitrogen | .12 | 1.54 |
| Phosphoric acid | .01 | .006 |
| Potash | .59 | 1.69 |
Percentage of Food voided in the Solid and Liquid Excrements.
According to Wolff, the following table shows the percentage of the dry substance of the food which is voided in the solid and liquid excrements of the cow, ox, sheep, and horse:—
| Cow. | Ox. | Sheep. | Horse. | Average. | |
| Solid excreta | 38.0 | 44.0 | 42.6 | 46.7 | 42.8 |
| Urine | 5.8 | 6.3 | 6.8 | 5.7 | 6.2 |
| Total | 43.8 | 50.3 | 49.4 | 52.4 | 49.0 |
NOTE V. (p. 234).
Pig Excrements.
The excrements voided by pigs are poor in manurial constituents, because the food on which they are fed is generally of a very poor nature. In their case the urine is always very much richer in manurial ingredients than the solid excreta. The relative composition of the solid excreta and the urine will be best illustrated by quoting some experiments carried out by Wolff on this subject. The experiments were carried out with two pigs nine and a half months old, and each 121.9 kilogrammes (a kilogramme is equal to about 2-1/4 lb.) in weight. The first consumed daily 1000 grammes of barley, 5000 grammes of potatoes, and 2572 grammes of sour-milk. The second one consumed the same quantities of potatoes and sour-milk as the first, and 1000 grammes of peas. The following table gives the results of excreta and urine daily voided, in grammes:—
| Dry | Phosphoric | |||||||
| substance. | Nitrogen. | Ash. | Potash. | Lime. | Magnesia. | acid. | ||
| Solid | I. | 217.7 | 8.7 | 28.6 | 7.3 | 4.4 | 3.0 | 10.3 |
| excreta | II. | 161.1 | 9.1 | 31.1 | 5.9 | 4.9 | 2.8 | 11.1 |
| Urine | I. | 112.8 | 19.3 | 56.2 | 33.0 | 0.4 | 0.9 | 6.7 |
| II. | 137.7 | 30.6 | 62.2 | 37.1 | 0.2 | 1.1 | 7.1 | |
Manurial Constituents in 1000 Parts of Ordinary Foods.
Based on Lawes and Gilbert's Analyses.
(Warington's 'Chemistry of the Farm,' p. 139.)
| Dry | Phosphoric | |||
| matter. | Nitrogen. | Potash. | acid. | |
| Cotton-cake, decorticated | 918 | 70.4 | 15.8 | 30.5 |
| Rape-cake | 887 | 50.5 | 13.0 | 20.0 |
| Linseed-cake | 883 | 43.2 | 12.5 | 16.2 |
| Cotton-cake, undecorticated | 878 | 33.3 | 20.0 | 22.7 |
| Linseed | 882 | 32.8 | 10.0 | 13.5 |
| Palm-kernel meal, English | 930 | 25.0 | 5.5 | 12.2 |
| Beans | 855 | 40.8 | 12.9 | 12.1 |
| Peas | 857 | 35.8 | 10.1 | 8.4 |
| Malt-dust | 905 | 37.9 | 20.8 | 18.2 |
| Bran | 860 | 23.2 | 15.3 | 26.9 |
| Oats | 870 | 20.6 | 4.8 | 6.8 |
| Rice-meal | 900 | 19.1 | 6.1 | 23.8 |
| Wheat | 877 | 18.7 | 5.2 | 7.9 |
| Rye | 857 | 17.6 | 5.8 | 8.5 |
| Barley | 860 | 17.0 | 4.7 | 7.8 |
| Maize | 890 | 16.6 | 3.7 | 5.7 |
| Brewers' grains | 234 | 7.8 | 0.4 | 3.9 |
| Clover-hay | 840 | 19.7 | 18.6 | 5.6 |
| Meadow-hay | 857 | 15.5 | 16.0 | 4.3 |
| Bean-straw | 840 | 13.0 | 19.4 | 2.9 |
| Oat-straw | 857 | 6.4 | 16.3 | 2.8 |
| Barley-straw | 857 | 5.6 | 10.7 | 1.9 |
| Wheat-straw | 857 | 4.8 | 6.3 | 2.2 |
| Potatoes | 250 | 3.4 | 5.8 | 1.6 |
| Swedes | 107 | 2.2 | 2.0 | 0.6 |
| Carrots | 140 | 2.1 | 3.0 | 1.1 |
| Mangels | 120 | 1.8 | 4.6 | 0.7 |
| Turnips | 80 | 1.6 | 2.9 | 0.8 |
Analyses of Stable-Manure, made respectively with Peat-moss Litter and Wheat-straw (by Bernard Dyer, B.Sc.)
