But, Mrs. B., though experience daily proves the advantage of cultivation, there is still a difficulty which I cannot get over. A certain quantity of elementary principles exist in nature, which it is not in the power of man either to augment or diminish. Of these principles you have taught us that both the animal and vegetable creation are composed. Now the more of them is taken up by the vegetable kingdom, the less, it would seem, will remain for animals; and, therefore, the more populous the earth becomes, the less it will produce.
MRS. B.
Your reasoning is very plausible; but experience every where contradicts the inference you would draw from it; for we find that the animal and vegetable kingdoms, instead of thriving, as you would suppose, at each other’s expense, always increase and multiply together. For you should recollect that animals can derive the elements of which they are formed only through the medium of vegetables. And you must allow that your conclusion would be valid only if every particle of the several principles that could possibly be spared from other purposes were employed in the animal and vegetable creations. Now we have reason to believe that a much greater proportion of these principles than is required for such purposes remains either in an elementary state, or engaged in a less useful mode of combination in the mineral kingdom. Possessed of such immense resources as the atmosphere and the waters afford us, for oxygen, hydrogen, and carbon, so far from being in danger of working up all our simple materials, we cannot suppose that we shall ever bring agriculture to such a degree of perfection as to require the whole of what these resources could supply.
Nature, however, in thus furnishing us with an inexhaustible stock of raw materials, leaves it in some measure to the ingenuity of man to appropriate them to its own purposes. But, like a kind parent, she stimulates him to exertion, by setting the example and pointing out the way. For it is on the operations of nature that all the improvements of art are founded. The art of agriculture consists, therefore, in discovering the readiest method of obtaining the several principles, either from their grand sources, air and water, or from the decomposition of organised bodies; and in appropriating them in the best manner to the purposes of vegetation.
EMILY.
But, among the sources of nutritive principles, I am surprised that you do not mention the earth itself, as it contains abundance of coals, which are chiefly composed of carbon.
MRS. B.
Though coals abound in carbon, they cannot, on account of their hardness and impermeable texture, be immediately subservient to the purposes of vegetation.
EMILY.
No; but by their combustion carbonic acid is produced; and this entering into various combinations on the surface of the earth, may, perhaps, assist in promoting vegetation.
MRS. B.
Probably it may in some degree; but at any rate the quantity of nourishment which vegetables may derive from that source can be but very trifling, and must entirely depend on local circumstances.
CAROLINE.
Perhaps the smoky atmosphere of London is the cause of vegetation being so forward and so rich in its vicinity?
MRS. B.
I rather believe that this circumstance proceeds from the very ample supply of manure, assisted, perhaps, by the warmth and shelter which the town affords. Far from attributing any good to the smoky atmosphere of London, I confess I like to anticipate the time when we shall have made such progress in the art of managing combustion, that every particle of carbon will be consumed, and the smoke destroyed at the moment of its production. We may then expect to have the satisfaction of seeing the atmosphere of London as clear as that of the country.—But to return to our subject: I hope that you are now convinced that we shall not easily experience a deficiency of nutritive elements to fertilise the earth, and that, provided we are but industrious in applying them to the best advantage by improving the art of agriculture, no limits can be assigned to the fruits that we may expect to reap from our labours.
CAROLINE.
Yes; I am perfectly satisfied in that respect, and I can assure you that I feel already much more interested in the progress and improvement of agriculture.
EMILY.
I have frequently thought that the culture of the land was not considered as a concern of sufficient importance. Manufactures always take the lead; and health and innocence are frequently sacrificed to the prospect of a more profitable employment. It has often grieved me to see the poor manufacturers crowded together in close rooms, and confined for the whole day to the most uniform and sedentary employment, instead of being engaged in that innocent and salutary kind of labour, which Nature seems to have assigned to man for the immediate acquirement of comfort, and for the preservation of his existence. I am sure that you agree with me in thinking so, Mrs. B.?
MRS. B.
I am entirely of your opinion, my dear, in regard to the importance of agriculture; but as the conveniences of life, which we are all enjoying, are not derived merely from the soil, I am far from wishing to depreciate manufactures. Besides, as the labour of one man is sufficient to produce food for several, those whose industry is not required in tillage must do something in return for the food that is provided for them. They exchange, consequently, the accommodations for the necessaries of life. Thus the carpenter and the weaver lodge and clothe the peasant, who supplies them with their daily bread. The greater stock of provisions, therefore, which the husbandman produces, the greater is the quantity of accommodation which the artificer prepares. Such are the happy effects which naturally result from civilised society. It would be wiser, therefore, to endeavour to improve the situation of those who are engaged in manufactures, than to indulge in vain declamations on the hardships to which they are too frequently exposed.
But we must not yet take our leave of the subject of agriculture; we have prepared the soil, it remains for us now to sow the seed. In this operation we must be careful not to bury it too deep in the ground, as the access of air is absolutely necessary to its germination; the earth must, therefore, lie loose and light over it, in order that the air may penetrate. Hence the use of ploughing and digging, harrowing and raking, &c. A certain degree of heat and moisture, such as usually takes place in the spring, is likewise necessary.
CAROLINE.
One would imagine you were going to describe the decomposition of an old plant, rather than the formation of a new one; for you have enumerated all the requisites of fermentation.
MRS. B.
Do you forget, my dear, that the young plant derives its existence from the destruction of the seed, and that it is actually by the saccharine fermentation that the latter is decomposed?
CAROLINE.
True; I wonder that I did not recollect that. The temperature and moisture required for the germination of the seed is then employed in producing the saccharine fermentation within it?
MRS. B.
Certainly. But, in order to understand the nature of germination, you should be acquainted with the different parts of which the seed is composed. The external covering or envelope contains, besides the germ of the future plant, the substance which is to constitute its first nourishment; this substance, which is called the parenchyma, consists of fecula, mucilage, and oil, as we formerly observed.
