During the maximum advance of the ice from the Labradorean centre into the Continental basin it nearly reached the mouth of the Ohio River (near Cincinnati). An earlier advance from the Keewatin centre extended to the Missouri River in Missouri. There is evidence of a succession of advances and retreats of the ice forming a very complex history. With its final retreat the Great Lakes came into existence and the continent reached the stage in its development when man became prominent.
The study of glacial geology in North America was initiated, or at least given a fresh start and in the proper direction, by Louis Agassiz, and within recent years energetically carried forward by a large number of earnest workers. The stage of advance reached in this branch of geology which serves so admirably to link the present with the past is well presented in the numerous publications of T. C. Chamberlin and his associates.
The instructive history of the growth of North America and the successive appearance of higher and higher forms of life, the records of which have been discovered in the sedimentary rocks, has been made known by the combined studies of a large number of investigators, but the great task has been carried on mainly under the auspices of various national and State surveys. Chief among these is the present United States Geological Survey, which has published what may be justly termed a library of valuable literature and of topographic and geologic maps.
The Igneous Rocks (Plate IV).—Under the at present popular explanation of the origin of the earth, namely, the nebular hypothesis, and also the modification of it termed the meteoric hypothesis, the planet itself is considered to have been at one time in a molten condition. The starting-point of the study of the rocks composing the earth should be, therefore, the primitive crust cooled from fusion. In addition to this there have been throughout history geologic migrations of molten matter from deep within the earth towards the surface, and a part of the material thus forced outward, principally through fissures, has cooled in the rocks it penetrated, forming intrusions of various kinds, and a part has reached the surface and been extruded, as during volcanic eruptions.
Probably every known phase of vulcanism is illustrated by the igneous rocks of North America, and in certain branches of the subject, as the nature of intrusions and the changes which occur in the cooling of igneous magmas, marked advances in the world's knowledge have been made by American geologists.
Examples of volcanic phenomena on a grand scale are furnished by the still active volcanoes of the Caribbees, Central America, Mexico, and Alaska. Between southern Alaska and south-central Mexico there are no active craters, but a large number of volcanic mountains in various stages of erosion which form an instructive series illustrating the internal structure of the mode of accumulation of ejected fragment material and of lava-flows. In this series of mountains built by igneous agencies belongs the great volcanic piles of the Cascade region, of which Mounts Baker, Rainier, Adams, Hood, Jefferson, Mazama, Shasta, etc., are among the leading examples. Many other illustrations in the same connection, some of them in an advanced stage of erosion and now revealing only the dikes and necks of resistant rock that cooled and hardened well below the surface, occur widely throughout the southwest portion of the United States. The still recognisable volcanic mountains of the continent, with the exception of those of the Caribbees, are confined to its western half, and with the exception of certain almost perfect craters in eastern New Mexico are all within the Pacific mountains. A great belt of volcanoes, including a large number of both active and extinct examples, extends from Panama to the Aleutian Islands, a distance of some 7,000 miles, and is a part of the so-called "circle of fire" surrounding the Pacific Ocean. This belt is about 1,000 miles broad in its central part, where only extinct volcanoes exist, and narrows towards both its northern and southern extremities, which are defined by still steaming craters. The narrow northern portion, inclusive of the active volcanoes of the Alaskan Peninsula and the Aleutian Islands, is prolonged westward, and forms a curve concave to the southward, while the equally narrow southern portion marked by the energetic craters of Central America forms a curve concave to the northward. The entire belt has something the shape of a sigmoid curve, with a wide central portion.
In the preceding sketch of the growth of the continent it was shown that the Pacific mountain region is younger than the Atlantic mountain region. In this same connection certain interesting general conclusions have been reached in reference to igneous activity. In each of the great cordilleras referred to there have been extensive breaks in the earth's crust through which molten rocks have been forced upward. Volcanoes and various intrusions have been formed in each region, but in the eastern half of the continent the time since the last eruptions has been so great that all evidence in the relief of the land of the former presence of volcanic mountains has been obliterated. Erosion has cut deeply into the rocks on which the ancient volcanoes stood, and revealed in some instances the dikes occupying the fissures which supplied them. A large number of dikes of igneous rock occur in the Atlantic coast region from Prince Edward Island southward to Alabama and Georgia, and vast lava-flows of ancient date are still preserved about the south shore of Lake Superior. Volcanic eruptions in the older half of the continent have long since ceased and the breaks which gave them existence have been healed. The later movements in the western half of the continent have caused fresh fractures to form, through which molten matter has been forced to the surface. Many facts have been observed in each region which show an intimate connection between movements in the earth's crust which have produced fractures and the distribution of volcanoes.
