But if, as often happens, the Galena crystal be an octahedron, a further consideration is requisite in order to understand its structure, pursuing still the same hypothesis. The mineral is still, as in the other case, readily cleavable into small cubes, having their corners turned to the faces of the octahedron. Therefore these faces can no longer be conceived as made up of the faces of cubical elements of which the whole is constituted. If we suppose a pile of such small cubes to be closely built together, but with decreasing width above, so as to form a pyramid, the face of such a pyramid will no longer be plane; it will consist of a great number of the corners or edges of the small elementary cubes. It would appear at first sight, therefore, that such a face cannot represent the smooth polished surface of a crystal. 81

But when we come to look more closely, this difficulty disappears. For how large are these elementary cubes? We cannot tell, even supposing they really have any size. But we know that they must be, at any rate, very small; so small as to be inappreciable by our senses, for our senses find no limit to the divisibility of minerals by cleavage. Hence the surface of the pyramid above described would not consist of visible corners or edges, but would be roughened by specks of imperceptible size; or rather, by supposing these specks to become still smaller, the roughness becomes smoothness. And thus we may have a crystal with a smooth surface, made up of small cubes in such a manner that their surfaces are all oblique to the surface of the crystal.

Haüy, struck by some instances in which the supposition of such a structure of crystals appeared to account happily for several of their relations and properties, adopted and propounded it as a general theory. The small elements, of which he supposed crystals to be thus built up, he termed integrant molecules. The form of these molecules might or might not be the same as the primitive form with which his construction was supposed to begin; but there was, at any rate, a close connexion between these forms, since both of them were founded on the cleavage of the mineral. The tenet that crystals are constituted in the manner which I have been describing, I shall call the Theory of Integrant Molecules, and I have now to make some remarks on the grounds of this theory.

2. In the case of which I have spoken, the mineral used as the example, Galena, readily splits into cubes, and cubes are easily placed together so as to fit each other, and fill the space which they occupy. The same is the case in the mineral which suggested to Haüy his theory, namely, Calc Spar. The crystals of this substance are readily divisible into rhombohedrons, a form like a brick with oblique angles; and such bricks can be built together so as to produce crystals of all the immense varieties of form which Calc Spar presents. This kind of masonry is equally possible in many other 82 minerals; but as we go through the mineral kingdom in our survey, we soon find cases which offer difficulties. Some minerals cleave only in two directions, some in one only; in such cases we cannot by cleavage obtain an integrant molecule of definite form; one of its dimensions, at least, must remain indeterminate and arbitrary. Again, in some instances, we have more than three different planes of cleavage, as in Fluor Spar, where we have four. The solid, bounded by four planes, is a tetrahedron; or if we take four pairs of parallel faces, an octahedron. But if we attempt to take either of these forms for our integrant molecule, we are met by this difficulty: that a collection of such forms will not fill space. Perhaps this difficulty will be more readily conceived by the general reader if it be contemplated with reference to plane figures. It will readily be seen that a number of equal squares may be put together so as to fill the space which they occupy; but if we take a number of equal regular octagons, we may easily convince ourselves that no possible arrangement can make them cover a flat space without leaving blank spots between. In like manner octahedrons or tetrahedrons cannot be arranged in solid space so as to fill it. They necessarily leave vacancies. Hence the structure of Fluor Spar, and similar crystals, was a serious obstacle in the way of the theory of integrant molecules. That theory had been adopted in the first instance because portions of the crystal, obtained by cleavage, could be built up into a solid mass; but this ground of the theory failed altogether in such instances as I have described, and hence the theory, even upon the representations of its adherents, had no longer any claim to assent.

The doctrine of Integral Molecules, however, was by no means given up at once, even in such instances. In this and in other subjects, we may observe that a theory, once constructed and carried into detail, has such a hold upon the minds of those who have been in the habit of applying it, that they will attempt to uphold it by introducing suppositions inconsistent with 83 the original foundations of the theory. Thus those who assert the Atomic Theory, reconcile it with facts by taking the halves of atoms; and thus the Theory of Integrant Molecules was maintained for Fluor Spar, by representing the elementary octahedrons of which crystals are built up, as touching each other only by the edges. The contact of surface with surface amongst integrant molecules had been the first basis of the theory; but this supposition being here inapplicable, was replaced by one which made the theory no longer a representation of the facts (the cleavages), but a mere geometrical construction. Although, however, the inapplicability of the theory to such cases was thus, in some degree, disguised to the disciples of Haüy, it was plain that, in the face of such difficulties, the Theory of Integrant Molecules could not hold its place as a philosophical truth. But it still answered the purpose (a very valuable one, and one to which crystallography is much indebted,) of an instrument for calculating the geometrical relations of the parts of crystals to each other: for the integrant molecules were supposed to be placed layer above layer, each layer as we ascend, decreasing by a certain number of molecules and rows of molecules; and the calculation of these laws of decrement was, in fact, the best mode then known of determining the positions of the faces. The Theory of Decrements served to express and to determine, in a great number of the most obvious cases, the laws of phenomena in crystalline forms, though the Theory of Integrant Molecules could not be maintained as a just view of the structure of crystals.