The seed is generally divided into two compartments, called lobes, or cotyledons, as is exemplified by this bean (Plate XV. Fig. 1.)—the dark-coloured kind of string which divides the lobes is called the radicle, as it forms the root of the plant, and it is from a contiguous substance, called plumula, which is enclosed within the lobes, that the stem arises. The figure and size of the seed depend very much upon the cotyledons; these vary in number in different seeds; some have only one, as wheat, oats, barley, and all the grasses; some have three, others six. But most seeds, as, for instance, all the varieties of beans, have two cotyledons. When the seed is buried in the earth, at any temperature above 40 degrees, it imbibes water, which softens and swells the lobes; it then absorbs oxygen, which combines with some of its carbon, and is returned in the form of carbonic acid. This loss of carbon increases the comparative proportion of hydrogen and oxygen in the seed, and excites the saccharine fermentation, by which the parenchymatous matter is converted into a kind of sweet emulsion. In this form it is carried into the radicle by vessels appropriated to that purpose; and in the mean time, the fermentation having caused the seed to burst, the cotyledons are rent asunder, the radicle strikes into the ground and becomes the root of the plant, and hence the fermented liquid is conveyed to the plumula, whose vessels have been previously distended by the heat of the fermentation. The plumula being thus swelled, as it were, by the emulsive fluid, raises itself and springs up to the surface of the earth, bearing with it the cotyledons, which, as soon as they come in contact with the air, spread themselves, and are transformed into leaves.—If we go into the garden, we shall probably find some seeds in the state which I have described—
Vol. II. p. 250
see text and caption
Fig. 1 & 2.
A.B Cotyledons.
C Envelope.
D Radicle.
Fig. 3.
A.B Cotyledons.
C Plumula.
D Radicle.
Fig. 4.
A.B. Cotyledons.
C Plumula.
D Radicle.
Larger view (complete Plate)
EMILY.
Here are some lupines that are just making their appearance above ground.
MRS. B.
We shall take up several of them to observe their different degrees of progress in vegetation. Here is one that has but recently burst its envelope—do you see the little radicle striking downwards? (Plate XV. Fig. 2.) In this the plumula is not yet visible. But here is another in a greater state of forwardness—the plumula, or stem, has risen out of the ground, and the cotyledons are converted into seed leaves. (Plate XV. Fig. 3.)
CAROLINE.
These leaves are very thick and clumsy, and unlike the other leaves, which I perceive are just beginning to appear.
MRS. B.
It is because they retain the remains of the parenchyma, with which they still continue to nourish the young plant, as it has not yet sufficient roots and strength to provide for its sustenance from the soil.—But, in this third lupine (Plate XV. Fig. 4.), the radicle had sunk deep into the earth, and sent out several shoots, each of which is furnished with a mouth to suck up nourishment from the soil; the function of the original leaves, therefore, being no longer required, they are gradually decaying, and the plumula is become a regular stem, shooting out small branches, and spreading its foliage.
EMILY.
There seems to be a very striking analogy between a seed and an egg; both require an elevation of temperature to be brought to life; both at first supply with aliment the organised being which they produce; and as soon as this has attained sufficient strength to procure its own nourishment, the egg-shell breaks, whilst in the plant the seed-leaves fall off.
MRS. B.
There is certainly some resemblance between these processes; and when you become acquainted with animal chemistry, you will frequently be struck with its analogy to that of the vegetable kingdom.
As soon as the young plant feeds from the soil, it requires the assistance of leaves, which are the organs by which it throws off its super-abundant fluid; this secretion is much more plentiful in the vegetable than in the animal creation, and the great extent of surface of the foliage of plants is admirably calculated for carrying it on in sufficient quantities. This transpired fluid consists of little more than water. The sap, by this process, is converted into a liquid of greater consistence, which is fit to be assimilated to its several parts.
EMILY.
Vegetation, then, must be essentially injured by destroying the leaves of the plant?
MRS. B.
Undoubtedly; it not only diminishes the transpiration, but also the absorption by the roots; for the quantity of sap absorbed is always in proportion to the quantity of fluid thrown off by transpiration. You see, therefore, the necessity that a young plant should unfold its leaves as soon as it begins to derive its nourishment from the soil; and, accordingly, you will find that those lupines which have dropped their seed-leaves, and are no longer fed by the parenchyma, have spread their foliage, in order to perform the office just described.
But I should inform you that this function of transpiration seems to be confined to the upper surface of the leaves, whilst, on the contrary, the lower surface, which is more rough and uneven, and furnished with a kind of hair or down, is destined to absorb moisture, or such other ingredients as the plant derives from the atmosphere.
As soon as a young plant makes its appearance above ground, light, as well as air, becomes necessary to its preservation. Light is essential to the development of the colours, and to the thriving of the plant. You may have often observed what a predilection vegetables have for the light. If you make any plants grow in a room, they all spread their leaves, and extend their branches towards the windows.
CAROLINE.
And many plants close up their flowers as soon as it is dark.
EMILY.
But may not this be owing to the cold and dampness of the evening air?
MRS. B.
That does not appear to be the case; for in a course of curious experiments, made by Mr. Senebier, of Geneva, on plants which he reared by lamp-light, he found that the flowers closed their petals whenever the lamps were extinguished.
EMILY.
But pray, why is air essential to vegetation, plants do not breathe it like animals?
MRS. B.
At least not in the same manner; but they certainly derive some principles from the atmosphere, and yield others to it. Indeed, it is chiefly owing to the action of the atmosphere and the vegetable kingdom on each other, that the air continues always fit for respiration. But you will understand this better when I have explained the effect of water on plants.
