[2nd Ed.] [After a careful re-consideration of Sir D. Brewster’s asserted analysis of the solar light into three colors by means of 66 absorbing media, I cannot consider that he has established his point as an exception to Newton’s doctrine. In the first place, the analysis of light into three colors appears to be quite arbitrary, granting all his experimental facts. I do not see why, using other media, he might not just as well have obtained other elementary colors. In the next place, this cannot be called an analysis in the same sense as Newton’s analysis, except the relation between the two is shown. Is it meant that Newton’s experiments prove nothing? Or is Newton’s conclusion allowed to be true of light which has not been analysed by absorption? And where are we to find such light, since the atmosphere absorbs? But, I must add, in the third place, that with a very sincere admiration of Sir D. Brewster’s skill as an experimenter, I think his experiment requires, not only limitation, but confirmation by other experimenters. Mr. Airy repeated the experiments with about thirty different absorbing substances, and could not satisfy himself that in any case they changed the color of a ray of given refractive power. These experiments were described by him at a meeting of the Cambridge Philosophical Society.]
We now proceed to the corrections which the next generation introduced into the details of this doctrine.
THE discovery that the laws of refractive dispersion of different substances were such as to allow of combinations which neutralised the dispersion without neutralizing the refraction, is one which has hitherto been of more value to art than to science. The property has no definite bearing, which has yet been satisfactorily explained, upon the theory of light; but it is of the greatest importance in its application to the construction of telescopes; and it excited the more notice, in consequence of the prejudices and difficulties which for a time retarded the discovery.
Newton conceived that he had proved by experiment,31 that light 67 is white after refraction, when the emergent rays are parallel to the incident, and in no other case. If this were so, the production of colorless images by refracting media would be impossible; and such, in deference to Newton’s great authority, was for some time the general persuasion. Euler32 observed, that a combination of lenses which does not color the image must be possible, since we have an example of such a combination in the human eye; and he investigated mathematically the conditions requisite for such a result. Klingenstierna,33 a Swedish mathematician, also showed that Newton’s rule could not be universally true. Finally, John Dollond,34 in 1757, repeated Newton’s experiment, and obtained an opposite result. He found that when an object was seen through two prisms, one of glass and one of water, of such angles that it did not appear displaced by refraction, it was colored. Hence it followed that, without being colored, the rays might be made to undergo refraction; and that thus, substituting lenses for prisms, a combination might be formed, which should produce an image without coloring it, and make the construction of an achromatic telescope possible.
Euler at first hesitated to confide in Dollond’s experiments; but he was assured of their correctness by Clairaut, who had throughout paid great attention to the subject; and those two great mathematicians, as well as D’Alembert, proceeded to investigate mathematical formulæ which might be useful in the application of the discovery. The remainder of the deductions, which were founded upon the laws of dispersion of various refractive substances, belongs rather to the history of art than of science. Dollond used at first, for his achromatic object-glass, a lens of crown-glass, and one of flint-glass. He afterwards employed two lenses of the former substance, including between them one of the latter, adjusting the curvatures of his lenses in such a way as to correct the imperfections arising from the spherical form of the glasses, as well as the fault of color. Afterwards, Blair used fluid media along with glass lenses, in order to produce improved object-glasses. This has more recently been done in another form by Mr. Barlow. The inductive laws of refraction being established, their results have been deduced by various mathematicians, as Sir J. Herschel and Professor Airy among ourselves, who have simplified and extended the investigation of the formulæ which determine the best combination of lenses in the object-glasses and eye-glasses of 68 telescopes, both with reference to spherical and to chromatic aberrations.
According to Dollond’s discovery, the colored spectra produced by prisms of two substances, as flint-glass and crown-glass, would be of the same length when the refraction was different. But a question then occurred: When the whole distance from the red to the violet in one spectrum was the same as the whole distance in the other, were the intermediate colors, yellow, green, &c., in corresponding places in the two? This point also could not be determined any otherwise than by experiment. It appeared that such a correspondence did not exist; and, therefore, when the extreme colors were corrected by combinations of the different media, there still remained an uncorrected residue of color arising from the rest of the spectrum. This defect was a consequence of the property, that the spectra belonging to different media were not divided in the same ratio by the same colors, and was hence termed the irrationality of the spectrum. By using three prisms, or three lenses, three colors may be made to coincide instead of two, and the effects of this irrationality greatly diminished.
