“This conception of the intermittent action of creative power and purpose does not, I confess, commend itself to me. That, however, is not so surprising as that it should be thought that this curious conception of the action of creative power is of value to religion. Whether the intermittent theory is a true or an erroneous conception seems to me to have nothing to do with ‘religion’ in the large sense of that word so often misused. It seems to me to be a kind of mythology, and I should have thought could be of no special assistance to teachers of Christianity. Such theories of divided creative operations are traceable historically to polytheism.

“Lastly, with reference to Lord Kelvin’s statement that ‘modern biologists are coming once more to a firm acceptance of something—and that is “a vital principle.”’ I will not venture to doubt that Lord Kelvin has such persons among his acquaintance. On the other hand, I feel some confidence in stating that a more extensive acquaintance with modern biologists would have led Lord Kelvin to perceive that those whom he cites are but a trifling percentage of the whole. I do not myself know of any one of admitted leadership among modern biologists who is showing signs of ‘coming to a belief in the existence of a vital principle.’

“Biologists were, not many years ago, so terribly hampered by these hypothetical entities—‘vitality,’ ‘vital spirits,’ ‘anima animans,’ ‘archetypes,’ ‘vis medicatrix,’ ‘providential artifice,’ and others which I cannot now enumerate—that they are very shy of setting any of them up again. Physicists, on the other hand, seem to have got on very well with their problematic entities, their ‘atoms’ and ‘ether,’ and ‘the sorting demon of Maxwell.’ Hence, perhaps, Lord Kelvin offers to us, with a light heart, the hypothesis of a ‘a vital principle’ to smooth over some of our admitted difficulties. On the other hand, we biologists, knowing the paralysing influence of such hypotheses in the past, are as unwilling to have anything to do with ‘a vital principle,’ even though Lord Kelvin erroneously thinks we are coming to it, as we are to accept other strange ‘entities’ pressed upon us by other physicists of a modern and singularly adventurous type. Modern biologists (I am glad to be able to affirm) do not accept the hypothesis of ‘telepathy’ advocated by Sir Oliver Lodge, nor that of the intrusions of disembodied spirits pressed upon them by others of the same school.

“We biologists take no stock in these mysterious entities. We think it a more helpful method to be patient and to seek by observation of, and experiment with, the phenomena of growth and development to trace the evolution of life and of living things without the facile and sterile hypothesis of ‘a vital principle.’ Similarly, we seek by the study of cerebral disease to trace the genesis of the phenomena which are supposed by some physicists who have strayed into biological fields to justify them in announcing the ‘discovery’ of ‘telepathy’ and a belief in ghosts.”


CHAPTER II
THE ADVANCE OF SCIENCE, 1881–1906

I propose to give in the following pages an outline of the advance of science in the past twenty-five years. It is necessary to distinguish two main kinds of advancement, both of which are important. Francis Bacon gave the title ‘Advancement of Learning’ to that book in which he explained not merely the methods by which the increase of knowledge was possible, but advocated the promotion of knowledge to a new and influential position in the organization of human society. His purpose, says Dean Church, was ‘to make knowledge really and intelligently the interest, not of the school or the study or the laboratory only, but of society at large.’ So that in surveying the advancement of science in the past quarter of a century we should ask not only what are the new facts discovered, the new ideas and conceptions which have come into activity, but what progress has science made in becoming really and intelligently the interest of society at large. Is there evidence that there is an increase in the influence of science on the lives of our fellow-citizens and in the great affairs of the State? Is there an increased provision for securing the progress of scientific investigation in proportion to the urgency of its need or an increased disposition to secure the employment of really competent men trained in scientific investigation for the public service?

1. The Increase of Knowledge in the Several Branches of Science.

The boundaries of my own understanding and the practical consideration of what is appropriate to a brief essay must limit my attempt to give to the general reader some presentation of what has been going on in the workshops of science in this last quarter of a century. My point of view is essentially that of the naturalist, and in my endeavour to speak of some of the new things and new properties of things discovered in recent years I find it is impossible to give any systematic or detailed account of what has been done in each division of science. All that I shall attempt is to mention some of the discoveries which have aroused my own interest and admiration. I feel, indeed, that it is necessary to ask forbearance for my presumption in daring to treat of so many subjects in which I cannot claim to speak as an authority, but only as a younger brother full of fraternal pride and sympathy in the glorious achievements of the great experimentalists and discoverers of our day.