I have said that water forms the chief nourishment of plants; it is the basis not only of the sap, but of all the vegetable juices. Water is the vehicle which carries into the plant the various salts and other ingredients required for the formation and support of the vegetable system. Nor is this all; part of the water itself is decomposed by the organs of the plant; the hydrogen becomes a constituent part of oil, of extract, of colouring matter, &c. whilst a portion of the oxygen enters into the formation of mucilage, of fecula, of sugar, and of vegetable acids. But the greater part of the oxygen, proceeding from the decomposition of the water, is converted into a gaseous state by the caloric disengaged from the hydrogen during its condensation in the formation of the vegetable materials. In this state the oxygen is transpired by the leaves of plants when exposed to the sun’s rays. Thus you find that the decomposition of water, by the organs of the plant, is not only a means of supplying it with its chief ingredient, hydrogen, but at the same time of replenishing the atmosphere with oxygen, a principle which requires continual renovation, to make up for the great consumption of it occasioned by the numerous oxygenations, combustions, and respirations, that are constantly taking place on the surface of the globe.
EMILY.
What a striking instance of the harmony of nature.
MRS. B.
And how admirable the design of Providence, who makes every different part of the creation thus contribute to the support and renovation of each other!
But the intercourse of the vegetable and animal kingdoms through the medium of the atmosphere extends still further. Animals, in breathing, not only consume the oxygen of the air, but load it with carbonic acid, which, if accumulated in the atmosphere, would, in a short time, render it totally unfit for respiration. Here the vegetable kingdom again interferes; it attracts and decomposes the carbonic acid, retains the carbon for its own purposes, and returns the oxygen for ours.
CAROLINE.
How interesting this is! I do not know a more beautiful illustration of the wisdom which is displayed in the laws of nature.
MRS. B.
Faint and imperfect as are the ideas which our limited perceptions enable us to form of divine wisdom, still they cannot fail to inspire us with awe and admiration. What, then, would be our feelings, were the complete system of nature at once displayed before us! So magnificent a scene would probably be too great for our limited and imperfect comprehension, and it is no doubt among the wise dispensations of Providence, to veil the splendour of a glory with which we should be overpowered. But it is well suited to the nature of a rational being to explore, step by step, the works of the creation, to endeavour to connect them into harmonious systems; and, in a word, to trace in the chain of beings, the kindred ties and benevolent design which unites its various links, and secure its preservation.
CAROLINE.
But of what nature are the organs of plants which are endued with such wonderful powers?
MRS. B.
They are so minute that their structure, as well as the mode in which they perform their functions, generally elude our examination; but we may consider them as so many vessels or apparatus appropriated to perform, with the assistance of the principle of life, certain chemical processes, by means of which these vegetable compounds are generated. We may, however, trace the tannin, resins, gum, mucilage, and some other vegetable materials, in the organised arrangement of plants, in which they form the bark, the wood, the leaves, flowers, and seeds.
The bark is composed of the epidermis, the parenchyma, and the cortical layers.
The epidermis is the external covering of the plant. It is a thin transparent membrane, consisting of a number of slender fibres, crossing each other, and forming a kind of net-work. When of a white glossy nature, as in several species of trees, in the stems of corn and of seeds, it is composed of a thin coating of siliceous earth, which accounts for the strength and hardness of those long and slender stems. Sir H. Davy was led to the discovery of the siliceous nature of the epidermis of such plants, by observing the singular phenomenon of sparks of fire emitted by the collision of ratan canes with which two boys were fighting in a dark room. On analysing the epidermis of the cane, he found it to be almost entirely siliceous.
CAROLINE.
With iron then, a cane, I suppose, will strike fire very easily?
MRS. B.
I understand that it will.—In ever-greens the epidermis is mostly resinous, and in some few plants is formed of wax. The resin, from its want of affinity for water, tends to preserve the plant from the destructive effects of violent rains, severe climates, or inclement seasons, to which this species of vegetables is peculiarly exposed.
EMILY.
Resin must preserve wood just like a varnish, as it is the essential ingredient of varnishes?
MRS. B.
Yes; and by this means it prevents likewise all unnecessary expenditure of moisture.
The parenchyma is immediately beneath the epidermis; it is that green rind which appears when you strip a branch of any tree or shrub of its external coat of bark. The parenchyma is not confined to the stem or branches, but extends over every part of the plant. It forms the green matter of the leaves, and is composed of tubes filled with a peculiar juice.
The cortical layers are immediately in contact with the wood; they abound with tannin and gallic acid, and consist of small vessels through which the sap descends after being elaborated in the leaves. The cortical layers are annually renewed, the old bark being converted into wood.
EMILY.
But through what vessels does the sap ascend?
MRS. B.
That function is performed by the tubes of the alburnum, or wood, which is immediately beneath the cortical layers. The wood is composed of woody fibre, mucilage, and resin. The fibres are disposed in two ways; some of them longitudinally, and these form what is called the silver grain of the wood. The others, which are concentric, are called the spurious grain. These last are disposed in layers, from the number of which the age of the tree may be computed, a new one being produced annually by the conversion of the bark into wood. The oldest, and consequently most internal part of the alburnum, is called heart-wood; it appears to be dead, at least no vital functions are discernible in it. It is through the tubes of the living alburnum that the sap rises. These, therefore, spread into the leaves, and there communicate with the extremities of the vessels of the cortical layers, into which they pour their contents.
CAROLINE.
Of what use, then, are the tubes of the parenchyma, since neither the ascending nor descending sap passes through them?
MRS. B.