The lavas poured out by the more recent volcanoes of North America are mainly dark basic rocks, among which basalt predominates. An exception occurs in the case of the Mono craters near Mono Lake, California, which in recent time extruded a thick, viscous, highly siliceous, rhyolitic lava, much of which cooled quickly and formed volcanic glass or obsidian.
In addition to streams and sheets of lava, many volcanoes, and especially those in a state of explosive eruption, blew into the air quantities of fragmental material, such as scoria, bombs, volcanic gravel (lapilli), dust, etc., which was scattered far and wide over the land. More or less extensive sheets of this material, in many instances interstratified with sedimentary beds, and especially with the strata laid down in Tertiary lakes, or separating lava-flows, occur widely throughout the Pacific mountains. Dust showers of the nature just referred to have occurred at a recent date, and the fine white material that fell is now found at the surface in a large number of localities, ranging from Central America to the Yukon Valley and from Kansas and Nebraska to Oregon and Washington.
The most remarkable instance of the addition of volcanic rocks to the surface of North America is in the case of the Columbia River lava, which covers some 200,000 or more square miles of country in Washington, Oregon, and neighbouring States. In that region outwellings of highly liquid rock came from fissures and spread widely over the surface as veritable inundations, which on cooling became black, basaltic rock, but without forming mountains or craters. Where the Snake River has excavated its magnificent cañon in these still horizontal layers of basalt, a thickness of 4,000 feet is revealed, although the stream has not as yet cut through the formation, and in Stein Mountain, Oregon, a similar series of lava-sheets over 5,000 feet thick has been measured. The Columbia River lava was spread over the surface of a deeply eroded land in a series of vast overflows of molten material. The liquid rock covered the broad plains and extended into the valleys in the adjacent mountains, giving them level floors of basalt. Mountain spurs became capes and headlands and outstanding buttes were transformed into islands in the molten sea. The lava since cooled and crystallized has in places been folded and tilted; streams like the Columbia, Snake, Spokane Rivers, etc., have carved great cañons in it, and the surface, especially where it is still nearly horizontal, has decayed and yielded a wonderfully rich soil. It is the fine, rich residual material of these lava plains, redistributed in part by the wind, which furnishes the basis for the immense wheat industry of the northwestern portion of the United States.
The extrusion of molten rock from deep within the earth so as to form volcanoes or fissure eruptions at the surface is only a part of a widely extended and highly varied process. As geologists have discovered, particularly in deeply eroded regions, by no means all of the fissures which permit of the forcing upward of molten material in them reach the surface. Many of them died out before coming to the light and favoured the production of various forms of intrusion.
A fissure originating deep in the earth's crust and extending upward, perhaps with many branches and irregularities, if injected with molten rock from below gives origin to dikes. That is, a dike is a more or less vertical sheet of igneous rock which has cooled and crystallized in a fissure. Such sheets of intruded material cutting across the bedding of stratified rocks, or traversing older igneous or metamorphic terranes, are of common occurrence and are frequently abundant in deeply eroded regions. They occur particularly in mountains of upheaval, thus demonstrating the fact that to a large extent the fissure which became injected with molten magmas and perhaps gave origin to volcanoes, are due to movements in the rocks composing the earth's crust. The force which causes molten rock to rise in such fissures also tends to prolong and enlarge them. The heat of an intruded magma affects the rocks it traverses and produces what is termed contact metamorphism. Examples of dikes in the Newark system have already been referred to, and others are common throughout the Pacific mountains. Where the Columbia River lava in central Washington has been removed by erosion, hundreds, and in fact thousands, of dikes are exposed in the terranes on which it formerly rested.
When a dike ends above in horizontally bedded rocks it sometimes happens that the injected magma, especially if highly fluid, is forced in between the strata and spreads widely between the layers, forming an intruded sheet, which lifts a broad cover to a height equal to its own thickness. An example of an intrusion of this nature is furnished by the palisade trap-sheet in New Jersey and New York, which has a maximum thickness of about 1,000 feet, and is fully 100 miles in length from north to south. The portion which remains is but a remnant and is seldom over 2 or 3 miles wide. This sheet in common with its associated sandstones and shales has been tilted so as to dip westward at an angle of about 15 degrees, and its eastern border eroded so as to form the picturesque Palisades on the west bank of the Hudson opposite New York city. Many other similar intruded sheets are known in Nova Scotia, the Connecticut Valley, among the Pacific mountains, etc.