As one might expect, the progress of the Knowledge of Nature (for it is to that rather than to the historical, moral and mental sciences that English-speaking people refer when they use the word ‘science’) has consisted, in the last twenty-five years, in the amplification and fuller verification of principles and theories already accepted, and in the discovery of hitherto unknown things which either have fallen into place in the existing scheme of each science or have necessitated new views, some not very disturbing to existing general conceptions, others of a more startling and, at first sight, disconcerting character. Nevertheless I think I am justified in saying that, exciting and of entrancing interest as have been some of the discoveries of the past few years, there has been nothing to lead us to conclude that we have been on the wrong path—nothing which is really revolutionary; that is to say, nothing which cannot be accepted by an intelligible modification of previous conceptions. There is, in fact, continuity and healthy evolution in the realm of science. Whilst some onlookers have declared to the public that science is at an end, its possibilities exhausted, and but little of the hopes it raised realised, others have asserted on the contrary, that the new discoveries—such as those relating to the X-rays and to radium—are so inconsistent with previous knowledge as to shake the foundations of science, and to justify a belief in any and every absurdity of an unrestrained fancy. These two reciprocally destructive accusations are due to a class of persons who must be described as the enemies of science. Whether their attitude is due to ignorance or traditions of self-interest, such persons exist. It is one of the objects of our scientific associations and societies to combat those assertions and to demonstrate, by the discoveries announced at their meetings and the consequent orderly building up of the great fabric of ‘natural knowledge,’ that Science has not come to the end of her work—has, indeed, only as yet given mankind a foretaste of what she has in store for it—that her methods and her accomplished results are sound and trustworthy, serving with perfect adaptability for the increase of true discovery and the expansion and development of those general conceptions of the processes of nature at which she aims.

New Chemical Elements.—There can be no doubt that the past quarter of a century will stand out for ever in human history as that in which new chemical elements, not of an ordinary type, but possessed of truly astounding properties, were made known with extraordinary rapidity and sureness of demonstration. Interesting as the others are, it is the discovery of radio-activity and of the element radium which so far exceeds all others in importance that we may well account it a supreme privilege that it has fallen to our lot to live in the days of this discovery. No single discovery ever made by the searchers of nature even approaches that of radio-activity in respect of the novelty of the properties of matter suddenly revealed by it. A new conception of the structure of matter is necessitated and demonstrated by it, and yet, so far from being destructive and disconcerting, the new conception fits in with, grows out of, and justifies the older schemes which our previous knowledge has formulated.

Before saying more of radio-activity, which is apt to eclipse in interest every other topic of discourse, I must recall to you the discovery of the five inert gaseous elements by Rayleigh and Ramsay, which belongs to the period on which we are looking back. It was found that nitrogen obtained from the atmosphere invariably differed in weight from nitrogen obtained from one of its chemical combinations; and thus the conclusion was arrived at by Rayleigh that a distinct gas is present in the atmosphere, to the extent of 1 per cent., which had hitherto passed for nitrogen. This gas was separated, and to it the name argon (the lazy one) was given, on account of its incapacity to combine with any other element. Subsequently this argon was found by Ramsay to be itself impure, and from it he obtained three other gaseous elements equally inert: namely neon, krypton, and xenon. These were all distinguished from one another by the spectrum, the sign-manual of an element given by the light emitted in each case by the gas when in an incandescent condition. A fifth inert gaseous element was discovered by Ramsay as a constituent of certain minerals which was proved by its spectrum to be identical with an element discovered twenty-five years ago by Sir Norman Lockyer in the atmosphere of the sun, where it exists in enormous quantities. Lockyer had given the name ‘helium’ to this new solar element, and Ramsay thus found it locked up in certain rare minerals in the crust of the earth.

But by helium we are led back to radium, for it has been found only two years ago by Ramsay and Soddy that helium is actually formed by a gaseous emanation from radium. Astounding as the statement seems, yet that is one of the many unprecedented facts which recent study has brought to light. The alchemist’s dream is, if not realised, at any rate justified. One element is actually under our eyes converted into another; the element radium decays into a gas which changes into another element, namely helium.