They are supposed to perform the important function of secreting from the sap the peculiar juices from which the plant more immediately derives its nourishment. These juices are very conspicuous, as the vessels which contain them are much larger than those through which the sap circulates. The peculiar juices of plants differ much in their nature, not only in different species of vegetables, but frequently in different parts of the same individual plant: they are sometimes saccharine, as in the sugar-cane, sometimes resinous, as in firs and evergreens, sometimes of a milky appearance, as in the laurel.
EMILY.
I have often observed, that in breaking a young shoot, or in bruising a leaf of laurel, a milky juice will ooze out in great abundance.
MRS. B.
And it is by making incisions in the bark that pitch, tar, and turpentine are obtained from fir-trees. The durability of this species of wood is chiefly owing to the resinous nature of its peculiar juices. The volatile oils have, in a great measure, the same preservative effects, as they defend the parts, with which they are connected, from the attack of insects. This tribe seems to have as great an aversion to perfumes, as the human species have delight in them. They scarcely ever attack any odoriferous parts of plants, and it is not uncommon to see every leaf of a tree destroyed by a blight, whilst the blossoms remain untouched. Cedar, sandal, and all aromatic woods, are on this account of great durability.
EMILY.
But the wood of the oak, which is so much esteemed for its durability, has, I believe, no smell. Does it derive this quality from its hardness alone?
MRS. B.
Not entirely; for the chesnut, though considerably harder and firmer than the oak, is not so lasting. The durability of the oak is, I believe, in a great measure owing to its having very little heart-wood, the alburnum preserving its vital functions longer than in other trees.
CAROLINE.
If incisions are made into the alburnum and cortical layers, may not the ascending and descending sap be procured in the same manner as the peculiar juice is from the vessels of the parenchyma?
MRS. B.
Yes; but in order to obtain specimens of these fluids, in any quantity, the experiment must be made in the spring, when the sap circulates with the greatest energy. For this purpose a small bent glass tube should be introduced into the incision, through which the sap may flow without mixing with any of the other juices of the tree. From the bark the sap will flow much more plentifully than from the wood, as the ascending sap is much more liquid, more abundant, and more rapid in its motion than that which descends; for the latter having been deprived by the operation of the leaves of a considerable part of its moisture, contains a much greater proportion of solid matter, which retards its motion. It does not appear that there is any excess of descending sap, as none ever exudes from the roots of plants; this process, therefore, seems to be carried on only in proportion to the wants of the plant, and the sap descends no further, and in no greater quantity, than is required to nourish the several organs. Therefore, though the sap rises and descends in the plant, it does not appear to undergo a real circulation.
The last of the organs of plants is the flower, or blossom, which produces the fruits and seed. These may be considered as the ultimate purpose of nature in the vegetable creation. From fruits and seeds animals derive both a plentiful source of immediate nourishment, and an ample provision for the reproduction of the same means of subsistence.
The seed which forms the final product of mature plants, we have already examined as constituting the first rudiments of future vegetation.
These are the principal organs of vegetation, by means of which the several chemical processes which are carried on during the life of the plant are performed.
EMILY.
But how are the several principles which enter into the composition of vegetables so combined by the organs of the plant as to be converted into vegetable matter?
MRS. B.
By chemical processes, no doubt; but the apparatus in which they are performed is so extremely minute as completely to elude our examination. We can form an opinion, therefore, only by the result of these operations. The sap is evidently composed of water, absorbed by the roots, and holding in solution the various principles which it derives from the soil. From the roots the sap ascends through the tubes of the alburnum into the stem, and thence branches out to every extremity of the plant. Together with the sap circulates a certain quantity of carbonic acid, which is gradually disengaged from the former by the internal heat of the plant.
CAROLINE.
What! have vegetables a peculiar heat, analogous to animal heat?
MRS. B.
It is a circumstance that has long been suspected; but late experiments have decided beyond a doubt that vegetable heat is considerably above that of unorganised matter in winter, and below it in summer. The wood of a tree is about sixty degrees, when the thermometer is seventy or eighty degrees. And the bark, though so much exposed, is seldom below forty in winter.
It is from the sap, after it has been elaborated by the leaves, that vegetables derive their nourishment; in its progress through the plant from the leaves to the roots, it deposits in the several sets of vessels with which it communicates, the materials on which the growth and nourishment of each plant depends. It is thus that the various peculiar juices, saccharine, oily, mucous, acid, and colouring, are formed; as also the more solid parts, fecula, woody fibre, tannin, resins, concrete salts; in a word, all the immediate materials of vegetables, as well as the organised parts of plants, which latter, besides the power of secreting these from the sap for the general purpose of the plant, have also that of applying them to their own particular nourishment.
EMILY.
But why should the process of vegetation take place only at one season of the year, whilst a total inaction prevails during the other?
MRS. B.
Heat is such an important chemical agent, that its effect, as such, might perhaps alone account for the impulse which the spring gives to vegetation. But, in order to explain the mechanism of that operation, it has been supposed that the warmth of the spring dilates the vessels of plants, and produces a kind of vacuum, into which the sap (which had remained in a state of inaction in the trunk during the winter) rises: this is followed by the ascent of the sap contained in the roots, and room is thus made for fresh sap, which the roots, in their turn, pump up from the soil. This process goes on till the plant blossoms and bears fruit, which terminates its summer career: but when the cold weather sets in, the fibres and vessels contract, the leaves wither, and are no longer able to perform their office of transpiration; and, as this secretion stops, the roots cease to absorb sap from the soil. If the plant be an annual, its life then terminates; if not, it remains in a state of torpid inaction during the winter; or the only internal motion that takes place is that of a small quantity of resinous juice, which slowly rises from the stem into the branches, and enlarges their buds during the winter.
CAROLINE.
Yet, in evergreens, vegetation must continue throughout the year.
MRS. B.
