THE PHILOSOPHY OF THE MECHANICO-CHEMICAL SCIENCES.
1. IN some of the mechanical sciences, as Magnetism and Optics, the phenomena are found to depend upon position (the position of the magnet, or of the ray of light,) in a peculiar alternate manner. This dependence, as it was first apprehended, was represented by means of certain conceptions of space and force, as for instance by considering the two Poles of a magnet. But in all such modes of representing these alternations by the conceptions borrowed from other ideas, a closer examination detected something superfluous and something defective; and in proportion as the view which philosophers took of this relation was gradually purified from these incongruous elements, and was rendered more general and abstract by the discovery of analogous properties in new cases, it was perceived that the relation could not be adequately apprehended without considering it as involving a peculiar and independent Idea, which we may designate by the term Polarity.
We shall trace some of the forms in which this Idea has manifested itself in the history of science. In doing so we shall not begin, as in other Books of this work we have done, by speaking of the notion as it is 360 employed in common use: for the relation of Polarity is of so abstract and technical a nature, that it is not employed, at least in any distinct and obvious manner, on any ordinary or practical occasions. The idea belongs peculiarly to the region of speculation: in persons of common habits of thought it is probably almost or quite undeveloped; and even most of those whose minds have been long occupied by science, find a difficulty in apprehending it in its full generality and abstraction, and stript of all irrelevant hypothesis.
2. Magnetism.—The name and the notion of Poles were first adopted in the case of a magnet. If we have two magnets, their extremities attract and repel each other alternatively. If the first end of the one attract the first end of the other, it repels the second end, and conversely. In order to express this rule conveniently, the two ends of each magnet are called the north pole and the south pole respectively, the denominations being borrowed from the poles of the earth and heavens. ‘These poles,’ as Gilbert says1, ‘regulate the motions of the celestial spheres and of the earth. In like manner the magnet has its poles, a northern and a southern one; certain and determined points constituted by nature in the stone, the primary terms of its motions and effects, the limits and governors of many actions and virtues.’
The nature of the opposition of properties of which we speak
may be stated thus:
The North pole of one magnet attracts the South pole of
another magnet.
The North pole of one magnet repels the North pole
of another magnet.
The South pole of one magnet repels the South pole of another
magnet.
The South pole of one magnet attracts the North pole
of another magnet.
It will be observed that the contrariety of position which is indicated by putting the South pole for the North pole in either magnet, is accompanied by the 361 opposition of mechanical effect which is expressed by changing attraction into repulsion and repulsion into attraction: and thus we have the general feature of Polarity,—A contrast of properties corresponding to a contrast of positions.
3. Electricity.—When the phenomena of Electricity came to be studied, it appeared that they involved relations in some respects Analogous to those of magnetism.
Two kinds of electricity were distinguished, the positive and the negative; and it appeared that two bodies electrized positively, or two electrized negatively, repelled each other, like two north or two south magnetic poles; while a positively and a negatively electrized body attracted each other, like the north and south poles of two magnets. In conductors of an oblong form, the electricity could easily be made to distribute itself so that one end should be positively and one end negatively electrized; and then such conductors acted on each other exactly as magnets would do.
But in conductors, however electrized, there is no peculiar point which can permanently be considered as the pole. The distribution of electricity in the conductor depends upon external circumstances: and thus, although the phenomena offer the general character of polarity—alternative results corresponding to alternative positions,—they cannot be referred to poles. Some other mode of representing the forces must be adopted than that which makes them emanate from permanent points as in a magnet.
The phenomena of attraction and repulsion in electrized bodies were conveniently represented by means of the hypothesis of two electric fluids, a positive and a negative one, which were supposed to be distributed in the bodies. Of these fluids, it was supposed that each repelled its own parts and attracted those of the opposite fluid: and it was found that this hypothesis explained all the obvious laws of electric action. Here then we have the phenomena of polarization explained by a new kind of machinery:—two opposite fluids 362 distributed in bodies, and supplying them, so to speak, with their polar forces. This hypothesis not only explains electrical attraction, but also the electrical spark: namely, thus: when two bodies, of which the neighbouring surfaces are charged with the two opposite fluids, approach near to each other, the mutual attraction of the fluids becomes more and more intense, till at last the excess of fluid on the one body breaks through the air and rushes to the other body, in a form accompanied by light and noise. When this transfer has taken place, the attraction ceases, the positive and the negative fluid having neutralized each other. Their effort was to unite; and this union being effected, there is no longer any force in action. Bodies in their natural unexcited condition may be considered as occupied by a combination of the two fluids: and hence we see how the production of either kind of electricity is necessarily accompanied with the production of an equivalent amount of the opposite kind.