For the reasons already mentioned, we do not pursue this subject further,35 but turn to those optical facts which finally led to a great and comprehensive theory.
[2nd Ed.] [Mr. Chester More Hall, of More Hall, in Essex, is said to have been led by the study of the human eye, which he conceived to be achromatic, to construct achromatic telescopes as early as 1729. Mr. Hall, however, kept his invention a secret. David Gregory, in his Catoptrics (1713), had suggested that it would perhaps be an improvement of telescopes, if, in imitation of the human eye, the object-glass were composed of different media. Encyc. Brit. art. Optics.
It is said that Clairaut first discovered the irrationality of the colored spaces in the spectrum. In consequence of this irrationality, it follows that when two refracting media are so combined as to correct each other’s extreme dispersion, (the separation of the red and violet rays,) this first step of correction still leaves a residue of 69 coloration arising from the unequal dispersion of the intermediate rays (the green, &c.). These outstanding colors, as they were termed by Professor Robison, form the residual, or secondary spectrum.
Dr. Blair, by very ingenious devices, succeeded in producing an object-glass, corrected by a fluid lens, in which this aberration of color was completely corrected, and which performed wonderfully well.
The dispersion produced by a prism may be corrected by another prism of the same substance and of a different angle. In this case also there is an irrationality in the colored spaces, which prevents the correction of color from being complete; and hence, a new residuary spectrum, which has been called the tertiary spectrum, by Sir David Brewster, who first noticed it.
I have omitted, in the notice of discoveries respecting the spectrum, many remarkable trains of experimental research, and especially the investigations respecting the power of various media to absorb the light of different parts of the spectrum, prosecuted by Sir David Brewster with extraordinary skill and sagacity. The observations are referred to in chapter iii. Sir John Herschel, Prof. Miller, Mr. Daniel, Dr. Faraday, and Mr. Talbot, have also contributed to this part of our knowledge.]
THE laws of refraction which we have hitherto described, were simple and uniform, and had a symmetrical reference to the surface of the refracting medium. It appeared strange to men, when their attention was drawn to a class of phenomena in which this symmetry was wanting, and in which a refraction took place which was not even in the plane of incidence. The subject was not unworthy the notice and admiration it attracted; for the prosecution of it ended in the discovery of the general laws of light. The phenomena of which I now speak, are those exhibited by various kinds of crystalline bodies; but observed for a long time in one kind only, namely, the rhombohedral calc-spar; or, as it was usually termed, from the country which supplied the largest and clearest crystals, Iceland spar. These 70 rhombohedral crystals are usually very smooth and transparent, and often of considerable size; and it was observed, on looking through them, that all objects appeared double. The phenomena, even as early as 1669, had been considered so curious, that Erasmus Bartholin published a work upon them at Copenhagen,36 (Experimenta Crystalli Islandici, Hafniæ, 1669.) He analysed the phenomena into their laws, so far as to discover that one of the two images was produced by refraction after the usual rule, and the other by an unusual refraction. This latter refraction Bartholin found to vary in different positions; to be regulated by a line parallel to the sides of the rhombohedron; and to be greatest in the direction of a line bisecting two of the angles of the rhombic face of the crystal.
These rules were exact as far as they went; and when we consider how geometrically complex the law is, which really regulates the unusual or extraordinary refraction;—that Newton altogether mistook it, and that it was not verified till the experiments of Haüy and Wollaston in our own time;—we might expect that it would not be soon or easily detected. But Huyghens possessed a key to the secret, in the theory, which he had devised, of the propagation of light by undulations, and which he conceived with perfect distinctness and correctness, so far as its application to these phenomena is concerned. Hence he was enabled to lay down the law of the phenomena (the only part of his discovery which we have here to consider), with a precision and success which excited deserved admiration, when the subject, at a much later period, regained its due share of attention. His Treatise was written37 in 1678, but not published till 1690.