| Peat-moss litter. | Wheat-straw. | |
| Per cent. | Per cent. | |
| Total nitrogen | 0.88 | 0.61 |
| Equal to ammonia | 1.07 | 0.74 |
| Phosphoric acid | 0.37 | 0.43 |
| Equal to Tribasic phosphate of lime (or Tricalcic phosphate) | 0.80 | 0.94 |
| Potash | 1.02 | 0.59 |
NOTE VIII. (p. 242).
Analyses of Bracken (by J. Hughes, F.C.S.)
| Peat-moss litter. | Wheat-straw. | |
| No. 1 | No. 2 | |
| Young fern. | Old fern. | |
| Per cent. | Per cent. | |
| Water | 11.66 | 14.90 |
| *Organic matter | 83.38 | 80.54 |
| +Mineral matter | 4.96 | 4.56 |
| 100.0 | 100.0 | |
| Containing— | ||
| *Nitrogen | 2.42 | 0.90 |
| +Silica | 1.60 | 2.81 |
| Potash | 1.15 | 0.10 |
| Soda | 0.64 | 0.26 |
| Lime | 0.44 | 0.62 |
| Magnesia | 0.13 | 0.47 |
| Phosphoric acid | 0.60 | 0.30 |
NOTE IX. (p. 244).
Analyses of Horse-Manure.
For a fuller discussion of this question, the reader is referred to Heiden's 'Düngerlehre,' vol. ii. p. 185, and also to Storer's 'Agricultural Chemistry,' vol. i. p. 575. The statements in the different text-books as to the quantity of manure produced by the horse are such as naturally to perplex the student. This discrepancy is due, however, to the different methods adopted by different writers of calculating this amount. The subject is further discussed in the footnote to p. 252. The following analyses of horse-manure may be valuable for reference. They are taken from Storer's 'Agricultural Chemistry,' vol. i. p. 496:—
| 1. | 2. | 3. | 4. | 5. | Average. | |
| Water | 75.76 | 69.30 | 67.23 | 72.13 | 71.30 | 71.15 |
| Dry matter | 24.24 | 24.82 | 32.72 | 27.87 | 28.70 | 27.67 |
| Ash ingredients | 5.07 | 5.05 | 6.49 | 3.37 | 3.30 | 4.65 |
| Potash | 0.51 | 0.63 | 0.22 | 0.59 | 0.53 | 0.49 |
| Lime> | 0.30 | 0.74 | 0.17 | 0.41 | 0.21 | 0.36 |
| Magnesia | 0.19 | 0.29 | 0.20 | 0.17 | 0.14 | 0.20 |
| Phosphoric acid | 0.41 | 0.67 | 0.35 | 0.12 | 0.28 | 0.36 |
| Ammonia | 0.26 | 0.12 | 0.15 | 0.44 | — | 0.24 |
| Total nitrogen | 0.53 | 0.69 | 0.47 | 0.67 | 0.58 | 0.59 |
NOTE X. (p. 247).
The Nature of the Chemical Reactions of Ammonia "Fixers."
For the student, the exact nature of the chemical reactions taking place may be of interest.
