1. IT has appeared in the preceding chapter that in cases in which the phenomena suggest to us the idea of Polarity, we are also led to assume some material machinery as the mode in which the polar forces are exerted. We assume, for instance, globular particles which possess poles, or the vibrations of a fluid, or two fluids attracting each other; in every case, in short, some hypothesis by which the existence and operation of the Polarity is embodied in geometrical and mechanical properties of a medium; nor is it possible for us to avoid proceeding upon the conviction that some such hypothesis must be true; although the nature of the connexion between the mechanism and the phenomena must still be indefinite and arbitrary.
But since each class of Polar Phenomena is thus referred to an ulterior cause, of which we know no more than that it has a polar character, it follows that different Polarities may result from the same cause manifesting its polar character under different aspects. Taking, for example, the hypothesis of globular particles, if electricity result from an action dependent upon the poles of each globule, magnetism may depend upon an action in the equator of each globule; or taking the supposition of transverse vibrations, if polarized light result directly from such vibrations, crystallization may have reference to the axes of the elasticity of the medium by which the vibrations are rendered transverse,—so far as the polar character only of the phenomena is to be accounted for. I say this may be so, in so far only as the polar character of the phenomena is concerned; for whether the relation of 372 electricity to magnetism, or of crystalline forces to light, can really be explained by such hypotheses, remains to be determined by the facts themselves. But since the first necessary feature of the hypothesis is, that it shall give polarity, and since an hypothesis which does this, may, by its mathematical relations, give polarities of different kinds and in different directions, any two co-existent kinds of polarity may result from the same cause, manifesting itself in various manners.
The conclusion to which we are led by these general considerations is, that two co-existing classes of polar phenomena may be effects of the same cause. But those who have studied such phenomena more deeply and attentively have, in most or in all cases, arrived at the conviction that the various kinds of Polarity in such cases must be connected and fundamentally identical. As this conviction has exercised a great influence, both upon the discoveries of new facts and upon the theoretical speculations of modern philosophers, and has been put forward by some writers as a universal principle of science, I will consider some of the cases in which it has been thus applied.
2. Connexion of Magnetic and Electric Polarity.—The polar phenomena of electricity and magnetism are clearly analogous in their laws: and obvious facts showed at an early period that there was some connexion between the two agencies. Attempts were made to establish an evident and definite relation between the two kinds of force, which attempts proceeded upon the principle now under consideration;—namely, that in such cases, the two kinds of Polarity must be connected. Professor Œrsted, of Copenhagen, was one of those who made many trials founded upon this conviction: yet all these were long unsuccessful. At length, in 1820, he discovered that a galvanic current, passing at right angles near to a magnetic needle, exercises upon it a powerful deflecting force. The connexion once detected between magnetism and galvanism was soon recognized as constant and universal. It was represented in different hypothetical modes by different persons; some considering the galvanic 373 current as the primitive axis, and the magnet as constituted of galvanic currents passing round it at right angles to the magnetic axis; while others conceived the magnetic axis as the primitive one, and the electric current as implying a magnetic current round the wire. So far as many of the general relations of these two kinds of force were concerned, either mode of representation served to express them; and thus the assumption that the two Polarities, the magnetic and the electric, were fundamentally identical, was verified, so far as the phenomena of magnetic attraction, and the like, were concerned.
I need not here mention how this was further confirmed by the experiments in which, by means of the forces thus brought into view, a galvanic wire was made to revolve round a magnet, and a magnet round a galvanic wire;—in which artificial magnets were constructed of coils of galvanic wire;—and finally, in which the galvanic spark was obtained from the magnet. The identity which sagacious speculators had divined even before it was discovered, and which they had seen to be universal as soon as it was brought to light, was completely manifested in every imaginable form.