The laws of the ordinary and the extraordinary refraction in Iceland spar are related to each other; they are, in fact, similar constructions, made, in the one case, by means of an imaginary sphere, in the other, by means of a spheroid; the spheroid being of such oblateness as to suit the rhombohedral form of the crystal, and the axis of the spheroid being the axis of symmetry of the crystal. Huyghens followed this general conception into particular positions and conditions; and thus obtained rules, which he compared with observation, for cutting the crystal and transmitting the rays in various manners. “I have examined in detail,” says he,38 “the properties of the 71 extraordinary refraction of this crystal, to see if each phenomenon which is deduced from theory, would agree with what is really observed. And this being so, it is no slight proof of the truth of our suppositions and principles; but what I am going to add here confirms them still more wonderfully; that is, the different modes of cutting this crystal, in which the surfaces produced give rise to refractions exactly such as they ought to be, and as I had foreseen them, according to the preceding theory.”
Statements of this kind, coming from a philosopher like Huyghens, were entitled to great confidence; Newton, however, appears not to have noticed, or to have disregarded them. In his Opticks, he gives a rule for the extraordinary refraction of Iceland spar which is altogether erroneous, without assigning any reason for rejecting the law published by Huyghens; and, so far as appears, without having made any experiments of his own. The Huyghenian doctrine of double refraction fell, along with his theory of undulations, into temporary neglect, of which we shall have hereafter to speak. But in 1788, Haüy showed that Huyghens’s rule agreed much better than Newton’s with the phenomena: and in 1802, Wollaston, applying a method of his own for measuring refraction, came to the same result. “He made,” says Young,39 “a number of accurate experiments with an apparatus singularly well calculated to examine the phenomena, but could find no general principle to connect them, until the work of Huyghens was pointed out to him.” In 1808, the subject of double refraction was proposed as a prize-question by the French Institute; and Malus, whose Memoir obtained the prize, says, “I began by observing and measuring a long series of phenomena on natural and artificial faces of Iceland spar. Then, testing by means of these observations the different laws proposed up to the present time by physical writers, I was struck with the admirable agreement of the law of Huyghens with the phenomena, and I was soon convinced that it is really the law of nature.” Pursuing the consequences of the law, he found that it satisfied phenomena which Huyghens himself had not observed. From this time, then, the truth of the Huyghenian law was universally allowed, and soon afterwards, the theory by which it had been suggested was generally received.
The property of double refraction had been first studied only in Iceland spar, in which it is very obvious. The same property belongs, 72 though less conspicuously, to many other kinds of crystals. Huyghens had noticed the same fact in rock-crystal;40 and Malus found it to belong to a large list of bodies besides; for instance, arragonite, sulphate of lime, of baryta, of strontia, of iron; carbonate of lead; zircon, corundum, cymophane, emerald, euclase, felspar, mesotype, peridote, sulphur, and mellite. Attempts were made, with imperfect success, to reduce all these to the law which had been established for Iceland spar. In the first instance, Malus took for granted that the extraordinary refraction depended always upon an oblate spheroid; but M. Biot41 pointed out a distinction between two classes of crystals in which this spheroid was oblong and oblate respectively, and these he called attractive and repulsive crystals. With this correction, the law could be extended to a considerable number of cases; but it was afterwards proved by Sir D. Brewster’s discoveries, that even in this form, it belonged only to substances of which the crystallization has relation to a single axis of symmetry, as the rhombohedron, or the square pyramid. In other cases, as the rhombic prism, in which the form, considered with reference to its crystalline symmetry, is biaxal, the law is much more complicated. In that case, the sphere and the spheroid, which are used in the construction for uniaxal crystals, transform themselves into the two successful convolutions of a single continuous curve surface; neither of the two rays follows the law of ordinary refraction; and the formula which determines their position is very complex. It is, however, capable of being tested by measures of the refractions of crystals cut in a peculiar manner for the purpose, and this was done by MM. Fresnel and Arago. But this complex law of double refraction was only discovered through the aid of the theory of a luminiferous ether, and therefore we must now return to the other facts which led to such a theory.
