APPENDIX II

CHEMICAL CONSTITUTION OF SOME ARMENIAN LAKES

Samples of water from Lakes Van, Nazik, Bulama (Gop), and from two lakes in the Nimrud crater were collected by us, carefully sealed, and submitted as soon as possible to the late Mr. William Thorp, B.Sc., for analysis. Unfortunately the samples were not large enough to permit of more than a single analysis in each case, estimating the various constituents in succession. Hence it was not possible to examine for ammonia or organic matter, or for certain compounds of which slight traces may have been present.

With regard to Lake Van, three previous analyses of its water have been made at various times, and the following tables have been prepared in order to facilitate comparison.

LAKE VAN.

Quantities of solids in solution estimated in parts per 100,000 parts of water.

Chancourtois.1 Abich.2 Serda.3 Thorp.
Chlorine 566.679 488.182 579.114 568.9
Carbonates 329.057 249.448 328.637 320.565
Sulphates 212.773 188.476 198.467 203.4
Phosphates ... ... 0.146 0.05
Nitrates ... ... ... ...
Soda 1206.370 862.848 1040.864 1115.916
Potash 29.742 29.238 52.809 39.919
Magnesia 26.211 21.250 27.311 not determined
Lime ... ... 5.240 ...
Strontia ... ... 0.063 ...
Iron oxide ... ... 0.303 ...
Manganese oxide ... ... 0.223 ...
Ammonia ... ... 0.573 ...
Silica 18.000 trace 7.284 7.53
Alumina 3.58 0.347 1.01
Total solids in solution 2260.000 1734.21 2110.979 2248.9
Suspended matter ... ... A little organic matter 0.39

Calculated composition in parts per 100,000.
Chancourtois. Abich. Serda. Thorp.
Sodium chloride 938.000 810.67 953.835 938.837
Sodium
,,
carbonate
861.000 543.84 714.426 773.110
Sodium
,,
sulphate
333.000 258.68 266.527 369.095
Potassium sulphate 55.000 54.06 97.655 73.819
Magnesium carbonate 55.000 40.71 57.308 not determined
Magnesium
,,
sulphate
... 22.67 ...
not
,,
determined
,,
Calcium carbonate ... ... 4.692 ...
Calcium
,,
sulphate
... ... 5.928 ...
Calcium
,,
phosphate
... ... 0.319 ...
Strontium sulphate ... ... 0.111 ...
Iron carbonate ... ... 0.488 ...
Manganese carbonate ... ... 0.360 ...
Ammonium chloride ... ... 1.699 ...
Silica 18.000 3.58 7.284 7.53
Alumina 0.347 1.01
Nitrates ... ... ... 0.05
Percentage of solids in solution 22.6% 17.34% 21.10% 22.48%

The specific gravity of the water was determined by Chancourtois as 1.0188, and by Abich as 1.0189, both at 19° C. As Abich points out, the water of Lake Van is nearly identical in composition with that of some of the soda-lakes at the south-eastern foot of Ararat, in the Araxes plain. In some of these the chloride, in others the carbonate, and in others again the sulphate of sodium is the predominating constituent. Probably the composition of the waters of Lake Van vary somewhat in different parts of the lake; Abich’s sample was certainly less saline than those of the other analysts.

The following analyses of the extraordinarily saline waters of Lake Urmi are appended for contrast rather than for comparison with those of Lake Van.

LAKE URMI.

Quantities of solids in solution estimated in parts per 100,000 parts of water.

Abich.4 Günther and Manley.5
Chlorine 12,686.8 8,536
Sulphates 929.03 631.2
Soda 10,106.4 6,814
Potash ... 140.2
Magnesia 1,099.3 626.6
Lime 37.7 70.6
Traces of bromides Traces of barium.
... No traces either of bromine or iodine.

In this case Abich’s sample was a stronger solution than Günther’s, the percentage of solid salts being 22.28 and 14.89 respectively. Yet the relative proportion of the various salts is very similar, as shown by the following comparison of percentages:—
Abich. Günther and Manley.
Sodium chloride 86.37 86.203
Magnesium chloride 6.94 6.816
Magnesium
,,
sulphate
6.08 4.150
Calcium chloride 0.27 ...
Calcium
,,
sulphate
0.34 1.151
Potassium sulphate ... 1.741
100.00 100.061

The specific gravity in the two cases were determined as 1.175 and 1.113 respectively.

The remaining four analyses by Mr. Thorp were made from our small samples of water taken from fresh-water lakes.

Quantities estimated in parts per 100,000.

Lake Bulama. Lake Nazik. Nimrud Crater, Large Lake. Nimrud Crater, Warm Lake.
Chlorine 0.35 1.50 2.15 4.25
Sulphates ... ... ... ...
Nitrates 0.05 0.05 0.08 0.05
Sodium and potassium carbonates 8.80 ... ... 91.13
Magnesia 1.29 ... ... ...
Lime 2.71 3.32 ... 5.82
Iron oxide 0.60 0.01 ... 0.08
Silica 3.5 ... ... 13.8
Alumina 1.71 0.24 ... 0.68
Total solids in solution 25.86 18.74 39.41 114.43
Suspended matter 21.33 0.36 1.88 2.18

The water of Lake Bulama is slightly ferruginous and yet slightly alkaline. The unpleasant odour from the lake doubtless arose from the fermentation of much vegetable matter in suspension and solution; it could not be due to sulphur compounds, since there is an absence of sulphates, and the low proportion of chlorine indicates freedom from animal contamination.

Lake Nazik.—A soft water, with very little contamination.

Nimrud crater.—An accident to the sample of water from the large lake caused the loss of the iron, alumina, lime, and magnesia estimations. Some vegetable matter occurred in suspension.

The water of the warm lake is slightly alkaline, but the ratio of the potassium to the sodium could not be determined. It was rather turbid owing to fine fragments of vegetable matter. It is scarcely conceivable that it can possess healing properties.


1 Comptes-rendus, Acad. des Sciences, Paris, 1847, xxi. p. 1111. 

2 Vergl. chem. Untersuch. d. Wässer d. casp. Meeres, Urmia u. Van-Sees, Mém. Acad. Sc. St. Pétersbourg, 1859, Séries 6, math. et phys. vol. vii. 

3 Müller-Simonis, P., Du Caucase an Golfe Persique, Paris, 1892, p. 258. 

4 Loc. cit. 

5 Proc. Roy. Soc. lxv. p. 312, London, 1899.