A marked variation in the process just outlined occurs when, as the controlling condition, the intruded magma is highly viscous instead of highly fluid, and the friction of contact and of flow is greatly increased. Under such circumstances the intruded magma expands less widely than is the case when an intruded sheet is formed, and a thick intrusion results, which lifts a small cover perhaps to a great height. Intrusions of this nature are sometimes expanded in their upper portions into a more or less mushroom shape, and from their fancied resemblance to cisterns of once molten rock within older terranes have been termed laccoliths. The typical examples are furnished by the Henry Mountains in southern Utah, described by G. K. Gilbert. Other similar intrusions in Colorado have been studied by Whitman Cross, and yet other examples have been discovered in various parts of the Pacific mountains. In the case of certain of the laccoliths in the Henry Mountains, now laid bare by erosion, the cistern-like mass of intruded material is 12,000 feet or more in diameter, some 5,000 feet thick in the central part, and lifted a cover of stratified rocks fully 7,000 feet thick.
Where a dike ends above in older rocks, and particularly in horizontally stratified sedimentary beds, in a pipe-like form, similar to the conduit of a volcano, but without reaching the surface, the unexpanded or but slightly enlarged summit portion lifts a comparatively small cover into a dome, and what has been termed a plutonic plug results.
All the various phases of intrusions thus far referred to, it will be readily seen, are variations of one process. The wide range in the results produced are dependent on local conditions, either in respect to terranes invaded, as, for example, whether or not they are undisturbed sedimentary beds, and on the physical condition of the intruded material, in reference especially to its degree of viscosity. There is an intimate and even a genetic connection between intrusions on the one hand and volcanic and fissure eruptions on the other. If fissures lead from portions of the earth's crust sufficiently deep to permit the rocks to become plastic or fused on account of the relief of pressure due to the opening of the fissure, the magma may be forced to the surface, becoming more and more plastic or more perfectly fluid as the weight upon it decreased, and volcanic phenomena result; or if the fissure fails to reach the surface intrusions of various forms may be produced. The simplest form of intrusion, the dike, results under whatever condition the summit portion of the magma comes to rest. A magma forced upward in fissures in the earth's crust may meet moist rocks or even reservoirs of water, and in such instances steam or gases are produced and a new force is added, which may produce explosions.
In addition to the intrusions of the various classes just referred to there are others on a far larger scale, examples of which occur in North America, but as yet their mode of origin has been but little studied. I refer to vast upwellings of molten or plastic material beneath the more rigid portions of the earth's crust, which elevate domes, perhaps 200 or 300 miles or more in their various horizontal diameters. The great areas occupied by intrusive granite, as the one from which the Bitter Root Mountains in Idaho have been sculptured, are of this nature. These "regional intrusions," as they may be termed, elevate mountains in the same general manner as in the case of laccoliths, but of far greater size. To the elevations produced in this manner I have ventured to apply the name subtuberant mountains, in expression of the idea that they have resulted from vertical uplifts, due to the upswelling of molten material beneath.
The Metamorphic Rocks (Plate IV).—At the contact of either sedimentary or igneous rocks with intrusive rocks of whatever form, such as dikes, sheets, laccoliths, etc., there has been in many well-known instances an alteration of the terranes penetrated or uplifted which is most intense along the contact and diminishes at a distance. This change or metamorphism, as it is termed, consists of an alteration in the colour, texture, hardness, mineral and chemical composition, etc., of the rocks affected, and may be manifest throughout a thickness of but a few feet, or perhaps only a few inches, but near large intrusions is apt to be traceable for scores or hundreds of feet. In the case of intense contact metamorphism, the altered rock assumes a new form, and may exhibit a crystalline and foliated or schistose structure. The changes referred to are most marked when water is present, and are thought to be due largely to the influence of heated water percolating through the rocks and producing changes by solution and deposition. The principal agencies which take part in contact metamorphism are heat, heated waters, pressure, and perhaps movements within the rocks.
There are extensive regions throughout which the rocks have been changed in a manner similar to the alterations commonly found adjacent to igneous intrusions which, in general, have been brought about in some other way. This regional metamorphism, as it is termed, has affected the rocks in certain instances throughout districts measuring many hundreds of square miles in surface extent, and with a vertical range of many thousands of feet. The rocks referred to have been changed without fusion from a previous condition, during which they were either sedimentary beds or cooled and crystallized igneous magma. This conclusion has been verified in numerous instances by tracing the thoroughly altered rocks to regions where the change has been less intense and finally to where they pass by insensible gradations into easily recognisable sedimentary or igneous terranes. Common examples of metamorphic rocks are mica, schist, gneiss, statuary marble, certain granites, etc. These rocks frequently have a foliated or fissile structure, such as it is presumed would result from a flowing movement within the mass while under great pressure. Characteristically also the rocks are composed of interlocking crystals or portions of crystals, which are not contained in a glassy base, as is the case with most rocks that have crystallized from fusion. That is, the metamorphic rocks are characteristically holocrystalline, while igneous rocks are porphyritic, or cryptocrystalline.