Yes; but in winter it goes on in a very imperfect manner, compared to the vegetation of spring and summer.
We have dwelt much longer on the history of vegetable chemistry than I had intended; but we have at length, I think, brought the subject to a conclusion.
CAROLINE.
I rather wonder that you did not reserve the account of the fermentations for the conclusion; for the decomposition of vegetables naturally follows their death, and can hardly, it seems, be introduced with so much propriety at any other period.
MRS. B.
It is difficult to determine at what point precisely it may be most eligible to enter on the history of vegetation; every part of the subject is so closely connected, and forms such an uninterrupted chain, that it is by no means easy to divide it. Had I begun with the germination of the seed, which, at first view, seems to be the most proper arrangement, I could not have explained the nature and fermentation of the seed, or have described the changes which manure must undergo, in order to yield the vegetable elements. To understand the nature of germination, it is necessary, I think, previously to decompose the parent plant, in order to become acquainted with the materials required for that purpose. I hope, therefore, that, upon second consideration, you will find that the order which I have adopted, though apparently less correct, is in fact the best calculated for the elucidation of the subject.
CONVERSATION XXIII.
ON THE COMPOSITION OF ANIMALS.
----
MRS. B.
We are now come to the last branch of chemistry, which comprehends the most complicated order of compound beings. This is the animal creation, the history of which cannot but excite the highest degree of curiosity and interest, though we often fail in attempting to explain the laws by which it is governed.
EMILY.
But since all animals ultimately derive their nourishment from vegetables, the chemistry of this order of beings must consist merely in the conversion of vegetable into animal matter.
MRS. B.
Very true; but the manner in which this is effected is, in a great measure, concealed from our observation. This process is called animalisation, and is performed by peculiar organs. The difference of the animal and vegetable kingdoms does not however depend merely on a different arrangement of combinations. A new principle abounds in the animal kingdom, which is but rarely and in very small quantities found in vegetables; this is nitrogen. There is likewise in animal substances a greater and more constant proportion of phosphoric acid, and other saline matters. But these are not essential to the formation of animal matter.
CAROLINE.
Animal compounds contain, then, four fundamental principles; oxygen, hydrogen, carbon, and nitrogen?
MRS. B.
Yes; and these form the immediate materials of animals, which are gelatine, albumen, and fibrine.
EMILY.
Are those all? I am surprised that animals should be composed of fewer kinds of materials than vegetables; for they appear much more complicated in their organisation.
MRS. B.
Their organisation is certainly more perfect and intricate, and the ingredients that occasionally enter into their composition are more numerous. But notwithstanding the wonderful variety observable in the texture of the animal organs, we find that the original compounds, from which all the varieties of animal matter are derived, may be reduced to the three heads just mentioned. Animal substances being the most complicated of all natural compounds, are most easily susceptible of decomposition, as the scale of attractions increases in proportion to the number of constituent principles. Their analysis is, however, both difficult and imperfect; for as they cannot be examined in their living state, and are liable to alteration immediately after death, it is probable that, when submitted to the investigation of a chemist, they are always more or less altered in their combinations and properties, from what they were, whilst they made part of the living animal.
EMILY.
The mere diminution of temperature, which they experience by the privation of animal heat, must, I should suppose, be sufficient to derange the order of attractions that existed during life.
MRS. B.
That is one of the causes, no doubt: but there are many other circumstances which prevent us from studying the nature of living animal substances. We must therefore, in a considerable degree, confine our researches to the phenomena of these compounds in their inanimate state.
These three kinds of animal matter, gelatine, albumen, and fibrine, form the basis of all the various parts of the animal system; either solid, as the skin, flesh, nerves, membranes, cartilages, and bones; or fluid, as blood, chyle, milk, mucus, the gastric and pancreatic juices, bile, perspiration, saliva, tears, &c.
CAROLINE.
Is it not surprising that so great a variety of substances, and so different in their nature, should yet all arise from so few materials, and from the same original elements?
MRS. B.
The difference in the nature of various bodies depends, as I have often observed to you, rather on their state of combination, than on the materials of which they are composed. Thus, in considering the chemical nature of the creation in a general point of view, we observe that it is throughout composed of a very small number of elements. But when we divide it into the three kingdoms, we find that, in the mineral, the combinations seem to result from the union of elements casually brought together; whilst in the vegetable and animal kingdoms, the attractions are peculiarly and regularly produced by appropriate organs, whose action depends on the vital principle. And we may further observe, that by means of certain spontaneous changes and decompositions, the elements of one kind of matter become subservient to the reproduction of another; so that the three kingdoms are intimately connected, and constantly contributing to the preservation of each other.
EMILY.
There is, however, one very considerable class of elements, which seems to be confined to the mineral kingdom: I mean metals.
MRS. B.
Not entirely; they are found, though in very minute quantities, both in the vegetable and animal kingdoms. A small portion of earths and sulphur enters also into the composition of organised bodies. Phosphorus, however, is almost entirely confined to the animal kingdom; and nitrogen, but with few exceptions, is extremely scarce in vegetables.
Let us now proceed to examine the nature of the three principal materials of the animal system.
Gelatine, or jelly, is the chief ingredient of skin, and of all the membranous parts of animals. It may be obtained from these substances, by means of boiling water, under the forms of glue, size, isinglass, and transparent jelly.
CAROLINE.
But these are of a very different nature; they cannot therefore be all pure gelatine.
MRS. B.
Not entirely, but very nearly so. Glue is extracted from the skin of animals. Size is obtained either from skin in its natural state, or from leather. Isinglass is gelatine procured from a particular species of fish; it is, you know, of this substance that the finest jelly is made, and this is done by merely dissolving the isinglass in boiling water, and allowing the solution to congeal.
EMILY.