IF the Extraordinary Refraction of Iceland spar had appeared strange, another phenomenon was soon noticed in the same 73 substance, which appeared stranger still, and which in the sequel was found to be no less important. I speak of the facts which were afterwards described under the term Polarization. Huyghens was the discoverer of this class of facts. At the end of the treatise which we have already quoted, he says,42 “Before I quit the subject of this crystal, I will add one other marvellous phenomenon, which I have discovered since writing the above; for though hitherto I have not been able to find out its cause, I will not, on that account, omit pointing it out, that I may give occasion to others to examine it.” He then states the phenomena; which are, that when two rhombohedrons of Iceland spar are in parallel positions, a ray doubly refracted by the first, is not further divided when it falls on the second: the ordinarily refracted ray is ordinarily refracted only, and the extraordinary ray is only extraordinarily refracted by the second crystal, neither ray being doubly refracted. The same is still the case, if the two crystals have their principal planes parallel, though they themselves are not parallel. But if the principal plane of the second crystal be perpendicular to that of the first, the reverse of what has been described takes place; the ordinarily refracted ray of the first crystal suffers, at the second, extraordinary refraction only, and the extraordinary ray of the first suffers ordinary refraction only at the second. Thus, in each of these positions, the double refraction of each ray at the second crystal is reduced to single refraction, though in a different manner in the two cases. But in any other position of the crystals, each ray, produced by the first, is doubly refracted by the second, so as to produce four rays.
A step in the right conception of these phenomena was made by Newton, in the second edition of his Opticks (1717). He represented them as resulting from this;—that the rays of light have “sides,” and that they undergo the ordinary or extraordinary refraction, according as these sides are parallel to the principal plane of the crystal, or at right angles to it (Query 26). In this way, it is clear, that those rays which, in the first crystal, had been selected for extraordinary refraction, because their sides were perpendicular to the principal plane, would all suffer extraordinary refraction at the second crystal for the same reason, if its principal plane were parallel to that of the first; and would all suffer ordinary refraction, if the principal plane of the second crystal were perpendicular to that of the first, and 74 consequently parallel to the sides of the refracted ray. This view of the subject includes some of the leading features of the case, but still leaves several considerable difficulties.
No material advance was made in the subject till it was taken up by Malus,43 along with the other circumstances of double refraction, about a hundred years afterwards. He verified what had been observed by Huyghens and Newton, on the subject of the variations which light thus exhibits; but he discovered that this modification, in virtue of which light undergoes the ordinary, or the extraordinary, refraction, according to the position of the plane of the crystal, may be impressed upon it many other ways. One part of this discovery was made accidentally.44 In 1808, Malus happened to be observing the light of the setting sun, reflected from the windows of the Luxembourg, through a rhombohedron of Iceland spar; and he observed that in turning round the crystal, the two images varied in their intensity. Neither of the images completely vanished, because the light from the windows was not properly modified, or, to use the term which Malus soon adopted, was not completely polarized. The complete polarization of light by reflection from glass, or any other transparent substance, was found to take place at a certain definite angle, different for each substance. It was found also that in all crystals in which double refraction occurred, the separation of the refracted rays was accompanied by polarization; the two rays, the ordinary and the extraordinary, being always polarized oppositely, that is, in planes at right angles to each other. The term poles, used by Malus, conveyed nearly the same notion as the term sides which had been employed by Newton, with the additional conception of a property which appeared or disappeared according as the poles of the particles were or were not in a certain direction; a property thus resembling the polarity of magnetic bodies. When a spot of polarized light is looked at through a transparent crystal of Iceland spar, each of the two images produced by the double refraction varies in brightness as the crystal is turned round. If, for the sake of example, we suppose the crystal to be turned round in the direction of the points of the compass, N, E, S, W, and if one image be brightest