The analogy between rocks altered by contact metamorphism and those affected by regional metamorphism had led to the conclusion that the latter, like the former, have been changed by heat and the passage through them of heated water bearing mineral matter, and especially silica, in solution. More than this, the foliation frequently so characteristic of metamorphic rocks is considered as evidence of a flowing movement or shearing of the material while under pressure. In short, rocks are altered by heat, especially if water is present in them, by motion, and by chemical changes produced by percolating waters, and perhaps in still other ways. The degree of heat required is not definitely known, and probably varies according to the nature of the rocks, the presence or absence of water, etc., but is certainly less than that necessary to produce fusion, and is thought, in general, to be in the neighbourhood of 750° F. While heat alone is considered as sufficient to produce metamorphism, it is probable that in most instances two or more of the agencies just referred to have been in operation at the same time. In the case of the foliated rocks motion within the mass seems to have been the predominating factor, and dynamical metamorphism is considered as important as heat metamorphism.
In North America, as is indicated roughly on the map forming Plate IV, metamorphic rocks occur at the surface over a great region in eastern and northeastern Canada, in Labrador and Newfoundland, in the New England States, and thence southward along the eastern side of the Appalachians. Other extensive regions occupied by similar rocks occur in many of the ranges of the Pacific mountains, from Alaska to Panama, and are known in the West Indies.
Not only do the metamorphosed rocks outcrop at the surface over large areas, but, as may be inferred from such outcrops, as well as from the records of numerous borings, underlies nearly the entire extent of the sedimentary formations. The basal portion of the continent, with the exception of certain areas where igneous rocks occur, is formed of metamorphosed terranes. So generally is this true, that it is safe to say that if a boring is begun at any locality on the continent where sedimentary beds occur, and is continued downward until the sedimentary rocks are passed through, metamorphic terranes will be found beneath. The same is true also where the surface is composed of lava-sheets. The exceptions, where metamorphosed rocks do not occur beneath sedimentary or volcanic beds, are when igneous intrusions or ancient lava-flows are present at a depth.
In the brief description given of the Archean system on a preceding page, it was stated that the rocks composing it are largely metamorphic. But rocks of practically any age may be altered in the several ways mentioned above, and the resulting gneisses, schists, etc., be indistinguishable from those of the Archean. In fact, some of the metamorphosed rocks of North America, as certain gneisses, schists, etc., of the Sierra Nevada and Cascade Mountains, are known to be of Mesozoic and even Cenozoic age.
In speaking of the growth of North America, and again in connection with the distribution of volcanic mountains, it was shown that there has been a progressive migration of the field of action of the forces which upheave the rocks so as to form land areas, and also of the movements in the rocks which produce fractures and lead to the origin of volcanoes. In a similar way the sphere of influence of metamorphism as indicated by the age of the transformed rocks in various regions has in a general way migrated from east to west across the continent.
In the Laurentian Highlands the metamorphosed rocks are of pre-Cambrian age; in New England and the Appalachian region they are, in part at least, of Paleozoic age; and in the Sierra Nevada and Cascade Mountains metamorphosed Mesozoic and Cenozoic rocks occur. As movements in the outer portion of the earth's crust may produce fractures in any class of rocks, and as such fractures favour the intrusion of igneous material, the metamorphic rocks may contain igneous intrusions similar to those noted above in connection with sedimentary rocks. As the stratification so marked in sedimentary beds is lacking in metamorphosed rocks, it is not to be expected that intrusions will take the form of sheets, laccoliths, etc., but rather appear as dikes with perhaps irregular branches. As the same region may experience two or more periods of metamorphism, it is evident that great complexities may arise, as, for example, when a metamorphosed terrane is penetrated by dikes and irregular intrusions and again subjected to metamorphosing conditions. These considerations lead to the suggestion that rocks metamorphosed in pre-Cambrian time, for example, would be apt to be more complex than those of Mesozoic date. In general, this has been found to be true, as is suggested by the fact that to the pre-Cambrian metamorphosed terranes, as previously stated, the name Basement Complex has been applied.
Summary.—The relation of the three great divisions into which the rocks composing North America, in common with all other portions of the known lithosphere, are divided, may perhaps be better understood when it is remembered that the igneous rocks came from below in a molten condition; that the sedimentary rocks have been formed at the surface from the débris of either igneous, metamorphic, or previously formed sedimentary beds; and that metamorphic rocks have been produced within the earth's outer crust by the alteration of either igneous or sedimentary rocks. When the heat which produced certain phases of metamorphism is sufficiently increased, greater freedom of molecular and chemical changes occur and the material acted on passes to the condition of an igneous magma. The three great classes of rocks considered above are thus seen to be but stages in a cycle which the material of the lithosphere passes through.