3. The Theory of Integrant Molecules, however, involved this just and important principle: that a true view of the intimate structure of crystals must include and explain the facts of crystallization, that is, crystalline form and cleavage; and that it must take these into account, according to their degree of Symmetry. So far all theories concerning the elements of crystals must agree. And it was soon seen that this was, in reality, all that had been established by the investigations of Haüy and his school. I have already, in the 84 History, quoted Weiss’s reflections on making this step. ‘When in 1809,’ he says5, ‘I published my Dissertation, I shared the common opinion as to the necessity of the assumption, and the reality of the existence of a primitive form, at least in a sense not very different from the usual sense of the expression.’ He then proceeds to relate that he sought a ground for such an opinion, independent of the doctrine of Atoms, which he, in common with a great number of philosophers of that time in his own country, was disposed to reject, inclining to believe that the properties of bodies were determined by Forces which acted in them, and not by Molecules of which they were composed. He adds, that in pursuing this train of thought, he found, ‘that out of his Primitive Forms there was gradually unfolded to his hands that which really governs them, and is not affected by their casual fluctuations; namely, the Fundamental Relations of their Dimensions,’ or as we now may call them, Axes of Symmetry. With reference to these Axes, he found, as he goes on to say, that ‘a multiplicity of internal Oppositions, necessarily and mutually interdependent, are developed in the crystalline mass, each Relation having its own Polarity; so that the Crystalline Character is co-extensive with these Polarities.’ The character of these polarities, whether manifested in crystalline faces, cleavage, or any other incidents of crystallization, is necessarily displayed in the degree and kind of Symmetry which the crystal possesses: and thus this Symmetry, in all our speculations concerning the structure of crystals, necessarily takes the place of that enumeration of Primitive Forms which were rejected as inconsistent with observed facts, and destitute of sound scientific principle.

I may just notice here what I have stated in the History of Mineralogy6, that the distinction of systems of crystallization, as introduced by Weiss and Mohs, was strikingly confirmed by Sir David Brewster’s discoveries respecting the optical properties of minerals. 85 The splendid phenomena which were produced by passing polarized light through crystals, were found to vary according as the crystals were of the Rhombohedral, Square Pyramidal, Oblong Prismatic, or Tessular System. The Optical Symmetry exactly corresponded with the Geometrical Symmetry. In the two former Systems were crystals uniaxal in respect of their optical properties; the oblong prismatic, was biaxal; while in the tessular, the want of a predominant axis prevented the phenomena here spoken of from occurring at all. The optical experiments must have led, and would have led, to a classification of crystals into the above systems or something nearly equivalent, even had they not been already so arranged by attention to their forms.

4. While in Germany Weiss and Mohs with their disciples, were gradually rejecting what was superfluous in the previous crystallographical hypotheses, philosophers in England were also trying to represent to themselves the constitution of crystals in a manner which should be free from the obviously arbitrary and untenable fictions of the Haüyian school. These attempts, however, were not crowned with much success. One mode of representing the structure of crystals which suggested itself, was to reject the polyhedral forms which Haüy gave to his integrant molecules, and to conceive the elements of crystals as spheres, the properties of the crystal being determined not by the surfaces, but by the position of the elements. This was done by Wollaston, in the Philosophical Transactions for 1813. He applied this view to the tessular system, in which, indeed, the application is not difficult; and he showed that octahedral and tetrahedral figures may be deduced from symmetrical arrangements of equal spherules. But though in doing this, he manifested a perception of the conditions of the problem, he appeared to lose his hold on the real question when he tried to pass on to other systems of crystallization. For he accounted for the rhombohedral system by supposing the spheres changed into spheroids. Such a procedure involved him in a gratuitous and useless hypothesis: for to what purpose do we introduce the 86 arrangement of atoms (instead of their figure,) as a mode of explaining the symmetry of the crystallization, when at the next step we ascribe to the atom, by an arbitrary fiction, a symmetry of figure of the same kind as that which we have to explain? It is just as easy, and as allowable, to assume an elementary rhombohedron, as to assume elementary spheroids, of which the rhombohedrons are constructed.