4. Voltaic Electricity.—Such is the case in Franklinic electricity,—that which is excited by the common electrical machine. In studying Voltaic electricity, we are led to the conviction that the fluid which is in a condition of momentary equilibrium in electrized conductors, exists in the state of a Current in the voltaic circuit. And here we find polar relations of a new kind existing among the forces. Two voltaic Currents attract each other when they are moving in the same, and repel each other when they are moving in opposite, directions.
But we find, in addition to these, other polar relations of a more abstruse kind, and which the supposition of two fluids does not so readily explain. For instance, if such fluids existed, distinct from each other, it might be expected that it would be possible to exhibit one of them separate from the other. Yet in all the phenomena of electromotive currents, we attempt in vain to obtain one kind of electricity separately. ‘I have not,’ says Mr. Faraday2, ‘been able to find a 363 single fact which could be adduced to prove the theory of two electricities rather than one, in electric currents; or, admitting the hypothesis of two electricities, have I been able to perceive the slightest grounds that one electricity can be more powerful than the other, or that it can be present without the other, or that it can be varied or in the slightest degree affected without a corresponding variation in the other.’ ‘Thus,’ he adds, ‘the polar character of the powers is rigorous and complete.’ Thus, we too may remark, all the superfluous and precarious parts gradually drop off from the hypothesis which we devise in order to represent polar phenomena; and the abstract notion of Polarity—of equal and opposite powers called into existence by a common condition—remains unincumbered with extraneous machinery.
5. Light.—Another very important example of the application of the Idea of Polarity is that supplied by the discovery of the polarization of light. A ray of light may, by various processes, be modified, so that it has different properties according to its different sides, although this difference is not perceptible by any common effects. If, for instance, a ray thus modified, pass perpendicularly through a circular glass, and fall upon the eye, we may turn the glass round and round in its frame, and we shall make no difference in the brightness of the spot which we see. But if, instead of a glass, we look through a longitudinal slice of tourmaline, the spot is alternately dark and bright as we turn the crystal through successive quadrants. Here we have a contrast of Properties (dark and bright) corresponding to a contrast of positions, (the position of a line east and west being contrasted with the position north and south,) which, as we have said, is the general character of Polarity. It was with a view of expressing this character that the term Polarization was originally introduced. Malus was forced by his discoveries into the use of this expression. ‘We find,’ he says, in 1811, ‘that light acquires properties which are relative only to the sides of the ray,—which are the same for the north and south sides of the ray, (using 364 the points of the compass for description’s sake only,) and which are different when we go from the north and south to the east or to the west sides of the ray. I shall give the name of poles to these sides of the ray, and shall call polarization the modification which gives to light these properties relative to these poles. I have put off hitherto the admission of this term into the description of the physical phenomena with which we have to do: I did not dare to introduce it into the Memoirs in which I published my last observations: but the variety of forms in which this new phenomenon appears, and the difficulty of describing them, compel me to admit this new expression; which signifies simply the modification which light has undergone in acquiring new properties which are not relative to the direction of the ray, but only to its sides considered at right angles to each other, and in a plane perpendicular to its direction.’
The theory which represents light as an emission of particles was in vogue at the time when Malus published his discoveries; and some of his followers in optical research conceived that the phenomena which he thus described rendered it necessary to ascribe poles and an axis to each particle of light. On this hypothesis, light would be polarized when the axes of all the particles were in the same direction: and, making such a supposition, it may easily be conceived capable of transmission through a crystal whose axis is parallel to that of the luminous particles, and intransmissible when the axis of the crystal is in a position transverse to that of the particles.
The hypothesis of particles possessing poles is a rude and arbitrary assumption, in this as in other cases; but it serves to convey the general notion of polarity, which is the essential feature of the phenomena. The term ‘polarization of light has sometimes been complained of in modern times as hypothetical and obscure. But the real cause of obscurity was, that the Idea of Polarity was, till lately, very imperfectly developed in men’s minds. As we have seen, the general notion of Polarity,—opposite properties in opposite 365 directions,—exactly describes the character of the optical phenomena to which the term is applied.
