Silver has many uses. Like gold, it is a beautiful metal that long has been used for coins and ornaments. A large amount of silver goes to make articles such as spoons, forks, platters, and trays. The photographic industry uses silver—much of the film for cameras is coated with a silver halide. Doctors and dentists use silver, too. The mixture that a dentist uses to fill teeth contains silver along with several other metals. Doctors sometimes use silver wire to fasten broken bones, and silver compounds and solutions, such as silver nitrate, are used in some kinds of medical treatment.
Perhaps more people have heard of legendary, lost silver mines of Texas than of the actual and important silver deposits found in the Trans-Pecos country of west Texas. Some of the west Texas silver minerals include argentite, cerargyrite, and native silver. Although the argentite and native silver commonly found there are mixed with galena, a lead mineral, or with chalcocite, a copper mineral, they also occur separately.
The element silver is found alone as native silver. When pure, it is rather easy to recognize. It is metallic and has a silver-white color that may tarnish to gray, black, or yellowish brown. Native silver is heavy (it has a specific gravity of 10.5) and soft (a pocket knife scratches it easily). When you rub it across a streak plate, native silver, unless it is tarnished, leaves a shiny, silver-white streak. This metal is so ductile that it can be drawn into a wire. It is also malleable and flattens when hit with a hammer.
Silver occurs as crystals, which are poorly shaped cubes and octahedrons, or as irregular masses. It may have a net-like appearance (called reticulate), or it may be shaped like little needles (described then as acicular). It occurs in wires (then called filiform) or as scales or plates.
Prospector.
Two of the Texas silver minerals, argentite and cerargyrite, do not resemble silver at all. Argentite, a silver sulfide, is also called silver glance. It is a dark, lead-gray mineral with a metallic luster that weathers to a dull black. When you rub it across a streak plate, argentite gives a shiny, blackish to lead-gray streak. This mineral is soft enough to leave a mark on paper. It has a specific gravity of 7.3, and it is sectile enough to be cut smoothly (like soap) with a knife. In some places argentite is found as irregular masses or as a coating on rocks and other minerals.
Another silver mineral, cerargyrite (or horn silver) is a silver chloride. This mineral has a nonmetallic luster and is transparent to translucent. It resembles pearl-gray, white, greenish, or colorless wax. When exposed to the light it turns violet brown or black. Cerargyrite is soft—you can scratch it with a fingernail. Like argentite, it is sectile. This mineral has a specific gravity of 5.5, and it commonly occurs as irregular masses and as crusts.
These silver minerals have been mined at a number of places in Trans-Pecos Texas. The largest silver mine in Texas, the Presidio mine, is located near Shafter in south-central Presidio County. It contains argentite, cerargyrite, and native silver, along with galena and several other minerals. This mine is not open now, but in the years between 1885 and 1942, it produced a large amount of silver along with some lead and gold. There are several other lead-silver mines in this Shafter area, but none has produced as much as the Presidio mine.
In this mine, the silver minerals occur mostly in large, flat deposits in Permian limestone and other sedimentary rocks. The minerals are believed to have been deposited there—probably during Tertiary time—by solutions that came from hot magma far below the rocks. As they moved in along the layers of limestone, the solutions replaced portions of this rock with minerals containing silver, lead, and other elements. Later, water seeped into these deposits and dissolved some of the minerals. This dissolved material was then re-deposited, and it formed most of the minerals we now find there.
No silver is being mined in Texas at present, but it has, in the past, been produced from other Trans-Pecos mines. Galena that contains silver (called argentiferous galena) has been mined at the Bird mine at Altuda Mountain (about 14 miles east of Alpine) in northern Brewster County. It also has been obtained from mines in the Quitman Mountains and in the Eagle Mountains of Hudspeth County. Some cerargyrite has been mined at the Plata Verde mine near the Culberson-Hudspeth County line.
Several mines in the Van Horn area of Culberson and Hudspeth counties have produced silver along with copper. An important silver mine in this area is the now idle and flooded Hazel mine. (This mine is described with copper minerals on p. 52.)
Smoky Quartz. See Quartz.
Soapstone. See Talc and Soapstone.
Specular Hematite. See Hematite.
