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Title: Industrial Poisoning from Fumes, Gases and Poisons of Manufacturing Processes

Author: Josef Rambousek

Translator: Sir Thomas Morison Legge

Release date: November 1, 2019 [eBook #60605]
Most recently updated: October 17, 2024

Language: English

Credits: Produced by Suzanne Lybarger, Brian Janes and the Online
Distributed Proofreading Team at http://www.pgdp.net

*** START OF THE PROJECT GUTENBERG EBOOK INDUSTRIAL POISONING FROM FUMES, GASES AND POISONS OF MANUFACTURING PROCESSES ***

INDUSTRIAL POISONING

FROM FUMES, GASES AND POISONS
OF MANUFACTURING PROCESSES


BY THE SAME AUTHOR

LEAD POISONING
AND LEAD ABSORPTION:

THE SYMPTOMS, PATHOLOGY AND PREVENTION, WITH SPECIAL REFERENCE TO THEIR INDUSTRIAL ORIGIN AND AN ACCOUNT OF THE PRINCIPAL PROCESSES INVOLVING RISK.

By THOMAS M. LEGGE M.D. (Oxon.), D.P.H. (Cantab.), H.M. Medical Inspector of Factories; Lecturer on Factory Hygiene, University of Manchester; and KENNETH W. GOADBY, D.P.H. (Cantab.), Pathologist and Lecturer on Bacteriology, National Dental Hospital. Illustrated. viii+308 pp. 12s. 6d. net.

London: EDWARD ARNOLD.


INDUSTRIAL POISONING

FROM FUMES, GASES AND POISONS
OF MANUFACTURING PROCESSES

BY
DR. J. RAMBOUSEK
PROFESSOR OF FACTORY HYGIENE,
AND CHIEF STATE HEALTH OFFICER, PRAGUE

TRANSLATED AND EDITED BY
THOMAS M. LEGGE, M.D., D.P.H.
H.M. MEDICAL INSPECTOR OF FACTORIES
JOINT AUTHOR OF ‘LEAD POISONING AND LEAD ABSORPTION’

WITH ILLUSTRATIONS

LONDON
EDWARD ARNOLD
1913


TRANSLATOR’S PREFACE

I undertook the translation of Dr. Rambousek’s book because it seemed to me to treat the subject of industrial poisons in as novel, comprehensive, and systematic a manner as was possible within the compass of a single volume. Having learnt much myself from Continental writings on industrial diseases and factory hygiene, I was anxious to let others also see how wide a field they had covered and how thorough were the regulations for dangerous trades abroad, especially in Germany. A praiseworthy feature of Dr. Rambousek’s book was the wealth of references to the work of foreign writers which is made on almost every page. To have left these names and references, however, in the text as he has done would have made the translation tedious reading, and therefore for the sake of those who desire to pursue inquiry further I have adopted the course of collecting the great majority and placing them all together in an appendix at the end of the volume.

Dr. Rambousek as a medical man, a chemist, and a government official having control of industrial matters, is equipped with the very special knowledge required to describe the manufacturing processes giving rise to injurious effects, the pathology of the lesions set up, and the preventive measures necessary to combat them. In his references to work done in this country he has relied largely on abstracts which have appeared in medical and technical journals published on the Continent. I have only thought it necessary to amplify his statements when important work carried out here on industrial poisoning,—such as that on nickel carbonyl and on ferro-silicon—had been insufficiently noted. Such additions are introduced in square brackets or in footnotes.

In his preface Dr. Rambousek says ‘the book is intended for all who are, or are obliged to be, or ought to be, interested in industrial poisoning.’ No words could better describe the scope of the book.

The work of translation would never have been begun but for the assistance given me in Parts II and III by my sister, Miss H. Edith Legge. To her, and to Mr. H. E. Brothers, F.I.C., who has been to the trouble of reading the proofs and correcting many mistakes which my technical knowledge was insufficient to enable me to detect, my best thanks are due.

I am indebted to Messrs. Davidson & Co., Belfast, for permission to use figs. 46 and 48; to Messrs. Locke, Lancaster & Co., Millwall, for fig. 27; to Mr. R. Jacobson, for figs. 30, 33, 37, 38, and 43; to Messrs. Siebe, Gorman & Co., for figs. 32, 39, and 40; to Messrs. Blackman & Co. for fig. 47; to Messrs. Matthews & Yates for fig. 54; to H.M. Controller of the Stationery Office for permission to reproduce figs. 52, 53, and 54, and the diagrams on p. 284; and lastly to my publisher, for figs. 41, 42, 43, and 49, which are taken from the book by Dr. K. W. Goadby and myself on ‘Lead Poisoning and Lead Absorption.’

T. M. L.

Hampstead, May 1913.