The relation of the electric and magnetic Polarities was found to be, that they were transverse to each other, and this relation exhibited under various conditions of form and position of the apparatus, gave rise to very curious and unexpected perplexities. The degree of complication which this relation may occasion, may be judged of from the number of constructions and modes of conception offered by Œrsted, Wollaston, Faraday, and others, for the purpose of framing a technical memory of the results. The magnetic polarity gives us the north and south poles of the needle; the electric polarity makes the current positive and negative; and these pairs of opposites are connected by relations of situation, as above and below, right and left; and give rise to the resulting motion of the needle one way or the other. 374
3. Ampère, by framing his hypotheses of the action of voltaic currents and the constitution of magnets, reduced all these technical rules to rigorous deductions from one general principle. And thus the vague and obscure persuasion that there must be some connexion between Electricity and Magnetism, so long an idle and barren conjecture, was unfolded into a complete theory, according to which magnetic and electromotive actions are only two different manifestations of the same forces; and all the above-mentioned complex relations of polarities are reduced to one single polarity, that of the electro-dynamic current.
4. As the Idea of Polarity was thus firmly established and clearly developed, it became an instrument of reasoning. Thus it led Ampère to maintain that the original or elementary forces in electro-dynamic action could not be as M. Biot thought they were, a statical couple, but must be directly opposite to each other. The same idea enabled Mr. Faraday to carry on with confidence such reasonings as the following8: ‘No other known power has like direction with that exerted between an electric current and a magnetic pole; it is tangential, while all other forces acting at a distance are direct. Hence if a magnetic pole on one side of a revolving plate follow its course by reason of its obedience to the tangential force exerted upon it by the very current of electricity which it has itself caused; a similar pole on the other side of the plate should immediately set it free from this force; for the currents which have to be formed by the two poles are in contrary directions.’ And in Article 1114 of his Researches, the same eminent philosopher infers that if electricity and magnetism are considered as the results of a peculiar agent or condition, exerted in determinate directions perpendicular to each other, one must be by some means convertible into the other; and this he was afterwards able to prove to be the case in fact.
375 Thus the principle that the Co-existent Polarities of magnetism and electricity are connected and fundamentally identical, is not only true, but is far from being either vague or barren. It has been a fertile source both of theories which have, at present, a very great probability, and of the discovery of new and striking facts. We proceed to consider other similar cases.
5. Connexion of Electrical and Chemical Polarities.—The doctrine that the chemical forces by which the elements of bodies are held together or separated, are identical with the polar forces of electricity, is a great discovery of modern times; so great and so recent, indeed, that probably men of science in general have hardly yet obtained a clear view and firm hold of this truth. This doctrine is now, however, entirely established in the minds of the most profound and philosophical chemists of our time. The complete development and confirmation of this as of other great truths, was preceded by more vague and confused opinions gradually tending to this point; and the progress of thought and of research was impelled and guided, in this as in similar cases, by the persuasion that these co-existent polarities could not fail to be closely connected with each other. While the ultimate and exact theory to which previous incomplete and transitory theories tended is still so new and so unfamiliar, it must needs be a matter of difficulty and responsibility for a common reader to describe the steps by which truth has advanced from point to point. I shall, therefore, in doing this, guide myself mainly by the historical sketches of the progress of this great theory, which, fortunately for us, have been given us by the two philosophers who have played by far the most important parts in the discovery, Davy and Faraday.