Sulfur is one of Texas’ most valuable minerals. It consists of only a single element, sulfur. This mineral has a resinous luster and is transparent to translucent. Sulfur ordinarily is yellow, but impurities cause it to look greenish, brownish, reddish, or grayish. When you rub it across a streak plate, it leaves a white or a pale-yellow streak. Sulfur has a specific gravity of 2.04 to 2.09 and is soft enough to be scratched by a copper penny. It breaks with a conchoidal to uneven fracture. When it gets hot enough (478° Fahrenheit), sulfur will burn. For this reason, it often is called brimstone.
Sulfur does not conduct electricity and is a poor conductor of heat. You can test how poorly heat passes through it by holding a fragment of sulfur up to your ear. You may be able to hear a crackling sound. The sound results when the outer part of the fragment expands (due to the heat from your hand) while the inner part (which has received no heat) remains unchanged.
Crystals of sulfur are sometimes found, and most of them have either a double-pyramid shape or a flat, tabular shape. Sulfur also occurs as compact masses, as crusts, and as scattered grains.
Native sulfur deposits are found in two widely separated areas of Texas—one in west Texas and the other along the Gulf Coast in southeast Texas, extending over into Louisiana. In the Gulf Coast area, native sulfur is found on some of the salt domes.
The salt domes are huge (from about half a mile to more than 2 miles across), column-shaped masses made up of halite and some anhydrite. These masses have pushed up toward the surface through thousands of feet of sand, clay, and other sedimentary rocks. On top of many of the salt columns is a covering of limestone (calcite), anhydrite, and gypsum known as the cap-rock. It is in this cap-rock that the sulfur is found.
It is thought that when the masses of halite and anhydrite pushed toward the earth’s surface, some of the upper part of the halite dissolved. The anhydrite, however, did not dissolve, and it remained on top of the salt column. Then, a part of this anhydrite was altered into the gypsum, limestone, and sulfur that now are found in some of the cap-rocks. Laboratory experiments have shown that the sulfur in the cap-rocks likely formed through the action of sulfate-reducing bacteria. These bacteria, in the presence of petroleum, converted the sulfate in some of the anhydrite into hydrogen sulfide. Later, hydrogen sulfide was oxidized—perhaps by reaction with more of the anhydrite—to form the sulfur.
Most of the large cap-rock sulfur deposits are about 1,500 to 2,400 feet underground. At first, an attempt was made to get this sulfur out of the ground by digging shafts down to it, but loose, wet, caving sands and poisonous gases, such as hydrogen sulfide, made this mining method almost impossible. Finally, a chemist, Herman Frasch, found a way to obtain the sulfur by making use of sulfur’s low melting point. When sulfur gets slightly hotter than boiling water (235° to 247° Fahrenheit), it melts and becomes a dark, yellowish-brown liquid.
In the Frasch method of sulfur mining, a well is drilled into the salt-dome cap-rock, and three pipes, one inside the other, are put into the well. Superheated water under pressure (hotter than 212° Fahrenheit, the temperature at which water ordinarily turns into steam) is sent down one of the pipes to melt the sulfur in the cap-rock around the bottom of the well. Then, compressed air is sent down another of the pipes. This air presses against the liquid sulfur and forces it up to the surface through the third pipe. At the surface, the sulfur is poured into bins, where it cools and becomes a solid again, or it is transported molten, in pipelines and tankers.
Sulfur has been obtained from a number of the Texas Gulf Coast salt domes including Bryan Mound, Clemens dome, Damon Mound, and Hoskins Mound in Brazoria County; Palangana dome in Duval County; Long Point dome, Nash dome, and Orchard dome in Fort Bend County; High Island dome in Galveston County; Fannett dome and Spindletop dome in Jefferson County; Moss Bluff dome in Liberty County; Gulf dome in Matagorda County; and Boling dome in Wharton County.
In west Texas, sulfur occurs in Permian rocks both at the surface and underground. A small amount of sulfur has been mined in the Rustler Springs area of northeastern Culberson County and northwestern Reeves County, about 50 miles northwest of Pecos. There, scattered grains, crystals, and irregular masses of sulfur occur in cracks and in dissolved-out openings in the Castile Gypsum and in the surface gravel, gypsum, sand, and clay that cover most of this formation.