Radium, this wonder of wonders, was discovered owing to the study of the remarkable phosphorescence, as it is called—the glowing without heat—of glass vacuum-tubes through which electric currents are made to pass. Crookes, Lenard, and Röntgen each played an important part in this study, showing that peculiar rays or linear streams of at least three distinct kinds are set up in such tubes—rays which are themselves invisible, but have the property of making glass or other bodies which they strike glow with phosphorescent light. The celebrated Röntgen rays make ordinary glass give out a bright green light; but they pass through it, and cause phosphorescence outside in various substances, such as barium platino-cyanide, calcium tungstate, and many other such salts; they also act on a photographic plate and discharge an electrified body such as an electroscope. But the most remarkable feature about them is their power of penetrating substances opaque to ordinary light. They will pass through thin metal plates or black paper or wood, but are stopped by more or less dense material. Hence it has been possible to obtain ‘shadow pictures’ or skiagraphs by allowing the invisible Röntgen rays to pass through a limb or even a whole animal, the denser bone stopping the rays, whilst the skin, flesh, and blood let them through. They are allowed to fall (still invisible) on to a photographic plate, when a picture like an ordinary permanent photograph is obtained by their chemical action, or they may be made to exert their phosphorescence-producing power on a glass plate covered with a thin coating of a phosphorescent salt such as barium platino-cyanide, when a temporary picture in light and shade is seen.

The rays discovered by Röntgen were known as the X-rays, because their exact nature was unknown. Other rays studied in the electrified vacuum-tubes are known as cathode rays or radiant corpuscles, and others, again, as the Lenard rays.

It occurred to M. Henri Becquerel, as he himself tells us, to inquire whether other phosphorescent bodies besides the glowing vacuum-tubes of the electricians’ laboratory can emit penetrating rays like the X-rays. I say ‘other phosphorescent bodies,’ for this power of glowing without heat—of giving out, so to speak, cold light—is known to be possessed by many mineral substances. It has become familiar to the public in the form of ‘phosphorescent paint,’ which contains sulphide of calcium, a substance which shines in the dark after exposure to sunlight—that is to say, is phosphorescent. Other sulphides and the minerals fluor-spar, apatite, some gems, and, in fact, a whole list of substances have, under different conditions of treatment, this power of phosphorescence or shining in the dark without combustion or chemical change. All, however, require some special treatment, such as exposure to sunlight or heat or pressure, to elicit the phosphorescence, which is of short duration only. Many of the compounds of a somewhat uncommon metallic element, called uranium, used for giving a fine green colour to glass, are phosphorescent substances, and it was, fortunately, one of them which Henri Becquerel chose for experiment. Henri Becquerel is professor in the Jardin des Plantes of Paris; his laboratory is a delightful old-fashioned building, which had for me a special interest and sanctity when, a few years ago, I visited him there, for, a hundred years before, it was the dwelling-house of the great Cuvier. Here Henri Becquerel’s father and grandfather—men renowned throughout the world for their discoveries in mineralogy, electricity, and light—had worked, and here he had himself gone almost daily from his earliest childhood. Many an experiment bringing new knowledge on the relations of light and electricity had Henri Becquerel carried out in that quiet old-world place before the day on which, about twelve years ago, he made the experimental inquiry, ‘Does uranium give off penetrating rays like Röntgen rays?’ He wrapped a photographic plate in black paper, and on it placed and left lying there for twenty-four hours some uranium salt. He had placed a cross, cut out in thin metallic copper, under the uranium powder, so as to give some shape to the photographic print should one be produced. It was produced. Penetrating rays were given off by the uranium: the black paper was penetrated, and the form of the copper cross was printed on a dark ground (fig. 9). The copper was also penetrated to some extent by the rays from the uranium, so that its image was not left actually white. Only one step more remained before Becquerel made his great discovery. It was known, as I stated just now, that sulphide of calcium and similar substances become phosphorescent when exposed to sunlight, and lose this phosphorescence after a few hours. Becquerel thought at first that perhaps the uranium salt acquired its power similarly by exposure to light; but very soon, by experimenting with uranium salt long kept in the dark, he found that the emission of penetrating rays, giving photographic effects, was produced spontaneously. The emission of rays by this particular sample of uranium salt has shown no sign of diminution since this discovery. The emission of penetrating rays by uranium was soon found to be independent of its phosphorescence. Phosphorescent bodies, as such, do not emit penetrating rays. Uranium compounds, whether phosphorescent or not, emit and continue to emit, these penetrating rays, capable of passing through black paper and in a less degree through metallic copper. They do not derive this property from the action of light or any other treatment. The emission of these rays discovered by Becquerel is a new property of matter. It is called ‘radio-activity,’ and the rays are called Becquerel rays.