It will be observed that we are concerned here with the progress of theory, and not of experiment, except so far as it is confirmatory of theory. In Davy’s Memoir9 of 1826, on the Relations of Electrical and 376 Chemical Changes, he gives the historical details to which I have alluded. Already in 1802 he had conjectured that all chemical decompositions might be polar. In 1806 he attempted to confirm this conjecture, and succeeded, to his own satisfaction, in establishing10 that the combinations and decompositions by electricity were referable to the law of electrical attractions and repulsions; and advanced the hypothesis (as he calls it), that chemical and electrical attractions were produced by the same cause, acting in one case on particles, in the other on masses. This hypothesis was most strikingly confirmed by the author’s being able to use electrical agency as a more powerful means of chemical decomposition than any which had yet been applied. ‘Believing,’ he adds, ‘that our philosophical systems are exceedingly imperfect, I never attached much importance to this hypothesis; but having formed it after a copious induction of facts, and having gained by the application of it a number of practical results, and considering myself as much the author of it as I was of the decomposition of the alkalies, and having developed it in an elementary work as far as the present state of chemistry seemed to allow, I have never,’ he says, ‘criticised or examined the manner in which different authors have adopted or explained it, contented, if in the hands of others, it assisted the arrangements of chemistry or mineralogy, or became an instrument of discovery.’ When the doctrine had found an extensive acceptance among chemists, attempts were made to show that it had been asserted by earlier writers: and though Davy justly denies all value to these pretended anticipations, they serve to show, however dimly, the working of that conviction of the Connexion of Co-existent Properties which all along presided in men’s minds during this course of investigation. ‘Ritter and Winterl have been quoted,’ Davy says11, ‘among other persons, as having imagined or anticipated the relation between electrical powers and chemical affinities before the discovery of the pile 377 of Volta. But whoever will read with attention Ritter’s “Evidence that Galvanic action exists in organised nature,” and Winterl's Prolusiones ad Chemiam sæculi decimi noni, will find nothing to justify this opinion.’ He then refers to the Queries of Newton at the end of his Optics. ‘These,’ he says, ‘contain more grand and speculative views that might be brought to bear upon this question than any found in the works of modern electricians; but it is very unjust to the experimentalists who by the laborious application of new instruments, have discovered novel facts and analogies, to refer them to any such suppositions as that all attractions, chemical, electrical, magnetical, and gravitative, may depend upon the same cause.’ It is perfectly true, that such vague opinions, though arising from that tendency to generalize which is the essence of science, are of no value except so far as they are both rendered intelligible, and confirmed by experimental research.
The phenomena of chemical decomposition by means of the voltaic pile, however, led other persons to views very similar to those of Davy. Thus Grotthus in 180512 published an hypothesis of the same kind. ‘The pile of Volta,’ he says, ‘is an electrical magnet, of which each element, that is, each pair of plates, has a positive and a negative pole. The consideration of this polarity suggested to me the idea that a similar polarity may come into play between the elementary particles of water when acted upon by the same electrical agent; and I avow that this thought was for me a flash of light.’
6. The thought, however, though thus brought into being, was very far from being as yet freed from vagueness, superfluities, and errours. I have elsewhere noticed13 Faraday’s remark on Davy’s celebrated Memoir of 1806; that ‘the mode of action by which the effects take place is stated very generally, so generally, indeed, that probably a dozen precise schemes of electro-chemical action might be drawn up, differing 378 essentially from each other, yet all agreeing with the statement there given.’ When Davy and others proceeded to give a little more definiteness and precision to the statement of their views, they soon introduced into the theory features which it was afterwards found necessary to abandon. Thus14 both Davy, Grotthus, Riffault, and Chompré, ascribed electrical decomposition to the action of the poles, and some of them even pretended to assign the proportion in which the force of the pole diminishes as the distance from it increases. Faraday, as I have already stated, showed that the polarity must be considered as residing not only in what had till then been called the poles, but at every point of the circuit. He ascribed15 electro-chemical decomposition to internal forces, residing in the particles of the matter under decomposition, not to external forces, exerted by the poles. Hence he shortly afterwards16 proposed to reject the word poles altogether, and to employ instead, the term electrode, meaning the doors or passages (of whatever surface formed) by which the decomposed elements pass out. What have been called the positive and negative poles he further termed the Anode and Cathode; and he introduced some other changes in nomenclature connected with these. He then, as I have related in the History17, invented the Volta-electrometer, which enabled him to measure the quantity of voltaic action, and this he found to be identical with the quantity of chemical affinity; and he was thus led to the clearest view of the truth towards which he and his predecessors had so long been travelling, that electrical and chemical forces are identical18.
7. It will, perhaps, be said that this beautiful train of discovery was entirely due to experiment, and not to any à priori conviction that co-existent polarities 379 must be connected. I trust I have sufficiently stated that such an à priori principle could not be proved, nor even understood, without a most laborious and enlightened use of experiment; but yet I think that the doctrine, when once fully unfolded, exhibited clearly, and established as true, takes possession of the mind with a more entire conviction of its certainty and universality, in virtue of the principle we are now considering. When the theory has assumed so simple a form, it appears to derive immense probability (to say the least) from its simplicity. Like the laws of motion, when stated in its most general form, it appears to carry with it its own evidence. And thus this great theory borrows something of its character from the Ideas which it involves, as well as from the Experiments by which it was established.