In the first place, it must be distinctly understood that the form in which ammonia escapes from the manure-heap is not, as is so commonly erroneously stated in agricultural text-books, as "free" ammonia. Whenever ammonia is brought into contact with carbonic acid, carbonate of ammonia is formed. When it is remembered that carbonic acid is by far the most abundant of the gaseous products of the decomposition of organic matter, it will be at once seen that free ammonia could not exist under such circumstances.
1. In the case of hydrochloric acid, the following chemical equation will represent the nature of the reaction—
| 2HCl | (NH4)2CO3 | 2NH4Cl | H2O+CO2 | |||
| (Hydrochloric | + | (carbonate of | = | (sal-ammoniac,) | + | (carbonic acid.) |
| acid,) | ammonia,) |
2. In the case of sulphuric acid, the equation will be—
| H2SO4 | (NH4)2CO3 | (NH4)2SO4 | H2O+CO2 | |||
| (Sulphuric acid,) | + | (carbonate of | = | (sulphate of | + | (carbonic acid.) |
| ammonia,) | ammonia,) |
3. With gypsum (CaSO4)—
| CaSO4 | (NH4)2CO3 | CaCO3 | (NH4)2SO4 | |||
| (Gypsum,) | + | (carbonate of | = | (calcium | + | (sulphate of |
| ammonia,) | carbonate,) | ammonia.) |
4. With copperas (FeSO4)—
| FeSO4 | (NH4)2CO3 | FeCO3 | (NH4)2SO4 | |||
| (Sulphate of | + | (carbonate of | = | (ferrous | + | (sulphate of |
| iron,) | ammonia,) | carbonate,) | ammonia.) |
5. With sulphate of magnesia (MgSO4)—
| MgSO4 | (NH4)2CO3 | MgCO3 | (NH4)2SO4 | |||
| (Sulphate of | + | (carbonate of | = | (carbonate of | + | (sulphate of |
| magnesia,) | ammonia,) | magnesia,) | ammonia.) |
Reference has been made to the fact that magnesium sulphate may probably not only fix the ammonia, but the phosphoric acid. When magnesium sulphate, soluble phosphoric acid, and ammonia are brought in contact with one another, the double insoluble phosphate of ammonium and magnesium (MgNH4PO46Aq) is formed. While such a reaction is possible, it is highly improbable that it takes place to any extent. The double phosphate is a crystalline salt which only separates after a considerable time, and in the presence of a large excess of ammonia.
Analyses of Cow-Manure.[181]
| 1. | 2. | 3. | 4. | 5. | 6. | Average. | |
| Water | 85.30 | 77.71 | 74.02 | 72.87 | 75.00 | 77.50 | 77.06 |
| Dry matter | 14.70 | 22.30 | 25.98 | 27.13 | 25.00 | 22.50 | 22.93 |
| Ash ingredients | 2.04 | 4.71 | 3.94 | 6.70 | 6.22 | 2.20 | 4.30 |
| Potash | 0.36 | 0.46 | 0.56 | 1.69 | 0.39 | 0.40 | 0.64 |
| Lime | 0.29 | 0.37 | 0.58 | 0.41 | 0.24 | 0.31 | 0.48 |
| Magnesia | 0.19 | 0.11 | 0.13 | — | 0.18 | 0.11 | — |
| Phosphoric acid | 0.16 | 0.13 | 0.07 | 0.20 | 0.14 | 0.16 | 0.14 |
| Ammonia | 0.06 | 0.16 | 0.07 | — | 0.27 | — | 0.14 |
| Total nitrogen | 0.38 | 0.54 | 0.41 | 0.79 | 0.46 | 0.34 | 0.48 |
NOTE XII. (p. 259).