Sulfur has many uses. It is used as an insect-killer, thus helping our food crops to grow. It is used in pulp and paper manufacturing and in the vulcanizing of rubber. Some other uses are in the making of paints, dyes, and explosives. A large amount of sulfur goes to make sulfuric acid, which itself has numerous uses in the chemical, steel, oil refining, and other industries.
Sulfur is obtained from the cap-rock of Gulf Coastal Plain salt domes by the Frasch process.
Talc, a hydrous magnesium silicate, is an extremely soft mineral—your fingernail scratches it easily. It has a greasy or a pearly luster, and its color is white, light green, or gray. When rubbed across a streak plate, it leaves a white streak.
Talc cleaves perfectly in one direction, and the cleavage fragments are thin, flat, and sheet-like. Its fracture is uneven. This mineral has a soaplike or greasy feel, and it is sectile—a knife will cut through it. Talc is not particularly heavy—it has a specific gravity of 2.7 to 2.8. This mineral seldom occurs with a crystal shape. More commonly it is massive and is granular or layered.
Talc is not always found as a single, pure mineral. In nature, it commonly occurs mixed with one or more other minerals, such as tremolite, anthophyllite, chlorite, and magnetite. This combination of talc with other minerals forms a soft, greasy or soapy-feeling metamorphic rock called soapstone. The talc in this rock may be difficult to identify without special laboratory tests.
In Texas, talc and soapstone are found in Precambrian metamorphic rocks. In west Texas, talc occurs in an area about 20 miles long (just north of U. S. Highway 80 in the vicinity of Allamoore, Eagle Flat siding, and Talc Rock siding) in Hudspeth County. Some of this talc is mined from open pits and used by the ceramic industry to make wall tile. Some of it is finely ground, mixed with insect poison, and used as insect powders and dusts.
Deposits of soapstone, containing talc, occur in the Llano uplift area of central Texas with schist, gneiss, and serpentine rocks in northeastern Gillespie, northwestern Blanco, and southern Llano counties. Smaller deposits occur in northeastern Mason County and in northwestern and southeastern Llano County.
The Llano uplift area soapstones are light green to light buff. It is thought that some of them were once igneous rocks that contained magnesium minerals. Fluids, along with great heat and pressures below the earth’s surface, changed these igneous rocks into soapstone.
Some of this Llano uplift area soapstone is mined from open pits near Willow City in Gillespie County. It is used mostly in making insect powders and roofing granules. In addition, some of the central Texas soapstones have been used for hearths and for fireplace linings.
Topaz, an aluminum fluorosilicate, is a mineral especially prized by collectors because many specimens are gemstones. Topaz is transparent, has a glassy luster, and is quite hard (neither quartz nor a steel file will scratch it). The topaz that has been found in Texas is either colorless, pale blue, or sky blue. This mineral is fairly heavy—its specific gravity is 3.4 to 3.6. It cleaves perfectly in one direction (called basal cleavage), and some of the cleavage fragments have a flat, slabby appearance.
Topaz is commonly found as prism-shaped crystals, as cleavage fragments, and as irregular grains. Some fragments of topaz look like quartz. Topaz, however, is harder and heavier than quartz, and it has perfect basal cleavage, which quartz does not have.
In Texas, crystals, grains, and cleavage fragments of topaz occur in the Llano uplift area of central Texas. They are found near Streeter and Grit in west-central Mason County and near Katemcy in northern Mason County. Here, some of the topaz occurs in Precambrian pegmatite veins that cut through granite rocks. Most of the topaz, however, is found as pebbles in the gravels of nearby creeks, where it has washed after weathering out of the rocks.
Topaz crystal from near Streeter, Mason County, Texas.
Topaz probably originates when hot fluids move up out of molten magma into cracks and cavities in the surrounding rocks. There, the fluids react with elements in the rocks to form the topaz.
Topaz is a good gemstone because, in addition to its beauty, it is hard and is not easily marred by scratches. The Mason County topaz makes excellent gemstones. Most of it is beautiful and clear and is either colorless or of a pleasing blue color. These stones are cut, polished, and mounted in rings and other jewelry. A number of specimens of this Mason County topaz are displayed in museums.
