When a current is produced by a Daniell cell:
If, however, the copper sulphate solution be too weak, the water is decomposed instead of the copper sulphate, and hydrogen is deposited on the copper plate. This deposit of hydrogen lowers the voltage, hence care should be taken to maintain an adequate supply of copper sulphate.
The voltage of a Daniell cell varies from about 1.07 volt to 1.14 volt, according to the density of the copper sulphate solution and the amount of zinc sulphate present in the dilute sulphuric acid.
“Dry” Cells.—It is often necessary to use cells in places where there is considerable jarring or motion, as for automobile or marine ignition. The ordinary cell is not well adapted to this service on account of the liability of spilling the electrolyte, hence, the introduction of the so-called dry cell.
A dry cell is composed of two elements, usually zinc and carbon, and a liquid electrolyte. A zinc cup closed at the bottom and open at the top forms the negative electrode; this is lined with several layers of blotting paper or other absorbing material.
The positive electrode consists of a carbon rod placed in the center of the cup; the space between is filled with carbon—ground coke and dioxide of manganese mixed with an absorbent material. This filling is moistened with a liquid, generally sal-ammoniac. The top of the cell is closed with pitch to prevent leakage and evaporation. A binding post for holding the wire connections is attached to each electrode and each cell is placed in a paper box to protect the zincs of adjacent cells from coming into contact with each other when finally connected together to form a battery.
Points Relating to Dry Cells.—The following instructions on the care and operation of dry cells should be carefully noted and followed to get the best results:
Points Relating to the Care of Cells.—To get the best results from primary cells, they should receive proper attention and be maintained in good condition. The instructions here given should be carefully followed.
Cleanliness.—In the care of batteries, cleanliness is essential in order to secure best results. Zincs and coppers should be thoroughly cleaned every time a cell is taken out of use. The zinc, after being thoroughly cleaned, should be rubbed with a little mercury. This prevents local action. Porous cups should be soaked in clean water four or five hours and then wiped dry.
The terminals of each cell should be thoroughly cleansed and scraped bright so as to get good contact of the connecting wires and thus avoid extra resistance in the circuit.
Separating the Elements.—Obviously the positive and negative elements of a cell must not be in contact within the exciting fluid; they should be separated by a space of 3⁄8 to 1⁄2 inch. In the case of cells without porous cups, periodic attention must be given to ensure this condition being maintained.
Creeping.—As evaporation of the electrolyte takes place in a cell, it increases in strength, and crystals are left on the sides of the jar previously wetted by the solution, the action being very marked when the solution is a saturated one. The space between these crystals and the side of the jar acts as a number of capillary tubes, and draws up more liquid, which itself evaporates and deposits crystals above the former ones. So that finally the film of crystals passes over the edge of the jar and forms on the outside, thus making a kind of syphon which draws off the liquid. This action may, to a great extent, be prevented by warming the edges of the glass, or stoneware, jars, and of the porous pots, before the cells are made up, and dipping them while warm into some paraffin wax melted in warm oil, a precaution that should always be carried out when a dense solution of zinc sulphate is employed in the cell.
Amalgamated Zinc.—To “amalgamate” a piece of zinc, dip it into dilute sulphuric acid to clean its surface, then rub a little mercury over it by means of a piece of rag tied on to the end of a stick, and lastly, leave the zinc standing for a short time in a dish to catch the surplus mercury as it drains off.
The action of the amalgamated zinc is not well understood; by some it is considered that amalgamating the zinc prevents local currents by the amalgam mechanically covering up the impurities on the surface of the zinc and preventing their coming into contact with the liquid. By others it is thought that amalgamating the zinc protects it from local action by causing a film of hydrogen gas to adhere to it. This theory is based on the fact that while no action takes place when amalgamated zinc is placed in dilute sulphuric acid at ordinary atmospheric pressure, the creation of a vacuum above the liquid causes a rapid evolution of hydrogen, which, however, stops on the readmission of the air.
Amalgamating a zinc causes it to act as a somewhat more positive substance than before, therefore the voltage of a cell containing amalgamated zinc is slightly higher than that of a cell constructed with unamalgamated zinc.