The conditions which bring about these changes are still in action and are intimately associated with movements in the rocks of the earth's crust. When elevation raises a portion of the earth's crust above sea-level, erosion and redeposition ensue and sedimentary rocks are formed; the greater the elevation the more energetically the forces act which bring about denudation, transportation, and sedimentation. When depression occurs of sufficient amount to carry rocks previously at or near the surface into the zone of metamorphism, alterations follow, and in general the deeper the depression the greater the changes until metamorphism culminates in fusion, providing pressure does not counteract the influence of heat. Dynamical and chemical metamorphism may occur at less depth than purely heat metamorphism, and it may be presumed takes place in the axes of mountain ranges, even above sea-level. Such a broad view of the relations and genesis of the three great lithologic divisions of the material forming the earth's outer crust is necessary to the understanding of the conditions observed in the basal portion of the geological column, as it is termed, in which the age and order of succession of the sedimentary rocks is indicated. In certain localities, for example, the Cambrian rocks rest unconformably on a surface of metamorphic and igneous rocks—that is, the Basement Complex was raised above sea-level, eroded and subsequently depressed before the Cambrian sediments were laid upon it. In other localities the Cambrian rocks pass indefinitely into metamorphosed terranes beneath, which means that metamorphism invaded the series after the deposition of the Cambrian, and the characteristics of its junction with older rocks was obliterated. Similar relations may evidently be discovered at any horizon in the geological column. Obviously the chances of a system of stratified rocks becoming metamorphosed or of being removed by erosion, are greater the nearer their position to the base of the sedimentary series; in a similar way the chances of a sedimentary terrane becoming invaded by igneous intrusions is greater the greater its age; again, the older a sedimentary terrane the greater the chances of its becoming buried by subsequent deposition and the less the likelihood of its being exposed for study. The only position in which a sedimentary formation can maintain its integrity and be safe from destruction by erosion or transformation by metamorphism is below sea-level and above the zone of heat metamorphism; but even in this position it may have its distinctive features, including its fossils, obliterated by dynamical and chemical alterations. These suggestions are offered for the sake of indicating, as stated on a previous page, that the Cambrian and Algonkian rocks should not be considered as the first formed sediments, and that there is hope of the discovery of a rich fauna of older date than any at present known. In the search for the earliest evidence of animal life on the earth, North America holds out favourable conditions.
The most important branch of geology treats of the substances in the earth's crust that are of direct service to man, as, for example, building stones, coal, iron, petroleum, gold, etc. Only a glance can here be given at the conditions which have led to the origin of the materials of commercial value and to their geographical distribution.
From the mode of origin of the principal classes of rocks it may be reasonably inferred that certain minerals and ores will be developed or concentrated in one class of rocks and not in the others. To a great extent the facts observed during the development of mines, etc., sustain this prediction.
In the cooling and crystallizing of igneous rocks from a state of fusion many minerals are formed, the most common being silicates of the alkaline earths, which are usually inclosed in a glassy or cryptocrystalline base. The igneous rocks have characteristically a highly complex chemical composition, and although frequently containing the metallic element, etc., which are of economic importance, these are widely disseminated, and in nearly all cases in chemical combinations, as the minor ingredients of siliceous minerals. Although the igneous rocks sometimes contain valuable ores, they are in many, if not all instances, due to secondary enrichment and are not a result of primary crystallization from fusion. As all the material of the earth's crust was at one stage in the series of changes it has experienced consolidated from fusion, it follows that the ores and minerals now of economic value did not then exist, or were widely diffused and have since been formed or concentrated.
The processes of concentration referred to are carried on in various ways through the agency of mechanical, chemical, vital, molecular, and electrical forces, acting singly or in association. For example, concentration through the action of mechanical agencies is illustrated by the manner in which rocks are reduced to fragments in the every-day process of denudation and the resulting débris removed by streams and redeposited. In this process an assorting in reference to size, specific gravity, etc., takes place, and certain substances, as sand, for instance, is accumulated in one locality, and certain other substances, as clay, deposited in another locality. During this process gold, platinum, etc., owing to their high specific gravity, may be concentrated in stream channels. The accumulation of mineral matter through the action mainly of chemical agencies, occurs when the waters percolating through rocks dissolves certain substances, as calcium carbonate, for instance, and on coming to the surface as springs, or dripping from the roofs of caverns, deposit calcareous tufa, stalactites, etc. Silica, iron, manganese, and other substances are frequently concentrated in a similar manner.