8. We may find in many of Mr. Faraday’s subsequent reasonings, clear evidence that this idea of the Connexion of Polarities, as now developed, is not limited in its application to facts already known experimentally, but, like other ideas, determines the philosopher’s researches into the unknown, and gives us the form of knowledge even before we possess the matter. Thus, he says, in his Thirteenth Series19, ‘I have long sought, and still seek, for an effect or condition which shall be to statical electricity what magnetic force is to current electricity; for as the lines of discharge are associated with a certain transverse effect, so it appeared to me impossible but that the lines of tension or of inductive action, which of necessity precede the discharge, should also have their correspondent transverse condition or effect.’ Other similar passages might be found.
I will now consider another case to which we may apply the Principle of Connected Polarities.
9. Connexion of Chemical and Crystalline Polarities.—The close connexion between the Chemical Affinity and the Crystalline Attraction of elements cannot be overlooked. Bodies never crystallize but when their elements combine chemically; and solid bodies which 380 combine, when they do it most completely and exactly, also crystallize. The forces which hold together the elements of a crystal of alum are the same forces which make it a crystal. There is no distinguishing between the two sets of forces.
Both chemical and crystalline forces are polar, as we stated in the last chapter; but the polarity in the two cases is of a different kind. The polarity of chemical forces is then put in the most distinct form, when it is identified with electrical polarity; the polarity of the particles of crystals has reference to their geometrical form. And it is clear that these two kinds of polarity must be connected. Accordingly, Berzelius expressly asserts20 the necessary identity of these two polarities. ‘The regular forms of bodies suppose a polarity which can be no other than an electric or magnetic polarity.’ This being so seemingly inevitable, we might expect to find the electric forces manifesting some relation to the definite directions of crystalline forms. Mr. Faraday tried, but in vain, to detect some such relation. He attempted to ascertain21 whether a cube of rock crystal transmitted the electrical force of tension with different intensity along and across the axis of the crystal. In the first specimen there seemed to be some difference; but in other experiments, made both with rock crystal and with calc spar, this difference disappeared. Although therefore we may venture to assert that there must be some very close connexion between electrical and crystalline forces, we are, as yet, quite ignorant what the nature of the connexion is, and in what kind of phenomena it will manifest itself.
10. Connexion of Crystalline and Optical Polarities.—Crystals present to us optical phenomena which have a manifestly polar character. The double refraction, both of uniaxal and of biaxal crystals, is always accompanied with opposite polarization of the two rays; and in this and in other ways light is polarized in directions dependent upon the axes of the crystalline form, that is, on the directions of the polarities of the 381 crystalline particles. The identity of these two kinds of polarity (crystalline and optical) is too obvious to need insisting on; and it is not necessary for us here to decide by what hypothesis this identity may most properly be represented. We may hereafter perhaps find ourselves justified in considering the crystalline forces as determining the elasticity of the luminiferous ether to be different in different directions within the crystal, and thus as determining the refraction and polarization of the light which the crystal transmits. But at present we merely note this case as an additional example of the manifest connexion and fundamental identity of two co-existent polarities.
11. Connexion of Polarities in general.—Thus we find that the Connexion of different kinds of Polarities, magnetic, electric, chemical, crystalline, and optical, is certain as a truth of experimental science. We have attempted to show further that in the minds of several of the most eminent discoverers and philosophers, such a conviction is something more than a mere empirical result: it is a principle which has regulated their researches while it was still but obscurely seen and imperfectly unfolded, and has given to their theories a character of generality and self-evidence which experience alone cannot bestow.
It will, perhaps, be said that these doctrines,—that scientific researches may usefully be directed by principles in themselves vague and obscure;—that theories may have an evidence superior to and anterior to experience;—are doctrines in the highest degree dangerous, and utterly at variance with the soundest maxims of modern times respecting the cultivation of science.