Fig. 9.—Henri Becquerel’s Discovery of Radio Activity.

Photographic print or skiagraph of a copper Maltese Cross produced by uranium salt placed as a heap of powder on the surface of black paper wrapped round a sensitive plate. Between the paper and the uranium powder the flat copper cross was interposed. The rays from the uranium salt have penetrated the black paper, but have been intercepted to a large extent by the copper cross—so that the sensitive silver plate is darkened all about the cross—over an area corresponding to that of the heap of uranium salt, but is left pale where the copper figure blocked the path of the active rays given off by the uranium, partially but not wholly. It was thus proved that the rays from the uranium salt can pass through blackened paper and also though to a less extent through a plate of copper.

From this discovery by Becquerel to the detection and separation of the new element radium is an easy step in thought, though one of enormous labour and difficulty in practice. Professor Pierre Curie (whose name I cannot mention without expressing the grief caused to all men of science by the sad accident by which his life was taken) and his wife, Madame Sklodowski Curie, incited by Becquerel’s discovery, examined the ore called pitch-blende which is worked in mines in Bohemia and is found also in Cornwall. It is the ore from which all commercial uranium is extracted. The Curies found that pitch-blende has a radio-activity four times more powerful than that of metallic uranium itself. They at once conceived the idea that the radio-activity of the uranium salts examined by Becquerel is due not to the uranium itself, but to another element present with it in variable quantities. This proved to be in part true. The refuse of the first processes by which in the manufacturer’s works the uranium is extracted from its ore, pitch-blende, was found to contain four times more of the radio-active matter than does the pure uranium. By a long series of fusions, solutions, and crystallizations the Curies succeeded in ‘hunting down,’ as it were, the radio-active element. The first step gave them a powder mixed with barium chloride, and having 2,000 times the activity of the uranium in which Becquerel first proved the existence of the new property—radio-activity. Then step by step they purified it to a condition 10,000 times, then to 100,000 times, and finally to the condition of a crystalline salt having 1,800,000 times the activity of Becquerel’s sample of uranium. The purification could go no further, but the extraordinary minuteness of the quantity of the pure radio-active substance obtained and the amount of labour and time expended in preparing it may be judged of from the fact that of one ton of the pitch-blende ore submitted to the process of purification only the hundredth of a gram—the one-seventh of a grain—remained.

The amount of radium in pitch-blende is one ten-millionth per cent.; rarer than gold in sea-water. The marvel of this story and of all that follows consists largely in the skill and accuracy with which our chemists and physicists have learnt to deal with such infinitesimal quantities, and the gigantic theoretical results which are securely posed on this pin-point of substantial matter.

The Curies at once determined that the minute quantity of colourless crystals they had obtained was the chloride of a new metallic element with the atomic weight 225, to which they gave the name radium. The proof that radium is an element is given by its ‘sign-manual’—the spectrum which it shows to the observer when in the incandescent state. It consists of six bright lines and three fainter lines in the visible part of the spectrum, and of three very intense lines in the ultra-violet (invisible) part (fig. 10). A very minute quantity is enough for this observation; the lines given by radium are caused by no other known element in heaven or earth. They prove its title to be entered on the roll-call of elements.

Fig. 10.

A diagram of the visible lines of the spectrum of the elements Radium and Helium—when rendered incandescent by electric ‘sparking’ in a glass tube: kindly prepared for this book by Mr. Frederick Soddy of the University of Glasgow. The position of the chief great lines of the solar spectrum are marked on the lowest horizontal line. On the upper line the wave-lengths of the rays occupying the position indicated, are given. The figure 72 means that the wave-length of the ray occupying this position when refracted by the prism of the spectroscope is, as measured from crest to crest of the undulation, seven hundred and twenty millionths of a millimetre. It is generally written 720·0 µµ.

Lines exist at the ultra-violet end of the spectrum which can be photographed but do not affect the eye—that is to say are invisible. On the other hand the lines of the red end of the spectrum do not produce a photographic effect. Consequently a ‘photographed’ spectrum such as that given in the next figure (fig. 11) differs in the lines presented both at the red and the violet ends from the visible series of lines. The two (visible and photographed spectra) agree only from wave-length 587·6 µµ to wave-length 447·2 µµ.