The wine, lemon, and spices, are, I suppose, added only to flavour the jelly?
MRS. B.
Exactly so.
CAROLINE.
But jelly is often made of hartshorn shavings, and of calves’ feet; do these substances contain gelatine?
MRS. B.
Yes. Gelatine may be obtained from almost any animal substance, as it enters more or less into the composition of all of them. The process for obtaining it is extremely simple, as it consists merely in boiling the substance that contains it with water. The gelatine dissolves in water, and may be attained of any degree of consistence or strength, by evaporating this solution. Bones in particular produce it very plentifully, as they consist of phosphat of lime combined or cemented by gelatine. Horns, which are a species of bone, will yield abundance of gelatine. The horns of the hart are reckoned to produce gelatine of the finest quality; they are reduced to the state of shavings in order that the jelly may be more easily extracted by the water. It is of hartshorn shavings that the jellies for invalids are usually made, as they are of very easy digestion.
CAROLINE.
It appears singular that hartshorn, which yields such a powerful ingredient as ammonia, should at the same time produce so mild and insipid a substance as jelly?
MRS. B.
And (what is more surprising) it is from the gelatine of bones that ammonia is produced. You must observe, however, that the processes by which these two substances are obtained from bones are very different. By the simple action of water and heat, the gelatine is separated; but in order to procure the ammonia, or what is commonly called hartshorn, the bones must be distilled, by which means the gelatine is decomposed, and hydrogen and nitrogen combined in the form of ammonia. So that the first operation is a mere separation of ingredients, whilst the second requires a chemical decomposition.
CAROLINE.
But when jelly is made from hartshorn shavings, what becomes of the phosphat of lime which constitutes the other part of bones?
MRS. B.
It is easily separated by straining. But the jelly is afterwards more perfectly purified, and rendered transparent, by adding white of egg, which being coagulated by heat, rises to the surface along with any impurities.
EMILY.
I wonder that bones are not used by the common people to make jelly; a great deal of wholesome nourishment, might, I should suppose, be procured from them, though the jelly would perhaps not be quite so good as if made from hartshorn shavings?
MRS. B.
There is a prejudice among the poor against a species of food that is usually thrown to the dogs; and as we cannot expect them to enter into chemical considerations, it is in some degree excusable. Besides, it requires a prodigious quantity of fuel to dissolve bones and obtain the gelatine from them.
The solution of bones in water is greatly promoted by an accumulation of heat. This may be effected by means of an extremely strong metallic vessel, called Papin’s digester, in which the bones and water are enclosed, without any possibility of the steam making its escape. A heat can thus be applied much superior to that of boiling water; and bones, by this means, are completely reduced to a pulp. But the process still consumes too much fuel to be generally adopted among the lower classes.
CAROLINE.
And why should not a manufacture be established for grinding or macerating bones, or at least for reducing them to the state of shavings, when I suppose they would dissolve as readily as hartshorn shavings?
MRS. B.
They could not be collected clean for such a purpose, but they are not lost, as they are used for making hartshorn and sal ammoniac; and such is the superior science and industry of this country, that we now send sal ammoniac to the Levant, though it originally came to us from Egypt.
EMILY.
When jelly is made of isinglass, does it leave no sediment?
MRS. B.
No; nor does it so much require clarifying, as it consists almost entirely of pure gelatine, and any foreign matter that is mixed with it, is thrown off during the boiling in the form of scum.—These are processes which you may see performed in great perfection in the culinary laboratory, by that very able and most useful chemist the cook.
CAROLINE.
To what an immense variety of purposes chemistry is subservient!
EMILY.
It appears, in that respect, to have an advantage over most other arts and sciences; for these, very often, have a tendency to confine the imagination to their own particular object, whilst the pursuit of chemistry is so extensive and diversified, that it inspires a general curiosity, and a desire of enquiring into the nature of every object.
CAROLINE.
I suppose that soup is likewise composed of gelatine; for, when cold, it often assumes the consistence of jelly?
MRS. B.
Not entirely; for though soups generally contain a quantity of gelatine, the most essential ingredient is a mucous or extractive matter, a peculiar animal substance, very soluble in water, which has a strong taste, and is more nourishing than gelatine. The various kinds of portable soup consist of this extractive matter in a dry state, which, in order to be made into soup, requires only to be dissolved in water.
Gelatine, in its solid state, is a semiductile transparent substance, without either taste or smell.—When exposed to heat, in contact with air and water, it first swells, then fuses, and finally burns. You may have seen the first part of this operation performed in the carpenter’s glue-pot.
CAROLINE.
But you said that gelatine had no smell, and glue has a very disagreeable one.
MRS. B.
Glue is not pure gelatine; as it is not designed for eating, it is prepared without attending to the state of the ingredients, which are more or less contaminated by particles that have become putrid.
Gelatine may be precipitated from its solution in water by alcohol.—We shall try this experiment with a glass of warm jelly.—You see that the gelatine subsides by the union of the alcohol and the water.
EMILY.
How is it, then, that jelly is flavoured with wine, without producing any precipitation?
MRS. B.
Because the alcohol contained in wine is already combined with water, and other ingredients, and is therefore not at liberty to act upon the jelly as when in its separate state. Gelatine is soluble both in acids and in alkalies; the former, you know, are frequently used to season jellies.
CAROLINE.
Among the combinations of gelatine we must not forget one which you formerly mentioned; that with tannin, to form leather.
MRS. B.
True; but you must observe that leather can be produced only by gelatine in a membranous state; for though pure gelatine and tannin will produce a substance chemically similar to leather, yet the texture of the skin is requisite to make it answer the useful purposes of that substance.