In the justice and wisdom of this caution I entirely agree: and although I have shown that this principle of the Connexion of Polarities, rightly interpreted and established in each case by experiment, involves profound and comprehensive truths; I think it no less important to remark that, at least in the present stage of our knowledge, we can make no use of this principle without taking care, at every step, to determine by 382 clear and decisive experiments, its proper meaning and application. All endeavours to proceed otherwise have led, and must lead, to ignorance and confusion. Attempts to deduce from our bare Idea of Polarity, and our fundamental convictions respecting the connexion of polarities, theories concerning the forces which really exist in nature, can hardly have any other result than to bewilder men’s minds, and to misdirect their efforts.
So far, indeed, as this persuasion of a connexion among apparently different kinds of agencies, impels men, engaged in the pursuit of knowledge, to collect observations, to multiply, repeat, and vary experiments, and to contemplate the result of these in all aspects and relations, it may be an occasion of the most important discoveries. Accordingly we find that the great laws of phenomena which govern the motions of the planets about the sun, were first discovered by Kepler, in consequence of his scrutinizing the recorded observations with an intense conviction of the existence of geometrical and arithmetical harmonies in the solar system. Perhaps we may consider the discovery of the connexion of magnetism and electricity by Professor Œrsted in 1820, as an example somewhat of the same kind; for he also was a believer in certain comprehensive but undefined relations among the properties of bodies; and in consequence of such views entertained great admiration for the Prologue to the Chemistry of the Nineteenth Century, of Winterl, already mentioned. M. Œrsted, in 1803, published a summary of this work; and in so doing, praised the views of Winterl as far more profound and comprehensive than those of Lavoisier. Soon afterwards a Review of this publication appeared in France22, in which it was spoken of as a work only fit for the dark ages, and as the indication of a sect which had for some time ‘ravaged Germany,’ and inundated that country with extravagant and unintelligible mysticism. It was, therefore, a kind of triumph to M. Œrsted to be, after 383 some years’ labour, the author of one of the most remarkable and fertile physical discoveries of his time.
12. It was not indeed without some reason that certain of the German philosophers were accused of dealing in doctrines vast and profound in their aspect, but, in reality, indefinite, ambiguous, and inapplicable. And the most prominent of such doctrines had reference to the principle now under our consideration; they represented the properties of bodies as consisting in certain polarities, and professed to deduce, from the very nature of things, with little or no reference to experiment, the existence and connexion of these polarities. Thus Schelling, in his Ideas towards a Philosophy of Nature, published in 1803, says23, ‘Magnetism is the universal act of investing Multiplicity with Unity; but the universal form of the reduction of Multiplicity to Unity is the Line, pure Longitudinal Extension: hence Magnetism is determination of pure Longitudinal Extension; and as this manifests itself by absolute Cohesion, Magnetism is the determination of absolute Cohesion.’ And as Magnetism was, by such reasoning, conceived to be proved as a universal property of matter, Schelling asserted it to be a confirmation of his views when it was discovered that other bodies besides iron are magnetic. In like manner he used such expressions as the following24: ‘The threefold character of the Universal, the Particular, and the Indifference of the two,—as expressed in their Identity, is Magnetism, as expressed in their Difference, is Electricity, and as expressed in the Totality, is Chemical Process. Thus these forms are only one form; and the Chemical Process is a mere transfer of the three Points of Magnetism into the Triangle of Chemistry.’
It was very natural that the chemists should refuse to acknowledge, in this fanciful and vague language, (delivered, however, it is to be recollected, in 1803,) an anticipation of Davy’s doctrine of the identity of electrical and chemical forces, or of Œrsted’s 384 electro-magnetic agency. Yet it was perhaps no less natural that the author of such assertions should look upon every great step in the electro-chemical theory as an illustration of his own doctrines. Accordingly we find Schelling welcoming, with a due sense of their importance, the discoveries of Faraday. When he heard of the experiment in which electricity was produced from common magnetism, he fastened with enthusiasm upon the discovery, even before he knew any of its details, and proclaimed it at a public meeting of a scientific body25 as one of the most important advances of modern science. We have (he thus reasoned) three effects of polar forces;—Electro-chemical Decomposition, Electrical Action, Magnetism. Volta and Davy had confirmed experimentally the identity of the two former agencies: Œrsted showed that a closed voltaic circuit acquired magnetic properties: but in order to exhibit the identity of electric and magnetic action it was requisite that electric forces should be extricated from magnetic. This great step Faraday, he remarked, had made, in producing the electric spark by means of magnets.