The two spectra given in fig. 10 show how great is the difference in the position and number of the bands of Radium and Helium—yet as shown in the next figure (fig. 11) the ‘emanation’ from Radium actually is transformed into Helium.

The atomic weight was determined in the usual way by precipitating the chlorine in a solution of radium chloride by means of silver. None of the precious element was lost in the process, but the Curies never had enough of it to venture on any attempt to prepare pure metallic radium. This is a piece of extravagance no one has yet dared to undertake. Altogether the Curies did not have more than some four or five grains of chloride of radium to experiment with, and the total amount prepared and now in the hands of scientific men in various parts of the world probably does not amount to more than sixty grains at most. When Professor Curie lectured on radium four years ago at the Royal Institution in London he made use of a small tube an inch long and of one-eighth bore, containing nearly the whole of his precious store, wrenched by such determined labour and consummate skill from tons of black shapeless pitch-blende. On his return to Paris he was one day demonstrating in his lecture room with this precious tube the properties of radium when it slipped from his hands, broke, and scattered far and wide the most precious and magical powder ever dreamed of by alchemist or artist of romance. Every scrap of dust was immediately and carefully collected, dissolved, and re-crystallized, and the disaster averted with a loss of but a minute fraction of the invaluable product.

Thus, then, we have arrived at the discovery of radium—the new element endowed in an intense form with the new property ‘radio-activity’ discovered by Becquerel. The wonder of this powder, incessantly and without loss, under any and all conditions pouring forth by virtue of its own intrinsic property powerful rays capable of penetrating opaque bodies and of exciting phosphorescence and acting on photographic plates, can perhaps be realized when we reflect that it is as marvelous as though we should dig up a stone which without external influence or change, continually poured forth light or heat, manufacturing both in itself, and not only continuing to do so without appreciable loss or change, but necessarily having always done so for countless ages whilst sunk beyond the ken of man in the bowels of the earth.

Wonderful as the story is, so far it is really simple and commonplace compared with what yet remains to be told. I will only barely and abruptly state the fact that radio-activity has been discovered in other elements, some very rare, such as actinium and polonium; others more abundant and already known, such as thorium and uranium, though their radio-activity was not known until Becquerel’s pioneer-discovery. It is a little strange and no doubt significant that, after all, pure uranium is found to have a radio-activity of its own and not to have been altogether usurping the rights of its infinitesimal associate.

The wonders connected with radium really begin when the experimental examination of the properties of a few grains is made. What I am saying here is not a systematic, technical account of radium; so I shall venture to relate some of the story as it impresses me.

Leaving aside for a moment what has been done in regard to the more precise examination of the rays emitted by radium, the following astonishing facts have been found out in regard to it: (1) If a glass tube containing radium is much handled or kept in the waistcoat pocket, it produces a destruction of the skin and flesh over a small area—in fact, a sore place. (2) The smallest trace of radium brought into a room where a charged electroscope is present, causes the discharge of the electroscope. So powerful is this electrical action of radium that a very sensitive electrometer can detect the presence of a quantity of radium five hundred thousand times more minute than that which can be detected by the spectroscope (that is to say, by the spectroscopic examination of a flame in which minute traces of radium are present). (3) Radium actually realizes one of the properties of the hypothetical stone to which I compared it, giving out light and heat. For it does give out heat which it makes itself incessantly and without appreciable loss of substance or energy (‘appreciable’ is here an important qualifying term). It is also faintly self-luminous. Fairly sensitive thermometers show that a few granules of radium salt have always a higher temperature than that of surrounding bodies. Radium has been proved to give out enough heat to melt rather more than its own weight of ice every hour; enough heat in one hour to raise its own weight of water from the freezing-point to the boiling-point. After a year and six weeks a gram of radium has emitted enough heat to raise the temperature of a thousand kilograms of water one degree. And this is always going on. Even a small quantity of radium diffused through the earth will suffice to keep up its temperature against all loss by radiation! If the sun consists of a fraction of one per cent. of radium this will account for and make good the heat that is annually lost by it.