The addition of a very small amount of zinc to mercury causes the mercury to act as if it were zinc alone, arising perhaps from the amalgam having the effect of bringing the zinc to the surface.
Battery Connections.—There are three methods of connecting cells to form a battery; they may be connected:
A series connection consists in joining the positive pole of one cell to the negative pole of the other, as shown in fig. 72; this adds the voltage of each cell.
Thus, connecting in series four cells of one and one-half volts each will give a total of six volts.
Fig. 73 illustrates a parallel or multiple connection; this is made by connecting the positive terminal of one cell with the positive terminal of another cell and the negative terminal of the first cell with the negative terminal of the second cell.
A paralleled or multiple connection adds the amperage of each cell; that is, the amperage of the battery will equal the sum of the amperage of each cell.
For instance, four cells of twenty-five amperes each would give a total of one hundred amperes when connected in parallel.
A series multiple connection, fig. 74, consists of two series sets of cells connected in parallel. In series multiple connections the voltage of each set of cells or battery must be equal, or the batteries will be weakened, hence each battery of a series multiple connection should contain the same number of cells.
The voltage of a series multiple connection is equal to the voltage of one cell multiplied by the number of cells in one battery, and the amperage is equal to the amperage of one cell multiplied by the number of batteries.
Fig. 75 shows an incorrect method of wiring in series multiple connection. If the circuit be open, the six cells, on account of having more electromotive force than the four cells, will overpower them and cause a current to flow in the direction indicated by the arrows until the pressure of the six cells has dropped to that of the four. This will use up the energy of the six cells, but will not weaken the four cell battery. This action can be corrected by placing a two-way switch in the circuit at the junction of the two negative terminals so that only one battery can be used at a time.
Bodies differ from each other in a striking manner in the freedom with which the electric current moves upon them. If the electric current be imparted to a certain portion of the surface of glass or wax, it will be confined strictly to that portion of the surface which originally receives it, by contact with the source of electricity; but if it be in like manner imparted to a portion of the surface of a metallic body, it will instantaneously diffuse itself uniformly over the entire extent of such metallic surface, exactly as water would spread itself uniformly over a level surface on which it is poured.[3]
Bodies in which the electric current moves freely are called conductors, and those in which it does not move freely are called insulators. There is, however, no substance so good a conductor as to be devoid of resistance, and no substance of such high resistance as to be a non-conductor.
Mention should be made here of the misuse of the word non-conductor; the so-called “non-conductors” are properly termed insulators.
The bodies named in the following series possess conducting power in different degrees in the order in which they stand, the most efficient conductor being first, and the most efficient insulator being last in the list.
| Good conductors (metals and alloys)[4] | Silver |
| Copper | |
| Aluminum | |
| Zinc | |
| Brass (according to composition) | |
| Platinum | |
| Iron | |
| Nickel | |
| Tin | |
| Lead | |
| German silver (copper 2 parts, zinc 1, nickel 1) | |
| Platinoid (German silver 49 parts, tungsten 1 part) | |
| Antimony | |
| Mercury | |
| Bismuth. | |
| Fair conductors | Charcoal and coke |
| Carbon | |
| Plumbago | |
| Acid solutions | |
| Sea water | |
| Saline solutions | |
| Metallic ores | |
| Living vegetable substances | |
| Moist earth. | |
| Partial conductors | Water |
| The body | |
| Flame | |
| Linen | |
| Cotton | |
| Mahogany | Dry woods |
| Pine | |
| Rosewood | |
| Lignum Vitæ } | |
| Teak | |
| Marble. | |
| Insulators, or so-called non-conductors. | Slate |
| Oils | |
| Porcelain | |
| Dry leather | |
| Dry paper | |
| Wool | |
| Silk | |
| Sealing wax | |
| Sulphur | |
| Resin | |
| Gutta-percha | |
| Shellac | |
| Ebonite | |
| Mica | |
| Jet | |
| Amber | |
| Paraffin wax | |
| Glass (varies with quality) | |
| Dry air. |
The earth is a good conductor; much difficulty is frequently experienced by the wires making contact with some substance that will conduct the electricity to the earth. This is called “grounding.”