Concentration of previously widely disseminated substances principally through the agency of vital forces, is illustrated by the manner in which molluscs and polyps obtain calcium carbonate from water and deposit it in their shells or skeletons. The part played by plants in this same connection is shown by the way in which they eliminate carbon dioxide from the air or from water, and concentrate the carbon in their tissues. From the carbon accumulated in this manner, under certain conditions, deposits of peat, lignite, coal, graphite, etc., have resulted.
What may provisionally at least be termed molecular concentration occurs when similar molecules are brought together largely by water and crystallized to form mineral species. In order to simplify this brief discussion as much as practicable, this phase of concentration will be included under the chemical processes referred to above.
The three principal methods by which mineral substances are concentrated, namely, the mechanical, chemical, and vital, have in the main different fields of action. The mechanical and vital agencies operate at the surface of the lithosphere, although organic products, principally certain acids, descend into the earth in solution in water and play an important part in deep-seated chemical changes, as in the formation of mineral veins. The chemical agencies bring about the concentration of mineral substances both at or near the surface and at a depth.
The intensity with which the several agencies just referred to operate varies according to conditions. The mechanical agencies, for example, acting mainly through the aid of flowing water, are in general most potent in humid regions and where the land is high above sea-level. Vital agencies depend largely on climate and are most active in warm humid regions. The chemical agencies are influenced largely by heat, the presence of water, and by pressure.
It is interesting to note that a high degree of heat leads to the dissipation and wide distribution of substances previously concentrated; fusion, for example, permitting of the intimate mingling or recombination of substances, previously segregated, although during the dying stages of volcanic activity minerals like sulphur, cinnabar, etc., may be directly condensed and thus concentrated from a vaporous condition.
During the formation of the three main classes of rocks composing the earth's crust, the agencies leading to the concentration of various substances now of economic importance have to a great extent been different, and hence in a marked way the stones, ores, fuels, gems, etc., to be expected in each of the three classes of rocks, respectively, are distinct. Certain exceptions to this broad conclusion, however, arise from the fact that rocks belonging to each of the classes referred to may have been brought within the influence of the same or similar concentrating agencies and like results produced in each class.
Economic Importance of the Igneous Terranes.—The igneous rocks, as previously noted, are such as have cooled from fusion. On the cooling of magmas various minerals are formed, most commonly silicates, and except in a minor way in connection with the weaker stages of volcanic activity and the slow cooling of the rocks, there does not seem to be any marked tendency towards the concentration or segregation of metallic minerals or ores. Although igneous rocks do contain gold, silver, copper, etc., and a large variety of the rarer metals, they are widely disseminated. As is well known, however, igneous rocks are in some instances of value for the metallic mineral, gems, and ores associated with them, but in the great majority of instances at least, and as a rule, these minerals and ores are the result of subsequent changes and owe their origin mainly to deposition from heated, percolating water. Rich ore bodies frequently occur on the borders of igneous dikes, and in fissures and cavities in igneous rocks, but the process by which they have been formed is similar to that leading to the concentration of mineral matter in metamorphic rocks, and will be referred to later.
The igneous rocks themselves furnish desirable building stones, such as granite, diorite, porphyry, diabase, etc. With the exception of granite and the nearly related diorite, these have not as yet been extensively utilized in North America. Certain of the igneous rocks have been altered to serpentine, which on account of its pleasing green colour and the ease with which it can be cut and polished furnishes a stone valuable for interior uses. It is also employed, usually with a rough surface, in the construction of exterior walls of dwellings, gateways, etc. Large bodies of serpentine occur at a number of localities in the Atlantic mountains from Pennsylvania and Maryland northward, including eastern Canada, and also over extensive areas in the Pacific mountains, particularly in California, Washington, and Alaska.
The principal ores and minerals of commercial importance in the igneous rocks are native copper, as in northern Michigan; copper pyrites, as at Butte, Montana; gold, at many localities, including the Treadwell mine, Alaska; opal, which is mined on a small scale in Idaho and Washington. In practically all these instances, and numerous others that might be enumerated, the substances referred to have been deposited from solution in cavities in the rocks or have replaced other substances, and are due to what is termed above chemical concentration.
Economic Importance of the Sedimentary Terranes.—The sedimentary rocks are composed principally of fragmental material derived from the disintegration of older rocks transported and deposited mechanically, and resulting in the formation of sandstone, shale, etc., and of organically concentrated material, such as shells and corals, which form limestones. The deposits originating in these ways furnish excellent building stones, the principal classes being sandstones and limestones. These occur widely throughout North America, and in formations of all ages subsequent to the Archean. The sandstones were deposited near the shores of the seas, or in lakes, and the limestones principally in moderately deep oceans.
Sandstones occur largely in the Cambrian formation on the south shore of Lake Superior and about the borders of the Adirondack hills of New York. They are usually red or reddish-brown rocks, and their pleasing colours, durability, even grain, and the readiness with which they may be broken in any direction make them desirable building stones.