This is a tremendous fact, upsetting all the calculations of physicists as to the duration in past and future of the sun’s heat and the temperature of the earth’s surface. The geologists and the biologists have long contended that some thousand million years must have passed during which the earth’s surface has presented approximately the same conditions of temperature as at present, in order to allow time for the evolution of living things and the formation of the aqueous deposits of the earth’s crust. The physicists, notably Professor Tait and Lord Kelvin, refused to allow more than ten million years (which they subsequently increased to a hundred million)—basing this estimate on the rate of cooling of a sphere of the size and composition of the earth. They have assumed that its material is self-cooling. But, as Huxley pointed out, mathematics will not give a true result when applied to erroneous data. It has now, within these last five years, become evident that the earth’s material is not self-cooling, but on the contrary self-heating. And away go the restrictions imposed by physicists on geological time. They now are willing to give us not merely a thousand million years, but as many more as we want.

And now I have to mention the strangest of all the proceedings of radium—a proceeding in which the other radio-active bodies, actinium and thorium, resemble it. This proceeding has been entirely Rutherford’s discovery in Canada, and his name must be always associated with it. Radium (he discovered) is continually giving off, apart from and in addition to the rectilinear darting rays of Becquerel—an ‘emanation’—a gaseous ‘emanation.’ This ‘emanation’ is radio-active—that is, gives off Becquerel rays—and deposits ‘something’ upon bodies brought near the radium so that they become radio-active, and remain so for a time after the radium is itself removed. This emanation is always being formed by a radium salt, and may be most easily collected by dissolving the salt in water, when it comes away with a rush, as a gas. Sixty milligrams of bromide of radium yielded to Ramsay and Soddy ·124 (or about one-eighth) of a cubic millimetre of this gaseous emanation. What is it? It cannot be destroyed or altered by heat or by chemical agents; it is a heavy gas, having a molecular density of 100, and it can be condensed to a liquid by exposing it to the great cold of liquid air. It gives a peculiar spectrum of its own, and is probably a hitherto unknown inert gas—a new element similar to argon. But this by no means completes its history, even so far as experiments have as yet gone. The radium emanation decays, changes its character altogether, and loses half its radio-activity every four days. Precisely at the same rate as it decays the specimen of radium salt from which it was removed forms a new quantity of emanation, having just the amount of radio-activity which has been lost by the old emanation. All is not known about the decay of the emanation, but one thing is absolutely certain, having first been discovered by Ramsay and Soddy and subsequently confirmed by independent experiment by Madame Curie. It is this: After being kept three or four days the emanation becomes, in part at least, converted into helium—the light gas (second only in the list of elements to hydrogen), the gas found twenty-five years ago by Lockyer in the sun, and since obtained in some quantities from rare radio-active minerals by Ramsay! The proof of the formation of helium from the radium emanation is, of course, obtained by the spectroscope, and its evidence is beyond assail (see fig. 11). Here, then, is the partial conversion or decay of one element, radium, through an intermediate stage into another. And not only that, but if, as seems probable, the presence of helium indicates the previous presence of radium, we have the evidence of enormous quantities of radium in the sun, for we know helium is there in vast quantity. Not only that, but inasmuch as helium has been discovered in most hot springs and in various radio-active minerals in the earth, it may be legitimately argued that no inconsiderable quantity of radium is present in the earth. Indeed, it now seems probable that there is enough radium in the sun to keep up its continual output of heat, and enough in the earth to make good its loss of heat by radiation into space, for an almost indefinite period. Other experiments of a similar kind have rendered it practically certain that radium itself is formed by a somewhat similar transformation of uranium, so that our ideas as to the permanence and immutability on this globe of the chemical elements are destroyed, and must give place to new conceptions. It seems not improbable that the final product of the radium emanation after the helium is removed is or becomes the metal lead!

Fig. 11.
A{ Tube containingB{ Tube of RadiumC{ Tube of Hydrogen
{ Helium gas derived{ emanation, a{ gas for
{ from the{ year old.{ comparison.
{ mineral Clevelandite.

Photographs of the “spark” spectra of A, Helium as extracted from the mineral Clevelandite of B, the Radium “emanation” after a year’s enclosure in the tube used and of C of Hydrogen gas: copied from the paper by Mr. F. Giesel in the Berichte der Deutschen Chemischen Gesellschaft, vol. xxxix, part 10.

The three photographs are accurately super-imposed so as to show the coincident lines.