Mode of Transmission.—The exact nature of electricity is not known, yet the laws governing its action, under various conditions are well understood, just as the laws of gravitation are known, although the constitution of gravity cannot be defined. Electricity, though not a substance, can be associated with matter, and its transmission requires energy. While it is neither a gas nor a liquid, its behavior sometimes is similar to that of a fluid so that it is said to “flow” through a conductor. This expression of flowing does not really mean that there is an actual movement in the wire, similar to the flow of water in a pipe, but is a convenient expression for the phenomena involved.
Effect of Heat.—The conducting power of bodies is affected in different ways by their temperature. In the metals it is diminished by elevation of temperature; but in all other bodies, and especially in liquids, it is augmented. Some substances which are insulators in the solid state, become conductors when fused.
Sir H. Davy found that glass raised to a red heat became a conductor; and that sealing wax, pitch, amber, shellac, sulphur, and wax, became conductors when liquefied by heat.
Heating Effect of the Current.—If a current of electricity pass over a conductor, no change in the heat condition of the conductor will be observed as long as its transverse section is so considerable as to leave sufficient space for the free passage of the current. But, if this thickness be diminished, or the quantity of electricity passing over it be augmented, or, in general, if the ratio of the electricity to the magnitude of the space afforded to it be increased, the conductor will be found to undergo an elevation of temperature, which will be greater, the greater the quantity of the electricity and the less the space supplied for its passage.
These heat effects are manifested in different degrees in different metals, according to their varying conducting powers.
The poorest conductors, such as platinum and iron, suffer much greater changes of temperature by the same charge than the best conductors, such as gold and copper.
The charge of electricity, which only elevates the temperature of one conductor a small amount, will sometimes render another incandescent, and will vaporize a third.
Insulators.—The term insulator is used in two ways: 1, as in insulating substance or medium, and 2, as a specially formed piece of some insulating material, such as glass, porcelain, etc. No substance has the power of absolutely preventing the passage of electric currents between conductors but many have sufficient insulating power for practical purposes. The properties to be desired in a good insulating material are:
Permanence is the most important quality, and is the one least easily attained. The power of resisting breakdown is a complex quality, for it is not solely dependent on mere puncturing pressure, but also on mechanical goodness, and to a certain extent on the insulation resistance. It cannot be easily determined by a simple laboratory test, but must be found by experience of actual service conditions.
Impregnating Compounds.—These are used for the treatment of fibrous materials. They increase the insulating properties of the fibrous materials, render them moisture proof and able to withstand the effect of heat with less rapid deterioration.
When wires or cables are to be used under water, they must be made impervious, and great care must be taken to prevent the water penetrating and thus injuring the insulation.
Water as a Conductor.—Water, whether in the liquid or vaporous form, is a conductor, though of an order greatly inferior to the metals. This fact is of great importance in electrical phenomena. The atmosphere contains, suspended in it, always more or less aqueous vapor, the presence of which impairs its insulating property.
The best insulators become less efficient if their surface be moist, the electricity passing by the conducting power of the moisture. This circumstance also shows why it is necessary to dry previously the bodies on which it is desired to develop electricity by friction.
Resistance is that property of a substance that opposes the flow of an electric current through it.
The practical electrician has to measure electrical resistance, electromotive forces, and the capacities of condensers. Each of these several quantities is measured by comparison with ascertained standards, the particular methods of comparison varying, however, to meet the circumstances of the case.
Ohm’s law states that the strength of a current due to an electromotive force falls off in proportion as the resistance in the circuit increases. It is therefore possible to compare two resistances with one another by finding out in what proportion each will cause the current of a constant battery to fall off.[5]
Silver is taken as the standard, with the percentage of 100, and the conductivity of all other metals is expressed in hundredths of the conductivity of silver.
Conductivity of Metals and Liquids.—The metals in general, conduct well, hence their resistance is small, but metal wires must not be too thin or too long, or they will resist too much, and permit only a feeble current to pass through them. The liquids in the battery do not conduct nearly so well as the metals, and different liquids have different resistances. Pure water will hardly conduct at all, unless the voltage be very high.