The next animal substance we are to examine is albumen; this, although constituting a part of most of the animal compounds, is frequently found insulated in the animal system; the white of egg, for instance, consists almost entirely of albumen; the substance that composes the nerves, the serum, or white part of the blood, and the curds of milk, are little else than albumen variously modified.
In its most simple state, albumen appears in the form of a transparent viscous fluid, possessed of no distinct taste or smell; it coagulates at the low temperature of 165 degrees, and, when once solidified, it will never return to its fluid state.
Sulphuric acid and alcohol are each of them capable of coagulating albumen in the same manner as heat, as I am going to show you.
EMILY.
Exactly so.—Pray, Mrs. B., what kind of action is there between albumen and silver? I have sometimes observed, that if the spoon with which I eat an egg happens to be wetted, it becomes tarnished.
MRS. B.
It is because the white of egg (and, indeed, albumen in general) contains a little sulphur, which, at the temperature of an egg just boiled, will decompose the drop of water that wets the spoon, and produce sulphurated hydrogen gas, which has the property of tarnishing silver.
We may now proceed to fibrine. This is an insipid and inodorous substance, having somewhat the appearance of fine white threads adhering together; it is the essential constituent of muscles or flesh, in which it is mixed with and softened by gelatine. It is insoluble both in water and alcohol, but sulphuric acid converts it into a substance very analogous to gelatine.
These are the essential and general ingredients of animal matter; but there are other substances, which, though not peculiar to the animal system, usually enter into its composition, such as oils, acids, salts, &c.
Animal oil is the chief constituent of fat; it is contained in abundance in the cream of milk, whence it is obtained in the form of butter.
EMILY.
Is animal oil the same in its composition as vegetable oils?
MRS. B.
Not the same, but very analogous. The chief difference is that animal oil contains nitrogen, a principle which seldom enters into the composition of vegetable oils, and never in so large a proportion.
There are a few animal acids, that is to say, acids peculiar to animal matter, from which they are almost exclusively obtained.
The animal acids have triple bases of hydrogen, carbon, and nitrogen. Some of them are found native in animal matter; others are produced during its decomposition.
Those that we find ready formed are:
The bombic acid, which is obtained from silk-worms.
The formic acid, from ants.
The lactic acid, from the whey of milk.
The sebacic, from oil or fat.
Those produced during the decomposition of animal substances by heat, are the prussic and zoonic acids. This last is produced by the roasting of meat, and gives it a brisk flavour.
CAROLINE.
The class of animal acids is not very extensive?
MRS. B.
No; nor are they, generally speaking, of great importance. The prussic acid is, I think, the only one sufficiently interesting to require any further comment. It can be formed by any artificial process, without the presence of any animal matter; and it may likewise be obtained from a variety of vegetables, particularly those of the narcotic kind, such as poppies, laurel, &c. But it is commonly obtained from blood, by strongly heating that substance with caustic potash; the alkali attracts the acid from the blood, and forms with it a prussiat of potash. From this state of combination the prussic acid can be obtained pure by means of other substances which have the power of separating it from the alkali.
EMILY.
But if this acid does not exist ready formed in blood, how can the alkali attract it from it?
MRS. B.
It is the triple basis only of this acid that exists in the blood; and this is developed and brought to the state of acid, during the combustion. The acid therefore is first formed, and it afterwards combines with the potash.
EMILY.
Now I comprehend it. But how can the prussic acid be artificially made?
MRS. B.
By passing ammoniacal gas over red-hot charcoal; and hence we learn that the constituents of this acid are hydrogen, nitrogen, and carbon. The two first are derived from the volatile alkali, the last from the combustion of the charcoal.
CAROLINE.
But this does not accord with the system of oxygen being the principle of acidity.
MRS. B.
The colouring matter of prussian blue is called an acid, because it unites with alkalies and metals, and not from any other characteristic properties of acids; perhaps the name is not strictly appropriate. But this circumstance, together with some others of the same kind, has induced several chemists to think that oxygen may not be the exclusive generator of acids. Sir H. Davy, I have already informed you, was led by his experiments on dry acids to suspect that water might be essential to acidity. And it is the opinion of some chemists that acidity may possibly depend rather on the arrangement than on the presence of any particular principles. But we have not yet done with the prussic acid. It has a strong affinity for metallic oxyds, and precipitates the solutions of iron in acids of a blue colour. This is the prussian blue, or prussiat of iron, so much used in the arts, and with which I think you must be acquainted.
EMILY.
Yes, I am; it is much used in painting, both in oil and in water colours; but it is not reckoned a permanent oil-colour.
MRS. B.
That defect arises, I believe, in general, from its being badly prepared, which is the case when the iron is not so fully oxydated as to form a red oxyd. For a solution of green oxyd of iron (in which the metal is more slightly oxydated), makes only a pale green, or even a white precipitate, with prussiat of potash; and this gradually changes to blue by being exposed to the air, as I can immediately show you.
CAROLINE.
It already begins to assume a pale blue colour. But how does the air produce this change?
MRS. B.
By oxydating the iron more perfectly. If we pour some nitrous acid on it, the prussian blue colour will be immediately produced, as the acid will yield its oxygen to the precipitate, and fully saturate it with this principle, as you shall see.
CAROLINE.
It is very curious to see a colour change so instantaneously.
MRS. B.
Hence you perceive that prussian blue cannot be a permanent colour, unless prepared with red oxyd of iron, since by exposure to the atmosphere it gradually darkens, and in a short time is no longer in harmony with the other colours of the painting.
CAROLINE.
But it can never become darker, by exposure to the atmosphere, than the true prussian blue, in which the oxyd is perfectly saturated?
MRS. B.
Certainly not. But in painting, the artist not reckoning upon partial alterations in his colours, gives his blue tints that particular shade which harmonises with the rest of the picture. If, afterwards, those tints become darker, the harmony of the colouring must necessarily be destroyed.