The Newark system, extending in detached areas from Nova Scotia to South Carolina, contains immense quantities of brown and gray sandstone, which have been extensively quarried, particularly in the Connecticut Valley, New Jersey, Pennsylvania, and Maryland, and largely used in Atlantic coast cities. The Carboniferous and Devonian sandstones, usually of a gray colour, of Pennsylvania, Ohio, and neighbouring States, are largely used in the cities of the interior portions of the United States. Extensive deposits of Mesozoic and Cenozoic sandstones occur throughout the Pacific mountains, and afford a practically unlimited supply of good building material, which as yet has been but little utilized. The colours of sandstones vary from bright red through brown-yellow to gray, and in some cases are nearly white, depending largely on the condition of the iron present. The red rocks are dyed with ferric oxide; the brownstones contain iron, frequently in the cementing material that unites the grains, in various stages of oxidation and hydration; the gray stones may also contain iron, but if present it is in union with organic matter, as the ferric carbonate, for example. The Cambrian and Newark sandstones are prevailingly of some shade of red, for the reason that not enough organic matter is present to change the iron to a carbonate.
The sandstones when of an even fine grain and not too hard, are suitable for sharpening tools, and large quantities of grindstones, whetstones, etc., are made from them, as on the Lake Huron shore of Michigan, in Ohio, etc. Other sandstones, practically free from iron, are used in the manufacture of glass. The best example of "glass sand" is the Sylvania sandstone of southeastern Michigan. Unconsolidated sand is largely used in mixing mortars and cements, for smoothing stones used for architectural and monumental purposes, as foundry sand in making moulds for casting, and many other ways. Seaward from where sand is being deposited we find in the present oceans that as a rule fine bluish or greenish mud occurs, and still farther seaward, except where coral-polyps thrive, usually at a distance of 100 miles or more from land, the bottom is composed of calcareous mud or ooze. The sand and mud are derived from the land, and if consolidated form sandstone and shale. The calcareous ooze is derived from the life of the sea, largely minute lime-secreting foraminifera, together with shells of molluscs, and in the vicinity of coral islands or reefs the hard parts of coral growth are added. That is, the calcareous oozes are formed by the concentration of calcium carbonate through the vital action of animals and to a less extent of plants. Such material, if consolidated, would form ordinary limestone.
In North America there are terranes scores of hundreds of miles across in various directions and hundreds and even thousands of feet thick that have been formed in the manner just indicated. From this mode of origin it may be truthfully inferred that limestone may have been formed during any age since organisms having the power of secreting calcium carbonate existed on the earth. The limestones of North America range in age from the Algonkian period to the present time, and are still being formed in the ocean and in a minor way in lakes.
Impure limestones, frequently coloured or clouded with red, due to ferric oxide, are quarried on an extensive scale in eastern Tennessee, and are used for decorative purposes. The Tennessee limestones referred to are of Paleozoic age; in Florida porous rocks, known as coquina, composed of imperfectly consolidated shells of living species of molluscs, are used in the construction of buildings. Gray limestones susceptible of a good polish occur in Ohio and neighbouring States and are utilized to some extent for columns and interior finish of buildings, but in the main the stones of this nature when employed for architectural purposes are rough-faced. Vast amounts of limestone suitable for masonry occur widely throughout the Mississippi Valley in many of the ranges of the Pacific mountains, especially in the United States and Mexico, and are also of immense thickness in the West Indies.
In many instances limestone has been metamorphosed, as will be described below, and converted into crystalline marble. Commercially, however, all limestone, whether crystalline or not, which is susceptible of a polish, is termed marble.
Under certain conditions calcium carbonate is concentrated at or near the earth's surface by chemical agencies, as about springs where calcareous tufa, travertine, etc., are precipitated, and in caverns where stalactites and stalagmites are formed. Stalagmite sheets are sometimes composed of variegated, laminated layers, and when polished produce a beautiful decorative stone which passes under the name of onyx marble. Deposits of this character of commercial importance occur in Arizona and Mexico.
Calcium carbonate concentrated in lakes through the combined action of chemical and vital agencies produces the so-called marl, now extensively utilized in the manufacture of Portland cement. In this mode of accumulation the calcium carbonate is dissolved by percolating waters from the rocks and soils and carried to lakes in solution; it is there precipitated largely through the vital action of certain algæ and deposited as a fine white ooze. Thousands of deposits of this nature, varying in extent up to several hundred acres, and having a depth of from a few feet to 40 and even 60 or more feet, occur in the portion of the continent covered with glacial drift, and especially in the States from New England to Minnesota. The reasons for the greater abundance of marl in this region than elsewhere are that the glacial drift is there highly calcareous, numerous lakes are present, and the climatic conditions are such as to favour the growth of certain aquatic plants, and especially the Characeæ or stoneworts, which have the property of eliminating calcium carbonate from ordinary lake waters.