Salt and saltpetre dissolved in water are good conductors, and so are dilute acids, though strong sulphuric acid is a bad conductor. Gases are bad conductors.
Effect of Heat.—Another very important fact concerning the resistance of conductors is that the resistance in general increases with the temperature. While this fact is true regarding metals, it does not apply to non-metals. The resistance of different metals does not increase in the same proportion. Iron at 100 degrees C, has lost 39 per cent. of the conducting power it possessed at zero, while silver loses but 23 per cent.
Laws of Electrical Resistance.—Resistances in a circuit may be of two kinds:
1. Resistance of the conductors;
2. Resistance due to imperfect contact.
The latter kind of resistance is affected by pressure, for when the surfaces of two conductors are brought into more intimate contact the current passes more freely from one conductor to the other.
The following are the laws of the resistance of conductors:
1. The resistance of a conducting wire is proportional to its length.
If the resistance of a mile of telegraph wire be 13 ohms, that of fifty miles will be 50 × 13 = 650 ohms.
2. The resistance of a conducting wire is inversely proportional to the area of its cross section, and therefore in the usual round wires is inversely proportional to the square of its diameter.
Ordinary telegraph wire is about 1⁄6th of an inch thick; a wire twice as thick would conduct four times as well, having four times the area of cross section; hence an equal length of it would have only 1⁄4th the resistance.
3. The resistance of a conducting wire of given length and thickness depends upon the material of which it is made—that is, upon the specific resistance of the material.
Conductivity.—This is the inverse of resistance. The term expresses the capability of a substance to conduct the electric current.
If the symbol Y represent the conductivity of a substance, and I the current then:
and if R represent the resistance of a substance, then
Good conductors of heat are also good conductors of electricity.
Specific Conductivity.—The figure which indicates the relation between one substance and another as to their capacity to conduct electricity is called specific or relative conductivity. Taking the specific conductivity of silver as 100, that of pure copper is 96.
The specific resistance of a substance is the reverse of its relative conductivity. The specific resistance of a metal is generally expressed in millionths of an ohm as the resistance of a centimeter cube of that metal between opposite sides.
The following table gives the data for a few metals:
| Substance. | Specific Resistance in Microhms. | Specific Conductivity. |
| Silver | 1.609 | 100. |
| Copper | 1.642 | 96. |
| Gold | 2.154 | 74. |
| Iron (soft) | 9.827 | 16. |
| Lead | 19.847 | 8. |
| German Silver | 21.470 | 7.5 |
| Mercury (liquid) | 96.146 | 1.6 |
The specific resistance of copper is therefore:
Divided Circuits.—If a circuit be divided, as in fig. 83, into two branches at A, uniting again at B, the current will also be divided, part flowing through one branch and part through the other.
The relative strength of current in the two branches will be proportional to their conductivities.
This law will hold good for any number of branch resistances connected between A and B. Conductivity is, as shown before, the reciprocal of resistance.
EXAMPLE—If, in fig 83, the resistance of R = 10 ohms, and R′ = 20 ohms, the current through R will be to the current through R′ as 1⁄10 to 1⁄20; or, as 2:1, or, in other words, 2⁄3 of the total current will pass through R and 1⁄3 through R′. The joint resistance of the two branches between A and B will be less than the resistance of either branch singly, because the current has increased facilities for travel. In fact, the joint conductivity will be the sum of the two separate conductivities.
Taking again the resistance of R = 10 ohms and R′ = 20 ohms, the joint conductivity is
and the joint resistance is equal to the reciprocal[7] of 3⁄20
In most cases the resistance of the different branches will be alike. This simplifies the calculations considerably. Take, for instance, two branches of 100 ohms resistance each and find the joint resistance.
SOLUTION: 1⁄100 + 1⁄100 = 2⁄100; the reciprocal is 100⁄2 = 50 ohms, or, in other words, the joint resistance is one-half of the resistance of a single branch, and each branch, of course, will carry one-half of the total current in amperes.
With three branches of equal resistance, the joint resistance will be 1⁄3; with four branches 1⁄4; with 100 branches 1⁄100 of the resistance of a single branch.