CAROLINE.
Pray, of what nature is the paint called carmine?
MRS. B.
It is an animal colour prepared from cochineal, an insect, the infusion of which produces a very beautiful red.
CAROLINE.
Whilst we are on the subject of colours, I should like to learn what ivory black is?
MRS. B.
It is a carbonaceous substance obtained by the combustion of ivory. A more common species of black is obtained from the burning of bone.
CAROLINE.
But during the combustion of ivory or bone, the carbon, I should have imagined, must be converted into carbonic acid gas, instead of this black substance?
MRS. B.
In this, as in most combustions, a considerable part of the carbon is simply volatilised by the heat, and again obtained concrete on cooling. This colour, therefore, may be called the soot produced by the burning of ivory or bone.
CONVERSATION XXIV.
ON THE ANIMAL ECONOMY.
----
MRS. B.
We have now acquired some idea of the various materials that compose the animal system; but if you are curious to know in what manner these substances are formed by the animal organs, from vegetable, as well as from animal substances, it will be necessary to have some previous knowledge of the nature and functions of these organs, without which it is impossible to form any distinct idea of the process of animalisation and nutrition.
CAROLINE.
I do not exactly understand the meaning of the word animalisation?
MRS. B.
Animalisation is the process by which the food is assimilated, that is to say, converted into animal matter; and nutrition is that by which the food thus assimilated is rendered subservient to the purposes of nourishing and maintaining the animal system.
EMILY.
This, I am sure, must be the most interesting of all the branches of chemistry!
CAROLINE.
So I think; particularly as I expect that we shall hear something of the nature of respiration, and of the circulation of the blood?
MRS. B.
These functions undoubtedly occupy a most important place in the history of the animal economy.—But I must previously give you a very short account of the principal organs by which the various operations of the animal system are performed. These are:
| The | Bones; |
| Muscles, | |
| Blood vessels, | |
| Lymphatic vessels, | |
| Glands, and | |
| Nerves. |
The bones are the most solid part of the animal frame, and in a great measure determine its form and dimensions. You recollect, I suppose, what are the ingredients which enter into their composition?
CAROLINE.
Yes; phosphat of lime, cemented by gelatine.
MRS. B.
During the earliest period of animal life, they consist almost entirely of gelatinous membrane having the form of the bones, but of a loose spongy texture, the cells or cavities of which are destined to be filled with phosphat of lime; it is the gradual acquisition of this salt which gives to the bones their subsequent hardness and durability. Infants first receive it from their mother’s milk, and afterwards derive it from all animal and from most vegetable food, especially farinaceous substances, such as wheat-flour, which contain it in sensible quantities. A portion of the phosphat, after the bones of the infant have been sufficiently expanded and solidified, is deposited in the teeth, which consist at first only of a gelatinous membrane or case, fitted for the reception of this salt; and which, after acquiring hardness within the gum, gradually protrude from it.
CAROLINE.
How very curious this is; and how ingeniously nature has first provided for the solidification of such bones as are immediately wanted, and afterwards for the formation of the teeth, which would not only be useless, but detrimental in infancy!
MRS. B.
In quadrupeds the phosphat of lime is deposited likewise in their horns, and in the hair or wool with which they are generally clothed.
In birds it serves also to harden the beaks and the quills of their feathers.
When animals are arrived at a state of maturity, and their bones have acquired a sufficient degree of solidity, the phosphat of lime which is taken with the food is seldom assimilated, excepting when the female nourishes her young; it is then all secreted into the milk, as a provision for the tender bones of the nursling.
EMILY.
So that whatever becomes superfluous to one being, is immediately wanted by another; and the child acquires strength precisely by the species of nourishment which is no longer necessary to the mother. Nature is, indeed, an admirable economist!
CAROLINE.
Pray, Mrs. B., does not the disease in the bones of children, called the rickets, proceed from a deficiency of phosphat of lime?
MRS. B.
I have heard that this disease may arise from two causes; it is sometimes occasioned by the growth of the muscles being too rapid in proportion to that of the bones. In this case the weight of the flesh is greater than the bones can support, and presses upon them so as to produce a swelling of the joints, which is the great indication of the rickets. The other cause of this disorder is supposed to be an imperfect digestion and assimilation of the food, attended with an excess of acid, which counteracts the formation of phosphat of lime. In both instances, therefore, care should be taken to alter the child’s diet, not merely by increasing the quantity of aliment containing phosphat of lime, but also by avoiding all food that is apt to turn acid on the stomach, and to produce indigestion. But the best preservative against complaints of this kind is, no doubt, good nursing: when a child has plenty of air and exercise, the digestion and assimilation will be properly performed, no acid will be produced to interrupt these functions, and the muscles and bones will grow together in just proportions.
CAROLINE.
I have often heard the rickets attributed to bad nursing, but I never could have guessed what connection there was between exercise and the formation of the bones.
MRS. B.
Exercise is generally beneficial to all the animal functions. If man is destined to labour for his subsistence, the bread which he earns is scarcely more essential to his health and preservation than the exertions by which he obtains it. Those whom the gifts of fortune have placed above the necessity of bodily labour are compelled to take exercise in some mode or other, and when they cannot convert it into an amusement, they must submit to it as a task, or their health will soon experience the effects of their indolence.
EMILY.
That will never be my case: for exercise, unless it becomes fatigue, always gives me pleasure; and, so far from being a task, is to me a source of daily enjoyment. I often think what a blessing it is, that exercise, which is so conducive to health, should be so delightful; whilst fatigue, which is rather hurtful, instead of pleasure, occasions painful sensations. So that fatigue, no doubt, was intended to moderate our bodily exertions, as satiety puts a limit to our appetites.