The importance of the vital agencies in concentrating substances of economic value is illustrated by the manner in which coal, petroleum, and natural or rock-gas, etc., have been formed.
Land plants have the power, under the influence of light, of decomposing the carbon dioxide (carbonic-acid gas) of the air and fixing the carbon in their tissues, the oxygen being liberated and rendered available for animal respiration. Carbon is thus concentrated, and when plant remains accumulate and are preserved beneath water in swamps, a slow change takes place and peat is formed. The essential conditions for the accumulation of vegetable matter have been present on the earth ever since a land flora existed, and coal-beds occur at many different horizons. The earliest date at which land plants seem to have been sufficiently abundant to furnish material for coal-beds was the Carboniferous period. Although a similar flora existed during the preceding period, the Devonian, no coal-beds of workable thickness are known in the rocks of that age. Since the Carboniferous period coal has been found at many horizons in the sedimentary rocks, and peat is being accumulated at the present day.
The coal-fields of North America are more extensive than those of any other continent, excepting, perhaps, the at present but little known coal-bearing formations of Asia, and are distributed in temperate latitudes, from tide-water on the Atlantic to tide-water on the Pacific coasts, where the greatest commercial and intellectual development has been reached.
Coal of Carboniferous age occurs in large and valuable deposits in Nova Scotia and New Brunswick; there is a small area of graphitic anthracite, not now utilized, in Rhode Island; but the great fields are in Pennsylvania and the States southward to central Alabama, and westward to beyond the Mississippi. A detached coal-basin containing some 6,700 square miles, but a small part of which is productive, however, occurs in the central part of southern Michigan. Small coal-fields in Virginia and North Carolina, the first to be worked in America, are of Jura-Trias age and form part of the Newark system. Extensive fields of valuable coal of Mesozoic age, principally in the Laramie system, occur in New Mexico, Colorado, Wyoming, Montana, and still farther north along the same great belt in Canada.
Another highly valuable field of Mesozoic coal is now being extensively worked on Vancouver Island. The coals of the west side of the Pacific mountains, largely lignites, but in many instances of high grade and serviceable for steam coal, are mostly of Cenozoic age (Tertiary) and occur in California, Oregon, Washington, and Alaska. The distribution of the various coal-fields is indicated on the above map, and space will not be taken in describing their geographical relations.
Peat is present in innumerable swamps throughout the humid, temperate portion of the continent, especially from Louisiana and Florida northward, to the region about the Great Lakes and widely throughout Canada, but is at present of small commercial importance, although steps are being taken for its extensive utilization.
The most valuable of the coal deposits are of Carboniferous age, and lie to the east of the Rocky Mountains. The most of the coal is bituminous, or soft coal, used principally in generating steam and for manufacturing gas and coke. The exceptions occur in eastern Pennsylvania and in Rhode Island. These are considered as metamorphosed coals, although in the Pennsylvania region there is no evidence of the action of a high degree of heat. In the Rhode Island field the rocks associated with the coal are plainly metamorphic in character, and the coal has, in large part, been changed to graphitic anthracite.
That anthracite may be of any age, however, is indicated by the local changes that have occurred in Mesozoic and Cenozoic coals, where they have been penetrated by dikes and other varieties of intrusions, or have been altered by surface lava-flows. In such situations the coal has lost nearly all its volatile matter, and in composition and in certain instances, as in western Colorado, in physical character as well, is essentially an anthracite.
In addition to the various coal deposits referred to above there is a second series of organic compounds found stored in sedimentary rocks which consists of hydrocarbon. This series of substances includes natural or rock-gas, petroleum, maltha or semifluid hydrocarbon, and solid hydrocarbons, such as asphaltum, albertite, grahamite, ozokerite, etc. These substances are usually considered as being of organic origin and to have resulted from changes which take place in vegetable and animal tissues when buried and in most cases subjected to heavy pressure. A large part of the hydrocarbons referred to is thought to have been derived from animal organisms, an opinion which is sustained in an important manner by the fact that large stores of both petroleum and rock-gas have been discovered in rocks which were laid down before land vegetation is known to have existed. Marine algæ were present, however, so that it cannot be affirmed that the hydrocarbon of the earlier Paleozoic rocks came entirely from animal organisms. It is highly probable, however, that a large portion of the hydrocarbons stored in Paleozoic and later strata was derived from the animals whose hard parts occur so abundantly as fossils in the same or adjacent beds.