The spectrum B of the tube containing radium emanation is the one which we are comparing with the other two. When the radium emanation was first enclosed there was only a small quantity of helium developed in it, but after keeping for a year the quantity has greatly increased. After five minutes “sparking” (passage of the electric spark through the tube) the chief lines of helium become evident but faint in intensity. The present photograph B was obtained after forty minutes sparking, and one result of that longer “sparking” has been that a minute quantity of water vapour in the tube has been broken up—so as to yield the hydrogen spectrum, which is accordingly seen accompanying the now strong and brightly developed helium spectrum.

The lines of the spectrum B which correspond with those of hydrogen are at once recognised by the juxtaposition (below) of the pure Hydrogen spectrum from another tube—C: the lines in B belonging to and indicating helium are also recognised by comparison with the pure helium spectrum of the tube A juxta-posed above. A very few of the lines in B must be due to other minimal impurities as they are not present either in A or C.

Thirteen lines of the helium spectrum are thus photographed and recognised in the radium emanation.

The following lines are present in the photographic but invisible spectrum of radium (not given in fig. 10), viz. at 381·47 µµ (the strongest line in the radium spectrum) and at 364·96 (a strong line).

In the photographic but invisible spectrum of helium there are three very faint lines between wave-length 447·2 and 443·7 (appearing as two only in our photograph); a moderately strong one at 438·8; others at 414·4, at 412·1, at 402·6, and 396·5; a very strong one is present at 388·9, and a very faint one at 381·9. All these are seen in the photograph A and also in B. Special treatment and spectroscopes reveal four other very faint lines in the helium spectrum—the one furthest in the invisible direction (that is of highest refrangibility and lowest wave-length) being placed at 318·6 (Soddy).

It must be obvious from all the foregoing that radium is very slowly, but none the less surely, destroying itself. There is a definite loss of particles which, in the course of time, must lead to the destruction of the radium, and it would seem that the large new credit on the bank of time given to biologists in consequence of its discovery has a definite, if remote, limit. With the quantities of radium at present available for experiment, the amount of loss of particles is so small, and the rate so slow, that it cannot be weighed by the most delicate balance. Nevertheless it has been calculated that radium will transform half of itself in about fifteen hundred years, and unless it were being produced in some way all of the radium now in existence would disappear much too soon to make it an important geological factor in the maintenance of the earth’s temperature. As a reply to this depreciatory statement we have the discovery by Rutherford and others that radium is continually being formed afresh, and from that particular element in connection with which it was discovered—namely, uranium. Hypotheses and experiments as to the details of this process are at this moment in full swing, and results of a momentous kind, involving the building-up of an element with high atomic weight by the interaction of elements with a lower atomic weight, are thought by some physicists to be not improbable in the immediate future.

The delicate electric test for radio-activity has been largely applied in the last few years to all sorts and conditions of matter. As a result it appears that the radium emanation is always present in our atmosphere; that the air in caves is especially rich in it, as are underground waters. Tin-foil, glass, silver, zinc, lead, copper, platinum and aluminium are, all of them, slightly radio-active. The question has been raised whether this widespread radio-activity is due to the wide dissemination of infinitesimal quantities of strong radio-active elements, or whether it is the natural intrinsic property of all matter to emit Becquerel rays. This is the immediate subject of research.

Over and above the more simply appreciable facts which I have thus narrated, there comes the necessary and difficult inquiry, What does it all mean? What are the Becquerel rays of radio-activity? What must we conceive to be the structure and mechanism of the atoms of radium and allied elements, which can not only pour forth ceaseless streams of intrinsic energy from their own isolated substance, but are perpetually, though in infinitesimal proportions, changing their elemental nature spontaneously, so as to give rise to other atoms which we recognise as other elements?

I cannot venture as an expositor into this field. It belongs to that wonderful group of men, the modern physicists, who with an almost weird power of visual imagination combine the great instrument of exact statement and mental manipulation called mathematics, and possess an ingenuity and delicacy in appropriate experiment which must fill all who even partially follow their triumphant handling of Nature with reverence and admiration. Such men now or recently among us are Kelvin, Clerk Maxwell, Crookes, Rayleigh, and J. J. Thomson.

Becquerel showed early in his study of the rays emitted by radium that some of them could be bent out of their straight path by making them pass between the poles of a powerful electro-magnet. In this way have finally been distinguished three classes of rays given off by radium: (1) the alpha rays, which are only slightly bent, and have little penetrative power; (2) the beta rays, easily bent in a direction opposite to that in which the alpha rays bend, and of considerable penetrative power; (3) the gamma rays, which are absolutely unbendable by the strongest magnetic force, and have an extraordinary penetrative power, producing a photographic effect through a foot thickness of solid iron.