CONTENTS

PAGE
Introduction xiii
Part I.—Description of the industries and processes attended with risk of poisoning: incidence of such poisoning
Chemical Industry 1
Sulphuric acid industry (sulphur dioxide): use of sulphuric acid 4
Its effects on health 9
Hydrochloric acid, saltcake and soda industry 14
Their effects on health 20
Use of sulphate and sulphide of soda 22
Ultramarine 22
Sulphonal 22
Diethyl sulphate 23
Chlorine, chloride of lime and chlorates 23
Their effect on health 26
Other chlorine compounds and their use as well as bromine, iodine and fluorine 29
Chlorides of phosphorus 30
Chlorides of sulphur 31
Zinc chloride 32
Rock salt 32
Organic chlorine compounds 32
Carbon oxychloride (phosgene) 32
Carbon chlorine compounds (aliphatic) 33
Methyl chloride 33
Methylene chloride 34
Carbon tetrachloride 34
Ethyl chloride 34
Monochloracetic acid 34
Chloral 34
Chloroform 34
Chloride of nitrogen 35
Cyanogen chloride 35
Chlorobenzene 35
Benzo trichloride, benzyl chloride 35
Nitro- and dinitro-chlorobenzene 35
Iodine and iodine compounds 36
Bromine and bromine compounds 36
Methyl iodide and methyl bromide 36
Fluorine compounds 37
Hydrofluoric and silicofluoric acids 38
Manufacture and uses of nitric acid 39
Its effect on health 40
Nitric and nitrous salts and compounds 44
Barium nitrate 44
Ammonium nitrate 44
Lead nitrate 44
Mercurous and mercuric nitrate 44
Silver nitrate 45
Sodium nitrite 45
Amyl nitrite 45
Manufacture of explosives and their effects 45
Fulminate of mercury 46
Nitro-glycerin 46
Dynamite 47
Gun cotton 48
Collodion cotton, smokeless powder 48
Manufacture of phosphorus and lucifer matches and their effects 49
Other uses of phosphorus and compounds of phosphorus 52
Phosphor-bronze 52
Sulphide of phosphorus 52
Phosphoretted hydrogen 52
Superphosphate and artificial manure 53
Basic slag 54
Chromium compounds and their uses 55
Sodium and potassium bichromate 55
Lead chromate and chrome colours 55
Their effect on health 56
Manganese compounds and their effects 58
Mineral oil industry and the use of petroleum and benzine 59
Chemical cleaning 61
Their effect on health 61
Recovery and use of sulphur 64
Its effect on health 65
Sulphuretted hydrogen and its effect 65
Preparation and use of carbon bisulphide in vulcanising, &c. 68
Its effect on health 69
Preparation of illuminating gas 71
Its effect on health 74
Coke ovens and risk from them 77
Other kinds of power and illuminating gas 80
Producer gas 80
Blast furnace gas 82
Water gas 82
Dowson and Mond gas 82
Suction gas 83
Acetylene (calcium carbide) 85
Their effect on health 87
Ammonia and ammonium compounds 90
Use of ammonia and its effects 92
Cyanogen compounds 93
Use of cyanide, and their effects 95
Coal tar and tar products 96
Their effects on health 101
Artificial organic dye stuffs (coal tar colours) 107
Their effects on health 112
Recovery and use of metals 120
Lead poisoning in general 120
Lead, silver and zinc smelting 122
Spelter works 125
Lead poisoning in lead smelting and spelter works 126
White lead and other use of lead colours 131
Lead poisoning in the manufacture and use of white lead and lead paints 132
Manufacture of electric accumulators 134
The ceramic industry 135
Coarse ware pottery 136
Manufacture of stove tiles 137
Stoneware and porcelain 138
Lead poisoning in letterpress printing 138
Lead poisoning in filecutting, polishing precious stones, musical instrument making, &c. 140
Mercury (poisoning in its recovery and use) 141
Mercurial poisoning in water-gilding, coating mirrors, in felt hat making, &c. 142
Arsenic (poisoning in its recovery and in use of arsenic and arsenic compounds) 143
Recovery of arsenic and white arsenic 143
Poisoning by arseniuretted hydrogen gas 145
Antimony 146
Extraction of iron 146
Ferro-silicon 149
Zinc 151
Copper, brass (brassfounders’ ague) 151
Metal pickling 152
Other Industries 153
Treatment of stone and earths; lime burning, glass 153
Treatment of animal products 154
Preparation of vegetable foodstuffs 154
Poisonous woods 154
Textile industry 156
Part II.—Pathology and treatment of industrial poisoning
Industrial poisons in general 157
Channels of absorption, classification, susceptibility, immunity 158
Fate of poisons in the body—absorption, cumulative action, excretion 162
General remarks on treatment 163
Industrial poisons in particular 169
Group: mineral acids, halogens, inorganic halogen compounds, alkalis 169
Hydrochloric acid 170
Hydrofluoric and silico-fluoric acids 171
Sulphur dioxide and sulphuric acid 171
Nitrous fumes, nitric acid 172
Chlorine, bromine, iodine 173
Chlorides of phosphorus, sulphur and zinc 174
Ammonia 175
Alkalis 176
Group: Metals and metal-compounds 176
Lead and its compounds 177
Zinc and its alloys 182
Mercury and its compounds 183
Manganese and its compounds 184
Chromium and its compounds 185
Nickel salts (nickel carbonyl) 186
Copper 188
Silver and its compounds 188
Group: Arsenic, Phosphorus 189
Arsenic and its oxides 189
Phosphorus 190
Phosphoretted hydrogen 191
Group: Sulphuretted hydrogen, carbon bisulphide, and cyanogen (nerve poisons) 192
Sulphuretted hydrogen 192
Carbon bisulphide 193
Cyanogen compounds 195
Group: Arseniuretted hydrogen and carbonic oxide (blood poisons) 197
Group: Hydrocarbons of the aliphatic and aromatic series and their halogen and hydroxyl substitution products 202
Sub-group: Hydrocarbons of mineral oils and their distillation products (benzine, paraffin, &c.) 202
Sub-group: Hydrocarbons of the aromatic series 204
Benzene and its homologues 204
Naphthalene 208
Sub-group: Halogen substitution products of the aliphatic series (narcotic poisons) 208
Sub-group: Halogen substitution products of the benzene series 209
Sub-group: Hydroxyl substitution products of the fatty series 210
Group: Nitro- and amido-derivatives of the aliphatic and aromatic series 211
Sub-group: Nitro-derivatives of the aliphatic series 212
Sub-group: Nitro- and amido-derivatives of the aromatic series 212
Turpentine, pyridene, alkaloids, nicotine, poisonous woods 215
Part III.—Preventive measures against industrial poisoning
General preventive measures 217
International action, notification of poisoning, schedules of poisons 218
Special preventive measures for workers—selection, periodical medical examination, co-operation of workers, &c. 226
Rescue appliances 230
Washing accommodation and baths 237
Removal of dust and fumes by exhaust ventilation 242
Preventive Measures in Particular Industries 256
Sulphuric acid industry 256
Hydrochloric acid and soda industries 257
Chlorine, bleaching powder, chlorine compounds 259
Manufacture of nitric acid and explosives 260
Artificial manures, basic slag 261
Chromium and its compounds 265
Petroleum, benzine 267
Phosphorus, lucifer matches 268
Bisulphide of carbon 271
Illuminating gas, tar production 275
Gas power plant 276
Acetylene gas installations 278
Ammonia 279
Cyanogen, cyanogen compounds 280
Coal tar, tar products 280
Organic dye-stuffs, coal tar colours 285
Recovery and use of metals 288
Iron 289
Lead 292
Lead smelting 299
Electric accumulators 305
White lead and lead colours 310
Letterpress printing 316
Ceramic industry 319
File cutting 321
Other uses of lead 322
Zinc smelting 323
Brass casting, metal pickling 325
Recovery and use of mercury 326
Arsenic and its compounds 328
Gold and silver 329
Preventive Measures in other trades 329
Manufacture and use of varnishes 330
Production of vegetable foods 332
Wood working 335
Paper manufacture 336
Textile industries 336
Appendix 339
Index 355