It is to be recollected that in optics we never speak of the poles, but of the plane of polarization of a ray. The word sides, which Newton and Malus have used, neither of them appears to have been satisfied with; Newton, in employing it, had recourse to the strange Gallicism of speaking of the coast of usual and of unusual refraction of a crystal.
The modern theory of optics represents the plane of polarization of light as depending, not on the position in which the axes of the luminiferous particles lie, but on the direction of those transverse vibrations in which light consists. This theory is, as we have stated in the History, recommended by an extraordinary series of successes in accounting for the phenomena. And this hypothesis of transverse vibrations shows us another mechanical mode, (besides the hypothesis of particles with axes,) by which we may represent the polarity of a ray. But we may remark that the general notion of Polarity, as applied to light in such cases, would subsist, even if the undulatory theory were rejected. The idea is, as we have before said, independent of all hypothetical machinery.
I need not here refer to the various ways in which light may be polarized; as, for instance, by being reflected from the surface of water, or of glass, at certain angles, by being transmitted, through crystals, and in other ways. In all cases the modification produced, the polarization, is identically the same property. Nor need I mention the various kinds of phenomena which appear as contrasts in the result; for these are not merely light and dark, or white and black, but red and green, and generally, a colour and its complementary colour, exhibited in many complex and varied configurations. These multiplied modes in which polarized light presents itself add nothing to the original conception of Polarization: and I shall therefore pass on to another subject.
6. Crystallization.—Bodies which are perfectly crystallized exhibit the most complete regularity and 366 symmetry of form; and this regularity not only appears in their outward shape, but pervades their whole texture, and manifests itself in their cleavage, their transparency, and in the uniform and determinate optical properties which exist in every part, even in the smallest fragment of the mass. If we conceive crystals as composed of particles, we must suppose these particles to be arranged in the most regular manner; for example, if we suppose each particle to have an axis, we must suppose all these axes to be parallel; for the direction of the axis of the particles is indicated by the physical and optical properties of the crystal, and therefore this direction must be the same for every portion of the crystal. This parallelism of the axes of the particles may be conceived to result from the circumstance of each particle having poles, the opposite poles attracting each other. In virtue of forces acting as this hypothesis assumes, a collection of small magnetic particles would arrange themselves in parallel positions; and such a collection of magnetic particles offers a sort of image of a crystal. Thus we are led to conceive the particles of crystals as polarized, and as determined in their crystalline positions by polar forces. This mode of apprehending the constitution of crystals has been adopted by some of our most eminent philosophers. Thus Berzelius says3, ‘It is demonstrated, that the regular forms of bodies presuppose an effort of their atoms to touch each other by preference in certain points; that is, they are founded upon a Polarity;’—he adds, ‘a polarity which can be no other than an electric or magnetic polarity.’ In this latter clause we have the identity of different kinds of polarity asserted; a principle which we shall speak of in the next chapter. But we may remark, that even without dwelling upon this connexion, any notion which we can form of the structure of Crystals necessarily involves the idea of Polarity. Whether this polarity necessarily requires us to believe crystals to be composed of Atoms which exert an effort to touch 367 each other in certain points by preference, is another question. And, in agreement with what has been said respecting other kinds of polarity, we shall probably find, on a more profound examination of the subject, that while the Idea of Polarity is essential, the machinery by which it is thus expressed is precarious and superfluous.
7. Chemical Affinity.—We shall have, in the next Book, to speak of Chemical Affinity at some length; but since the ultimate views to which philosophers have been led, induce them to consider the forces of Affinity as Polar Forces, we must enumerate these among the examples of Polarity. In chemical processes, opposites tend to unite, and to neutralize each other by their union. Thus an acid or an alkali combine with vehemence, and form a compound, a neutral salt, which is neither acid nor alkaline.