Composition of Fresh and Rotten Farmyard Manure (Voelcker).
| Water | 66.17 | |
| * | Soluble organic matter | 2.48 |
| Solumble inorganic matter | 1.54 | |
| + | Insoluble organic matter | 25.76 |
| Insoluble inorganic matter | 4.05 | |
| 100.00 | ||
| * | Containing nitrogen | .149 |
| Equal to ammonia | .181 | |
| + | Containing nitrogen | .494 |
| Equal to ammonia | .599 | |
| Total percentage of nitrogen | .643 | |
| Equal to ammonia | .780 | |
| Ammonia in a volatile state | .034 | |
| Ammonia in form of salts | .088 |
| Soluble in water, 27.55 per cent;— | ||
| Soluble silica | 4.25 | |
| Phosphate of lime | 4.25 | |
| Lime | 1.10 | |
| Magnesia | 0.20 | |
| Potash | 10.26 | |
| Soda | 0.92 | |
| Chloride of sodium | 0.54 | |
| Sulphuric acid | 0.22 | |
| Carbonic acid and loss | 4.71 | |
| Insoluble in water. 72.45 per cent:— | ||
| Soluble silica | 17.34 | |
| Insoluble silicious matter | 10.04 | |
| Oxide of iron and alumina with phosphates | 8.47 | |
| (Containing phosphoric acid, 3.18 per cnet.) | ||
| (Equal to bone-earath, 6.88 percnet.) | ||
| Lime | 20.21 | |
| Magnesia | 2.56 | |
| Potash | 1.78 | |
| Soda | 0.38 | |
| Sulphuric acid | 1.27 | |
| Carbonic acid and loss | 10.40 | |
| 100.00 | ||
| Water | 75.42 | |
| * | Soluble organic matter | 3.71 |
| Soluble inorganic matter | 1.47 | |
| + | Insoluble organic matter | 12.82 |
| Insoluble inorganic matter | 6.58 | |
| 100.00 | ||
| * | Containing nitrogen | .297 |
| Equal to ammonia | .360 | |
| + | Containing nitrogen | .309 |
| Equal to ammonia | .375 | |
| Total amount of nitrogen | .606 | |
| Equal to ammonia | .735 | |
| Ammonia in a volatile state | .046 | |
| Ammonia in form of salts | .057 |
Composition of the whole ash:—
| Soluble in water, 18.27 per cent:— | ||
| Soluble silica | 3.16 | |
| Phosphate of lime | 4.75 | |
| Lime | 1.44 | |
| Magnesia | 0.59 | |
| Potash | 5.58 | |
| Soda | 0.29 | |
| Chloride of sodium | 0.46 | |
| Sulphuric acid | 0.72 | |
| Carbonic acid and loss | 1.28 | |
| Insoluble in water, 81.7 per cent:— | ||
| Soluble silica | 17.69 | |
| Insoluble silica | 12.54 | |
| Phosphate of lime | — | |
| Oxides of iron alumina with phosphates | 11.76 | |
| (Containing phosphoric acid, 3.40 per cent.) | ||
| (Equal to bone-earth, 7.36 per cent.) | ||
| Lime | 20.70 | |
| Magnesia | 1.17 | |
| Potash | 0.56 | |
| Soda | 0.47 | |
| Chloride of sodium | — | |
| Sulphuric acid | 0.79 | |
| Carbonic acid and loss | 16.05 | |
| 100.00 | ||
NOTE XIII. (p. 263).
Comparison of Fresh and Rotten Manure (Wolff).
| Fresh. | Moderately rotten | |
| (Taking the quantity of dry matter as the same.) | ||
| Dry matter | 25.00 | 25.00 |
| Ash | 3.81 | 4.76 |
| Nitrogen | 0.39 | 0.49 |
| Potash | 0.45 | 0.56 |
| Lime | 0.49 | 0.61 |
| Magnesia | 0.12 | 0.15 |
| Phosphoric acid | 0.18 | 0.23 |
| Sulphuric acid | 0.10 | 0.13 |
| Silica | 0.86 | 1.08 |
Lord Kinnaird's Experiments.[182]
"Lord Kinnaird has given the particulars of a very careful experiment. He tried to test the comparative value of manure kept in an open court with that kept under cover. He selected the same kind of cattle, gave them the same kind and quantity of food, and bedded them with the same kind of straw. A field of 20 acres of uniform land was selected. This having been equally divided, 2 acres out of each 10 gave the following results:—