13. Although conjectures and assertions of the kind thus put forth by Schelling involve a persuasion of the pervading influence and connexion of polarities, which persuasion has already been confirmed in many instances, they involve this principle in a manner so vague and ambiguous that it can rarely, in such a form, be of any use or value. Such views of polarity can never teach us in what cases we are and in what we are not expected to find polar relations; and indeed tend rather to diffuse error and confusion, than to promote knowledge. Accordingly we cannot be surprized to find such doctrines put forward by their authors as an evidence of the small value and small necessity of experimental science. This is done by the celebrated metaphysician Hegel, in his Encyclopædia26. ‘Since,’ 385 says he, ‘the plane of incidence and of reflection in simple reflection is the same plane, when a second reflector is introduced which further distributes the illumination reflected from the first, the position of the first plane with respect to the second plane, containing the direction of the first reflection and of the second, has its influence upon the position, illumination or darkening of the object as it appears by the second reflection. This influence must be the strongest when the two planes are what we must call negatively related to each other:—that is, when they are at right angles.’ ‘But,’ he adds, ‘when men infer (as Malus has done) from the modification which is produced by this situation, in the illumination of the reflection, that the molecules of light in themselves, that is, on their different sides, possess different physical energies; and when on this foundation, along with the phenomena of entoptical colours therewith connected, a wide labyrinth of the most complex theory is erected; we have then one of the most remarkable examples of the inferences of physics from experiment.’ If Hegel’s reasoning prove anything, it must prove that polarization always accompanies reflection under such circumstances as he describes: yet all physical philosophers know that in the case of metals, in which the reflection is most complete, light is not completely polarized at any angle; and that in other substances the polarization depends upon various circumstances which show how idle and inapplicable is the account which he thus gives of the property. His self-complacent remark about the inferences of physics from experiment, is intended to recommend by comparison his own method of considering the nature of ‘things in themselves;’ a mode of obtaining physical truth which had been more than exhausted by Aristotle, and out of which no new attempts have extracted anything of value since his time.
14. Thus the general conclusion to which we are led on this subject, is, that the persuasion of the existence and Connexion or Identity of various Polarities in nature, although very naturally admitted, and in many 386 cases interpreted and confirmed by observed facts, is of itself, so far as we at present possess it, a very insecure guide to scientific doctrines. When it is allowed to dictate our theories, instead of animating and extending our experimental researches, it leads only to errour, confusion, obscurity, and mysticism.
This Fifth Book, on the subject of Polarities, is a short one compared with most of the others. This arises in a great measure from the circumstance that the Idea of Polarity has only recently been apprehended and applied, with any great degree of clearness, among physical philosophers; and is even yet probably entertained in an obscure and ambiguous manner by most experimental inquirers. I have been desirous of not attempting to bring forward any doctrines upon the subject, except such as have been fully illustrated and exemplified by the acknowledged progress of the physical sciences. If I had been willing to discuss the various speculations which have been published respecting the universal prevalence of Polarities in the universe, and their results in every province of nature, I might easily have presented this subject in a more extended form; but this would not have been consistent with my plan of tracing the influence of scientific Ideas only so far as they have really aided in disclosing and developing scientific truths. And as the influence of this Idea is clearly distinguishable both from those which precede and those which follow, in the character of the sciences to which it gives rise, and as it appears likely to be hereafter of great extent and consequence, it seemed better to treat of it in a separate Book, although of a brevity disproportioned to the rest.
end of vol. i.
Cambridge: Printed at the University Press.