If, for instance, the resistance of an incandescent lamp hot be 180 ohms, the joint resistance of 100 such lamps connected in multiple is
If the electromotive force of the system is to be, say 110 volts, then, according to Ohm’s law, the current for 100 lamps is:
giving for each lamp a current of
In the case of two branches only, the following rule may be applied also:
Multiply the two resistances and divide the product by their sum.
Written as a formula:
Again, assuming that R = 10 ohms and R′ = 20 ohms:
This rule cannot be employed for more than two branches at a time.
EXAMPLE—A current of 42 amperes flows through three conductors in parallel of 5, 10 and 20 ohms resistance respectively. Find the current in each conductor.
SOLUTION: Joint Conductance = 1⁄5 + 1⁄10 + 1⁄20 = 7⁄20.
Supposing the current to be divided into 7 parts, 4 of these parts would flow in the first conductor 2 in the second and 1 in the third.
The whole current is 42 amperes.
The production of electricity is simply a transformation of energy from one form into another, usually mechanical energy is changed into electrical energy and a dynamo is simply a device for effecting the transformation.
Prof. Fessenden truly remarks there are two independent properties of matter—gravity and inertia—and these give two ways of defining force and energy.
It should always be remembered that electricity is something real, although not easily defined. And then, too, while it is not matter and not energy, yet under proper conditions (it having the power of doing work) it is convenient to speak of its performances as electric energy. The following questions and answers, although few in number, may present the subject with clearness.
Ques. What is energy?
Ans. Energy is the capacity for doing work.
Steam under pressure is an example, a spring bent ready to be released is another form, again, water stored in an elevated tank has capacity for doing work. These examples illustrate potential energy, as distinguished from kinetic energy. Potential energy may be defined as energy due to position, and kinetic energy, as energy due to momentum.
Ques. What is matter?
Ans. Matter is anything occupying space, and which prevents other matter occupying the same space at the same time.
Ques. What name is given the smallest quantity of matter which can exist?
Ans. The atom.
An atom means that which cannot be cut, scratched, or changed in form and that cannot be affected by heat or cold or any known force; although inconceivably small, atoms possess a definite size and mass.
Ques. What is a molecule?
Ans. A molecule is composed of two or more atoms.
Ques. What is the behaviour of these minute bodies?
Ans. They are perpetually in motion, vibrating with incredible velocities.
Ques. Why at this point are definitions of energy and of matter most useful?
Ans. Because, as stated, all electric action is an exhibition of energy, and energy must act through matter as its medium.
Ques. What is the difference between electricity and magnetism?[8]
Ans. The ultimate nature of neither is known. There are, however, some differences. To sustain a current of electricity requires energy. To sustain magnetism requires no energy. A current of electricity is always accompanied by a magnetic field of peculiar form. Magnetism alone cannot produce electricity. Electricity can do work; but magnetism cannot in the same sense—and alike with electricity, neither can it exist without contact with matter.
Ques. How is energy transmitted from one part of a material substance to another?
Ans. Gradually and successively. It requires a medium and also time.
Ques. What is the principal use or function in mechanics of electricity?
Ans. It is purely that of transmission. It corresponds to ropes, shafts and fluids as a medium of conveying and translating power or work.
Ques. What is work?
Ans. Work is the overcoming of resistance through a certain distance.
As a quantity of water moving from a higher to a lower level will do work, so also will a quantity of electricity falling through a difference of potential.
Ques. How is work measured?
Ques. What is a foot pound?
Ans. The amount of work done in raising a weight of one pound one foot or the equivalent, overcoming a pressure of one pound through a distance of one foot.
Ques. What is the electrical unit of work?
Ans. The volt-coulomb.
A volt-coulomb of work is performed when one ampere of current flows for one second in a circuit whose resistance is one ohm, when the pressure is one volt.
The Ampere-Hour.—A gallon of water may be drawn from a hydrant in a minute, or in an hour; it is still one gallon. So in electricity, a given amount of the current, say one coulomb, may be obtained in a second or in an hour.
The ampere is the unit rate of flow.
What is called the electric current is simply the relation of any quantity of electricity passed to the time it is passing; that is