when the crystal marks N and S, it will disappear when the crystal marks E and W: and on the contrary, the second image will vanish when the crystal marks N and S, 75 and will be brightest when the crystal marks E and W. The first of these images is polarized in the plane NS passing through the ray, and the second in the plane EW, perpendicular to the other. And these rays are oppositely polarized. It was further found that whether the ray were polarized by reflection from glass, or from water, or by double refraction, the modification of light so produced, or the nature of the polarization, was identical in all these cases;—that the alternatives of ordinary and extraordinary refraction and non-refraction, were the same, by whatever crystal they were tested, or in whatever manner the polarization had been impressed upon the light; in short, that the property, when once acquired, was independent of everything except the sides or poles of the ray; and thus, in 1811, the term “polarization” was introduced.45
This being the state of the subject, it became an obvious question, by what other means, and according to what laws, this property was communicated. It was found that some crystals, instead of giving, by double refraction, two images oppositely polarized, give a single polarized image. This property was discovered in the agate by Sir D. Brewster, and in tourmaline by M. Biot and Dr. Seebeck. The latter mineral became, in consequence, a very convenient part of the apparatus used in such observations. Various peculiarities bearing upon this subject, were detected by different experimenters. It was in a short time discovered, that light might be polarized by refraction, as well as by reflection, at the surface of uncrystallized bodies, as glass; the plane of polarization being perpendicular to the plane of refraction; further, that when a portion of a ray of light was polarized by reflection, a corresponding portion was polarized by transmission, the planes of the two polarizations being at right angles to each other. It was found also that the polarization which was incomplete with a single plate, either by reflection or refraction, might be made more and more complete by increasing the number of plates.
Among an accumulation of phenomena like this, it is our business to inquire what general laws were discovered. To make such discoveries without possessing the general theory of the facts, required no ordinary sagacity and good fortune. Yet several laws were detected at this stage of the subject. Malus, in 1811, obtained the important generalization that, whenever we obtain, by any means, a polarized ray of light, we produce also another ray, polarized in a contrary 76 direction; thus when reflection gives a polarized ray, the companion-ray is refracted polarized oppositely, along with a quantity of unpolarized light. And we must particularly notice Sir D. Brewster’s rule for the polarizing angle of different bodies.
Malus46 had said that the angle of reflection from transparent bodies which most completely polarizes the reflected ray, does not follow any discoverable rule with regard to the order of refractive or dispersive powers of the substances. Yet the rule was in reality very simple. In 1815, Sir D. Brewster stated47 as the law, which in all cases determines this angle, that “the index of refraction is the tangent of the angle of polarization.” It follows from this, that the polarization takes place when the reflected and refracted rays are at right angles to each other. This simple and elegant rule has been fully confirmed by all subsequent observations, as by those of MM. Biot and Seebeck; and must be considered one of the happiest and most important discoveries of the laws of phenomena in Optics.
The rule for polarization by one reflection being thus discovered, tentative formulæ were proposed by Sir D. Brewster and M. Biot, for the cases in which several reflections or refractions take place. Fresnel also in 1817 and 1818, traced the effect of reflection in modifying the direction of polarization, which Malus had done inaccurately in 1810. But the complexity of the subject made all such attempts extremely precarious, till the theory of the phenomena was understood, a period which now comes under notice. The laws which we have spoken of were important materials for the establishment of the theory; but in the mean time, its progress at first had been more forwarded by some other classes of facts, of a different kind, and of a longer standing notoriety, to which we must now turn our attention.
THE facts which we have now to consider are remarkable, inasmuch as the colours are produced merely by the smallness of dimensions of the bodies employed. The light is not analysed by any peculiar 77 property of the substances, but dissected by the minuteness of their parts. On this account, these phenomena give very important indications of the real structure of light; and at an early period, suggested views which are, in a great measure, just.