The alpha rays are shown to be streams of tiny bodies positively electrified, such as are given off by gas flames and red-hot metals. The particles have about twice the mass of a hydrogen atom, and they fly off with a velocity of 20,000 miles a second; that is, 40,000 times greater than that of a rifle bullet. The heat produced by radium is ascribed to the impact of these particles of the alpha rays.

The beta rays are streams of corpuscles similar to those given off by the cathode in a vacuum tube. They are charged with negative electricity and travel at the velocity of 100,000 miles a second. They are far more minute than the alpha particles. Their mass is equal to the one-thousandth of a hydrogen atom. They produce the major part of the photographic and phosphorescent effects of the radium rays.

The gamma rays are apparently the same, or nearly the same, thing as the X-rays of Röntgen. They are probably not particles at all, but pulses or waves in the ether set up during the ejection of the corpuscles which constitute the beta rays. They produce the same effects in a much smaller degree as do the beta rays, but are more penetrating.

The kind of conceptions to which these and like discoveries have led the modern physicist in regard to the character of that supposed unbreakable body—the chemical atom—the simple and unaffected friend of our youth—are truly astounding. Nevertheless, they are not destructive of our previous conceptions, but rather elaborations and developments of the simpler views, introducing the notion of structure and mechanism, agitated and whirling with tremendous force, into what we formerly conceived of as homogeneous or simply built-up particles, the earlier conception being not so much a positive assertion of simplicity as a non-committal expectant formula awaiting the progress of knowledge and the revelations which are now in our hands.

As I have already stated, the attempt to show in detail how the marvellous properties of radium and radio-activity in general are thus capable of a pictorial or structural representation is beyond the limits of the present essay; but the fact that such speculations furnish a scheme into which the observed phenomena can be fitted is what we may take on the authority of the physicists and chemists of our day.

Intimately connected with all the work which has been done in the past twenty-five years in the nature and possible transformations of atoms is the great series of investigations and speculations on astral chemistry and the development of the chemical elements which we owe to the unremitting labour during this period of Sir Norman Lockyer.

Wireless telegraphy.—Of great importance has been the whole progress in the theory and practical handling of electrical phenomena of late years. The discovery of the Hertzian waves and their application to wireless telegraphy is a feature of this period, though I may remind some of those who have been impressed by these discoveries that the mere fact of electrical action at a distance is that which hundreds of years ago gave to electricity its name. The power which we have gained of making an instrument oscillate in accordance with a predetermined code of signalling, although detached and a thousand miles distant, does not really lend any new support[15] to the notion that the old-time beliefs of thought-transference and second sight are more than illusions based on incomplete observation and imperfect reasoning. For the important factors in such human intercourse—namely, a signalling-instrument and a code of signals—have not been discovered, as yet in the structure of the human body, and have to be consciously devised and manufactured by man in the only examples of thought-transference over long distances at present discovered or laid bare to experiment and observation.

High and low temperatures.—The past quarter of a century has witnessed a great development and application of the methods of producing both very low and very high temperatures. Sir James Dewar, by improved apparatus, has produced liquid hydrogen and a fall of temperature probably reaching to the absolute zero. A number of applications of extremely low temperatures to research in various directions has been rendered possible by the facility with which they may now be produced. Similarly high temperatures have been employed in continuation of the earlier work of Deville, and others by Moissan, the distinguished French chemist.

Progress in Chemistry.—In chemistry generally the theoretical tendency guiding a great deal of work has been the completion and verification of the ‘periodic law’ of Mendeléeff; and, on the other hand, the search by physical agents such as light and electricity for evidence as to the arrangement of atoms in the molecules of the most diverse chemical compounds. The study of ‘valency’ and its outcome, stereo-chemistry, have been the special lines in which chemistry has advanced. As a matter of course hundreds, if not thousands, of new chemical bodies have been produced in the laboratory of greater or less theoretical interest. The discovery of the greatest practical and industrial importance in this connection is the production of indigo by synthetical processes, first by laboratory and then by factory methods, so as to compete successfully with the natural product. Von Baeyer and Heumann are the names associated with this remarkable achievement, which has necessarily dislocated a large industry which derived its raw material from British India.