This conception of contrariety and mutual neutralization, involves the Idea of Polarity. In the conception as entertained by the earlier chemists, the Idea enters very obscurely: but in the attempts which have more recently been made to connect this relation (of acid and base), with other relations, the chemical elements have been conceived as composed of particles which possess poles; like poles repelling, and unlike attracting each other, as they do in magnetic and electric phenomena. This is, however, a rude and arbitrary way of expressing Polarity, and, as may be easily shown, involves many difficulties which do not belong to the Idea itself. Mr. Faraday, who has been led by his researches to a conviction of the polar nature of the forces of chemical affinity, has expressed their character in a more general manner, and without any of the machinery of particles indued with poles. According to his view, chemical synthesis and analysis must always be conceived as taking place in virtue of equal and opposite forces, by which the particles are united or separated. These forces, by the very circumstance of their being polar, may be transferred from point to point. For if we conceive a string of particles, and if the positive force of the first particle 368 be liberated and brought into action, its negative force also must be set free: this negative force neutralizes the positive force of the next particle, and therefore the negative force of this particle (before employed in neutralizing its positive force) is set free: this is in the same way transferred to the next particle, and so on. And thus we have a positive force active at one extremity of a line of particles, corresponding to a negative force at the other extremity, all the intermediate particles reciprocally neutralizing each other’s action. This conception of the transfer of chemical action was indeed at an earlier period introduced by Grotthus4, and confirmed by Davy. But in Mr. Faraday’s hands we see it divested of all that is superfluous, and spoken of, not as a line of particles, but as ‘an axis of power, having [at every point] contrary forces, exactly equal, in opposite directions.’
8. General Remarks.—Thus, as we see, the notion of Polarity is applicable to many large classes of phenomena. Yet the Idea in a distinct and general form is only of late growth among philosophers. It has gradually been abstracted and refined from many extraneous hypotheses which were at first supposed to be essential to it. We have noticed some of these hypotheses;—as the poles of a body; the poles of the particles of a fluid; two opposite fluids; a single fluid in excess and defect; transverse vibrations. To these others might be added. Thus Dr. Prout5 assumes that the polarity of molecules results from their rotation on their axes, the opposite motions of contiguous molecules being the cause of opposite (positive and negative) polarities.
But none of these hypotheses can be proved by the fact of Polarity alone; and they have been in succession rejected when they had been assumed on that ground. Thus Davy, in 1826, speaking of chemical forces says6, ‘In assuming the idea of two ethereal, subtile, elastic 369 fluids, attractive of the particles of each other, and repulsive as to their own particles, capable of combining in different proportions with bodies, and according to their proportions giving them their specific qualities and rendering them equivalent masses, it would be natural to refer the action of the poles to the repulsions of the substances combined with the excess of one fluid, and the attractions of those united to the excess of the other fluid; and a history of the phenomena, not unsatisfactory to the reason, might in this way be made out. But as it is possible likewise to take an entirely different view of the subject, on the idea of the dependence of the results upon the primary attractive powers of the parts of the combination on a single subtile fluid, I shall not enter into any discussion on this obscure part of the theory.’ Which of these theories will best represent the case, will depend upon the consideration of other facts, in combination with the polar phenomena, as we see in the history of optical theory. In like manner Mr. Faraday proved by experiment7 the errour of all theories which ascribe electro-chemical decomposition to the attraction of the poles of the voltaic battery.
In order that they may distinctly image to themselves the Idea of Polarity, men clothe it in some of the forms of machinery above spoken of; yet every new attempt shows them the unnecessary difficulties in which they thus involve themselves. But on the other hand it is difficult to apprehend this Idea divested of all machinery; and to entertain it in such a form that it shall apply at the same time to magnetism and electricity, galvanism and chemistry, crystalline structure and light. The Idea of Polarity becomes most pure and genuine, when we entirely reject the conception of Poles, as Faraday has taught us to do in considering electro-chemical decomposition; but it is only by degrees and by effort that we can reach this point of abstraction and generality. 370
9. There is one other remark which we may here make. It was a maxim commonly received in the ancient schools of philosophy, that ‘Like attracts Like:’ but as we have seen, the universal maxim of Polar Phenomena is, that Like repels Like, and attracts Unlike. The north pole attracts the south pole, the positive fluid attracts the negative fluid; opposite elements rush together; opposite motions reduce each other to rest. The permanent and stable course of things is that which results from the balance and neutralization of contrary tendencies. Nature is constantly labouring after repose by the effect of such tendencies; and so far as Polar Forces enter into her economy, she seeks harmony by means of discord, and unity by opposition.
Although the Idea of Polarity is as yet somewhat vague and obscure, even in the minds of the cultivators of physical science, it has nevertheless given birth to some general principles which have been accepted as evident, and have had great influence on the progress of science. These we shall now consider.