Hooke appears to be the first person who made any progress in discovering the laws of the colors of thin plates. In his Micrographia, printed by the Royal Society in 1664, he describes, in a detailed and systematic manner, several phenomena of this kind, which he calls “fantastical colors.” He examined them in Muscovy glass or mica, a transparent mineral which is capable of being split into the exceedingly thin films which are requisite for such colors; he noticed them also in the fissures of the same substance, in bubbles blown of water, rosin, gum, glass; in the films on the surface of tempered steel; between two plane pieces of glass; and in other cases. He perceived also,48 that the production of each color required a plate of determinate thickness, and he employed this circumstance as one of the grounds of his theory of light.
Newton took up the subject where Hooke had left it; and followed it out with his accustomed skill and clearness, in his Discourse on Light and Colors, communicated to the Royal Society in 1675. He determined, what Hooke had not ascertained, the thickness of the film which was requisite for the production of each color; and in this way explained, in a complete and admirable manner, the colored rings which occur when two lenses are pressed together, and the scale of color which the rings follow; a step of the more consequence, as the same scale occurs in many other optical phenomena.
It is not our business here to state the hypothesis with regard to the properties of light which Newton founded on these facts;—the “fits of easy transmission and reflection.” We shall see hereafter that his attempted induction was imperfect; and his endeavor to account, by means of the laws of thin plates, for the colors of natural bodies, is altogether unsatisfactory. But notwithstanding these failures in the speculations on this subject, he did make in it some very important steps; for he clearly ascertained that when the thickness of the plate was about 1⁄178000th of an inch, or three times, five times, seven times that magnitude, there was a bright color produced; but blackness, when the thickness was exactly intermediate between those magnitudes. He found, also, that the thicknesses which gave red and 78 violet49 were as fourteen to nine; and the intermediate colors of course corresponded to intermediate thicknesses, and therefore, in his apparatus, consisting of two lenses pressed together, appeared as rings of intermediate sizes. His mode of confirming the rule, by throwing upon this apparatus differently colored homogeneous light, is striking and elegant. “It was very pleasant,” he says, “to see the rings gradually swell and contract as the color of the light was changed.”
It is not necessary to enter further into the detail of these phenomena, or to notice the rings seen by transmission, and other circumstances. The important step made by Newton in this matter was, the showing that the rays of light, in these experiments, as they pass onwards go periodically through certain cycles of modification, each period occupying nearly the small fraction of an inch mentioned above; and this interval being different for different colors. Although Newton did not correctly disentangle the conditions under which this periodical character is manifestly disclosed, the discovery that, under some circumstances, such a periodical character does exist, was likely to influence, and did influence, materially and beneficially, the subsequent progress of Optics towards a connected theory.
We must now trace this progress; but before we proceed to this task, we will briefly notice a number of optical phenomena which had been collected, and which waited for the touch of sound theory to introduce among them that rule and order which mere observation had sought for in vain.
THE phenomena which result from optical combinations, even of a comparatively simple nature, are extremely complex. The theory which is now known accounts for these results with the most curious exactness, and points out the laws which pervade the apparent confusion; but without this key to the appearances, it was scarcely possible that any rule or order should be detected. The undertaking was of 79 the same kind as it would have been, to discover all the inequalities of the moon’s motion without the aid of the doctrine of gravity. We will enumerate some of the phenomena which thus employed and perplexed the cultivators of optics.
The fringes of shadows were one of the most curious and noted of such classes of facts. These were first remarked by Grimaldi50 (1665), and referred by him to a property of light which he called Diffraction. When shadows are made in a dark room, by light admitted through a very small hole, these appearances are very conspicuous and beautiful. Hooke, in 1672, communicated similar observations to the Royal Society, as “a new property of light not mentioned by any optical writer before;” by which we see that he had not heard of Grimaldi’s experiments. Newton, in his Opticks, treats of the same phenomena, which he ascribes to the inflexion of the rays of light. He asks (Qu. 3), “Are not the rays of light, in passing by the edges and sides of bodies, bent several times backward and forward with a motion like that of an eel? And do not the three fringes of colored light in shadows arise from three such bendings?” It is remarkable that Newton should not have noticed, that it is impossible, in this way, to account for the facts, or even to express their laws; since the light which produces the fringes must, on this theory, be propagated, even after it leaves the neighborhood of the opake body, in curves, and not in straight lines. Accordingly, all who have taken up Newton’s notion of inflexion, have inevitably failed in giving anything like an intelligible and coherent character to these phenomena. This is, for example, the case with Mr. (now Lord) Brougham’s attempts in the Philosophical Transactions for 1796. The same may be said of other experimenters, as Mairan51 and Du Four,52 who attempted to explain the facts by supposing an atmosphere about the opake body. Several authors, as Maraldi,53 and Comparetti,54 repeated or varied these experiments in different ways.