Tourmaline is a complex silicate of boron and aluminum. Other elements, such as magnesium, sodium, lithium, calcium, iron, or fluorine, also may be present. This mineral has a glassy to resinous luster. Only the dark-colored varieties of tourmaline have been found in Texas. One is a black variety called schorl, and another is a brown variety called dravite. Other kinds of tourmaline, although not found in Texas, are colorless or some shade of blue, yellow, red, pink, or green. Some crystals even show more than one color.
Tourmaline is too hard to scratch with a steel file, it has a specific gravity of 3 to 3.25, and it has a conchoidal to uneven fracture. Very little light passes through the dark varieties, and some fragments of schorl look like shiny, black coal.
Tourmaline occurs as masses without crystal shapes, but crystals are commonly found. The crystals are prism-shaped and have small vertical grooves, called striations, on the prism faces. When you look at some crystals from an end, you will see that the cross section is a triangle with the sides bowed outward.
Black tourmaline crystals with milky quartz from north of Llano, Llano County, Texas.
Both the black and the brown varieties of tourmaline have been found at several places in the Llano uplift of central Texas. One well-known locality is at Town Mountain north of Llano in Llano County. Here, the tourmaline occurs in milky quartz that is associated with Precambrian granite rocks. In west Texas, in Culberson and Hudspeth counties, black tourmaline occurs in pegmatite rocks in the Van Horn Mountains, the Carrizo Mountains, and the Wylie Mountains. In the Eagle Mountains of Hudspeth County, it is found in metamorphic rocks as well as in pegmatites.
Some tourmaline formed from hot fluids containing boron that were given off by magmas far below the earth’s surface. These fluids traveled up through cracks and other openings in overlying rocks. As the fluids reacted with other elements and compounds, the tourmaline formed.
The clear, light-colored varieties of tourmaline are much admired, and they are more widely used as gemstones than are the dark-colored varieties. Some collectors, however, find that the dark-colored Texas tourmalines, when cut and polished, make shiny, attractive gemstones.
Some tourmaline is used as grinding material, but no Texas tourmaline is produced for this purpose.
Travertine. See Calcite.
In 1945, the world suddenly became aware of the awesome power of atomic energy when the element uranium was used to produce some of the first atomic bombs. Uranium does not occur alone in nature but is found combined with other elements in a number of minerals.
All of the uranium minerals are radioactive. The uranium they contain is gradually breaking down and changing into a series of 13 other elements, called daughter elements. Each daughter element breaks down and changes into the next daughter element of the series. While breaking down, these elements give off particles and rays of energy.
This energy or radioactivity is made up of what are called alpha particles, beta particles, and gamma rays. You cannot see, hear, taste, smell, or feel them. The alpha and beta particles are weak and do not travel far. The gamma rays, however, can travel farther and can pass through seemingly solid material. Scientists have found that these rays can move through about 1 foot of rock, 2½ feet of water, and several hundred feet of air.
Prospectors searching for uranium minerals carry instruments that are able to detect this radioactivity. The uranium itself gives off only alpha particles, but some of its daughter elements give off gamma rays. These daughter elements are normally found with the uranium, and it is their strong gamma rays that the instruments are most apt to detect.
A Geiger counter is used to detect radioactivity.
One of the instruments used is the Geiger counter. It indicates radioactivity by means of a meter, a flashing light, or a clicking sound, which can be heard through earphones. Another instrument for detecting radioactivity is the scintillation counter. It is more sensitive than the Geiger counter and it can detect radioactivity from a greater distance. The scintillation counter can be used from an automobile or an airplane, but the Geiger counter must be quite close to the source of radioactivity to be of use.
Various uranium minerals have been found, mostly in small amounts, in a number of places in Texas. Some of these minerals, such as uraninite or pitchblende, are heavy and dark colored. Others, including carnotite, tyuyamunite, autunite, and uranophane, are a shade of yellow or green. They are quite soft. Deposits of the light-colored uranium minerals have been mined from two areas of Texas. One of these areas is in Garza County on the Texas High Plains, and the other is in Karnes and Live Oak counties in the Gulf Coastal Plain.