INTRODUCTION

The attempt to systematise from the scientific standpoint the mass of material that has been collected about poisons is a very heavy task, even for the toxicologist who desires to treat his subject comprehensively. How much greater is the difficulty of writing a systematic book on industrial poisoning keeping practical application in the forefront!

Technical considerations which are decisive in the causation and prevention of industrial poisoning are here of especial moment, and must naturally influence classification of the subject-matter when the object is to assist those concerned in factory hygiene.

Bearing this in mind, I have divided the subject into three parts. The arrangement of the first, which gives as complete a statement as possible of the occurrence of industrial poisoning, into industries and processes was determined on technical grounds. The second, which amplifies the first, attempts to summarise the pathology or symptoms of the various forms of poisoning. The references to the literature of the particular subjects—as exhaustive as I could make them—will lighten further study. To these two parts, following on knowledge of causation and symptoms, the third, in which preventive measures are outlined, is linked.

The apparent drawback in use of the book is that one form of poisoning has often to be referred to in three places. But, I hope, this is more than counterbalanced by the completeness of the scheme which results from the subdivision of the subject.

The pathology of industrial poisoning necessitates frequent repetition when describing the branches of industry giving rise to the intoxication, as one and the same form can occur in the most varied processes. The numerous instances of actual cases of poisoning quoted must therefore be regarded as conforming to the same pathological type. Similarly, preventive measures require separate systematic treatment in order to avoid constant repetition which would otherwise obscure the general survey. Quite a number of means of prevention apply equally to several industries in which the same cause is at work. The success attained by thus simplifying the issues is the greater because such common measures are the easier to carry through and to supervise.

The method therefore has been adopted only after serious reflection and has been directed mainly by practical considerations.

Recent cases which have either been reported or come to the knowledge of the author have been given, with particulars as exact as possible. Cases dating back some time have been omitted intentionally so as to exclude everything which did not correspond with the present conditions of industry and trade. Historical facts only receive consideration in so far as they are fundamentally important and necessary for the sake of completeness.

The details given in Part I of actual instances will supply material for fresh efforts, renewed investigation, and new points of attack.