Newton had noticed certain rings of color produced by a glass speculum, which he called “colors of thick plates,” and which he attempted to connect with the colors of thin plates. His reasoning is by no means satisfactory; but it was of use, by pointing out this as a case in which his “fits” (the small periods, or cycles in the rays of light, of 80 which we have spoken) continued to occur for a considerable length of the ray. But other persons, attempting to repeat his experiments, confounded with them extraneous phenomena of other kinds; as the Duc de Chaulnes, who spread muslin before his mirror,55 and Dr. Herschel, who scattered hair-powder before his.56 The colors produced by the muslin were those belonging to shadows of gratings, afterwards examined more successfully by Fraunhofer, when in possession of the theory. We may mention here also the colors which appear on finely-striated surfaces, and on mother-of-pearl, feathers, and similar substances. These had been examined by various persons (as Boyle, Mazeas, Lord Brougham), but could still, at this period, be only looked upon as insulated and lawless facts.
BESIDES the above-mentioned perplexing cases of colors produced by common light, cases of periodical colors produced by polarized light began to be discovered, and soon became numerous. In August, 1811, M. Arago communicated to the Institute of France an account of colors seen by passing polarized light through mica, and analysing57 it with a prism of Iceland spar. It is remarkable that the light which produced the colors in this case was the light polarized by the sky, a cause of polarization not previously known. The effect which the mica thus produced was termed depolarization;—not a very happy term, since the effect is not the destruction of the polarization, but the combination of a new polarizing influence with the former. The word dipolarization, which has since been proposed, is a much more appropriate expression. Several other curious phenomena of the same kind were observed in quartz, and in flint-glass. M. Arago was not able to reduce these phenomena to laws, but he had a full conviction of their value, and ventures to class them with the great steps in 81 this part of optics. “To Bartholin we owe the knowledge of double refraction; to Huyghens, that of the accompanying polarization; to Malus, polarization by reflection; to Arago, depolarization.” Sir D. Brewster was at the same time engaged in a similar train of research; and made discoveries of the same nature, which, though not published till some time after those of Arago, were obtained without a knowledge of what had been done by him. Sir D. Brewster’s Treatise on New Philosophical Instruments, published in 1813, contains many curious experiments on the “depolarizing” properties of minerals. Both these observers noticed the changes of color which are produced by changes in the position of the ray, and the alternations of color in the two oppositely polarized images; and Sir D. Brewster discovered that, in topaz, the phenomena had a certain reference to lines which he called the neutral and depolarizing axes. M. Biot had endeavored to reduce the phenomena to a law; and had succeeded so far, that he found that in the plates of sulphate of lime, the place of the tint, estimated in Newton’s scale (see ante, chap. vii.), was as the square of the sine of the inclination. But the laws of these phenomena became much more obvious when they were observed by Sir D. Brewster with a larger field of view.58 He found that the colors of topaz, under the circumstances now described, exhibited themselves in the form of elliptical rings, crossed by a black bar, “the most brilliant class of phenomena,” as he justly says, “in the whole range of optics.” In 1814, also, Wollaston observed the circular rings with a black cross, produced by similar means in calc-spar; and M. Biot, in 1815, made the same observation. The rings in several of these cases were carefully measured by M. Biot and Sir D. Brewster, and a great mass of similar phenomena was discovered. These were added to by various persons, as M. Seebeck, and Sir John Herschel.