One of the light-colored uranium minerals, carnotite, is a potassium-uranium vanadate, which has a bright canary-yellow or lemon-yellow color. This mineral is transparent to translucent and has an earthy or a pearly luster. Carnotite usually is found as crusts and as powdery masses. It is quite soft and can be scratched with a fingernail.
Carnotite, along with tyuyamunite, autunite, and several other soft, yellowish or greenish uranium minerals, is found in the Texas Gulf Coastal Plain. These minerals occur in the Jackson, Catahoula, and Oakville strata (which are Tertiary in age) in an area extending from Gonzales County to the Rio Grande (in parts of the area indicated by no. 2 and no. 3 on the geologic map, pp. 4-5). The largest deposits in this district have been found in the Karnes County area.
The Gulf Coastal Plain uranium minerals occur mostly with sandstones and clays in a sequence of strata that contains volcanic ash. It is believed that small scattered amounts of uranium compounds that were present in the volcanic ash sediments were dissolved by seeping underground water. These waters then moved into the sandstones and clays where they deposited the uranium as carnotite and as other uranium minerals.
Another uranium mineral, uranophane (calcium-uranium silicate), also occurs in Texas. Uranophane has a yellow to yellow-orange color and a pearly to greasy luster. When rubbed across a streak plate, it leaves a light yellow to a light yellow-orange streak. It is soft enough to be scratched by a copper penny. Uranophane has been found in extrusive igneous rocks in northwestern Presidio County in west Texas.
A dark-colored uranium mineral, pitchblende, is a variety of the mineral uraninite, uranium dioxide. Pitchblende does not occur with a crystal shape but rather as rounded and irregular-shaped masses. It is brownish black, greenish black, or black. If you rub it across a streak plate, pitchblende leaves a brownish-black streak. This mineral is heavy (it has a specific gravity of 6.5 to 8.5) and hard (a pocket knife will not scratch it, although a steel file will). Pitchblende has a submetallic luster and looks dull, greasy, or like pitch or tar.
Small amounts of pitchblende have been found at several places in Texas. One of these localities is a few miles west of Burnet in Burnet County in central Texas. Here, the pitchblende occurs in Precambrian igneous rocks that are associated with gneiss. In south Texas, some fine, scattered particles of pitchblende have been found about 325 feet below the surface in Tertiary (Pliocene) sediments that cover the Palangana salt dome in Duval County. No pitchblende is mined in Texas.
Uranophane. See Uranium Minerals.
Vitrophyre. See Obsidian and Vitrophyre.
Volcanic ash deposits, which also are known as pumicite, are loose and powdery. They are made up mostly of material that is thrown into the air when volcanoes erupt. If a volcano erupts with a violent explosion, the nearby rocks are blown into powder. Molten lava also is hurled into the air, where some of it immediately cools to become tiny bubbles and particles of glass. The winds may carry some of this fine material far away before depositing it.
Deposits of volcanic ash are white, bluish, greenish, yellowish, or grayish, and some of them glisten like snow in the sunlight. They feel rough and gritty. When examined under a microscope, this material shows the tiny curved and sharp-cornered particles of the broken volcanic glass. Deposits of volcanic ash may also contain clay, silt, sand, or other impurities.
Volcanoes, which may have been located in the Davis Mountains and in other areas of west Texas and in northern Mexico, erupted during Tertiary time. The volcanic ash that we find at the surface today in some of the Tertiary formations in Texas could have come from these volcanoes. Tertiary volcanic ash deposits occur in the Texas Gulf Coastal Plain (such as in Brazos, Fayette, Karnes, Polk, Starr, Trinity, and other counties) and in the Trans-Pecos country of west Texas.
Volcanic ash deposits of Quaternary (Pleistocene) age, which are less than a million years old, are found in a number of counties on the Texas High Plains. Farther to the east, ash deposits occur in Baylor, Dickens, Kent, and Wilbarger counties. This volcanic ash may have come from a volcano that erupted in northern New Mexico during Quaternary time.
Volcanic ash or pumicite has several commercial uses. Some is used to make pozzolan cement, and some is used in sweeping compounds, cleansing and scouring powders, and abrasive soaps. Pumicite has been mined in Dickens, Scurry, Starr, and several other counties of Texas.
Wad. See Manganese Minerals.
Wood Opal. See Opal.