5. Many hypotheses of the same kind might be adduced, devised both by mineralogists and chemists. But almost all such speculations have been pursued with a most surprising neglect of the principle which obviously is the only sound basis on which they can proceed. The principle is this:—that All hypotheses concerning the arrangement of the elementary atoms of bodies in space must be constructed with reference to the general facts of crystallization. The truth and importance of this principle can admit of no doubt. For if we make any hypothesis concerning the mode of connexion of the elementary particles of bodies, this must be done with the view of representing to ourselves the forces which connect them, and the results of these forces as manifested in the properties of the bodies. Now the forces which connect the particles of bodies so as to make them crystalline, are manifestly chemical forces. It is only definite chemical compounds which crystallize; and in crystals the force of cohesion by which the particles are held together cannot in any way be distinguished or separated from the chemical force by which their elements are combined. The elements are understood to be combined, precisely because the result is a definite, apparently homogeneous substance. The properties of the compound bodies depend upon the elements and their mode of combination; for, in fact, these include everything on which they can depend. There are no other circumstances than these which can affect the properties of a body. Therefore all those properties which have reference to space, namely, the crystalline properties, cannot depend upon anything else than the arrangement of the elementary molecules in space. These 87 properties are the facts which any hypothesis of the arrangement of molecules must explain, or at least render conceivable; and all such hypotheses, all constructions of bodies by supposed arrangements of molecules, can have no other philosophical object than to account for facts of this kind. If they do not do this, they are mere arbitrary geometrical fictions, which cannot be in any degree confirmed or authorised by an examination of nature, and are therefore not deserving of any regard.

6. Those philosophers who have endeavoured to represent the mode in which bodies are constructed by the combination of their chemical atoms, have often undertaken to show, not only that the atoms are combined, but also in what positions and configurations they are combined. And it is truly remarkable, as I have already said, that they have done this, almost in every instance, without any consideration of the crystalline character of the resulting combinations; from which alone we receive any light as to the relation of their elements in space. Thus Dr. Dalton, in his Elements of Chemistry, in which he gave to the world the Atomic Theory as a representation of the doctrine of definite and multiple proportions, also published a large collection of Diagrams, exhibiting what he conceived to be the configuration of the atoms in a great number of the most common combinations of chemical elements. Now these hypothetical diagrams do not in any way correspond, as to the nature of their symmetry, with the compounds, as we find them displaying their symmetry when they occur crystallized. Carbonate of lime has in reality a triangular symmetry, since it belongs to the rhombohedral system; Dr. Dalton’s carbonate of lime would be an oblique rhombic prism or pyramid. Sulphate of baryta is really two-and-two membered; Dr. Dalton’s diagram makes it two-and-one membered. Alum is really octahedral or tessular; but according to the diagram it could not be so, since the two ends of the atom are not symmetrical. And the same want of correspondence between the facts and the hypothesis runs through the whole 88 system. It need not surprise us that the theoretical arrangement of atoms does not explain the facts of crystallization; for to produce such an explanation would be a second step in science quite as great as the first, the discovery of the atomic theory in its chemical sense. But we may allow ourselves to be surprised that an utter discrepance between all the facts of crystallization and the figures assumed in the theory, did not suggest any doubt as to the soundness of the mode of philosophizing by which this part of the theory was constructed.

7. Some little accordance between the hypothetical arrangements of chemical atoms and the facts of crystallization, does appear to have been arrived at by some of the theorists to whom we here refer, although by no means enough to show a due conviction of the importance of the principle stated above. Thus Wollaston, in the Essay above noticed, after showing that a symmetrical arrangement of equal spherules would give rise to octahedral and other tessular figures, remarks, very properly, that the metals, which are simple bodies, crystallize in such forms. M. Ampère7 also, in 1814, published a brief account of an hypothesis of a somewhat similar nature, and stated himself to have developed this speculation in a Memoir which has not yet, so far as I am aware, been published. In this notice he conceives bodies to be compounded of molecules, which, arranged in a polyhedral form, constitute particles. These representative forms of the particles depend on chemical laws. Thus the particles of oxygen, of hydrogen, and of azote, are composed each of four molecules. Hence it is collected that the particles of nitrous gas are composed of two molecules of oxygen and two of azote; and similar conclusions are drawn respecting other substances. These conclusions, though expressed by means of the polyhedrons thus introduced, are supported by chemical, rather than by crystallographical comparisons. The author does, indeed, appeal to the crystallization of sal 89 ammoniac as an argument8; but as all the forms which he introduces appear to belong to the tessular system of crystallization, there is, in his reasonings, nothing distinctive; and therefore nothing, crystallographically speaking, of any weight on the side of this theory.

8. Any hypothesis which should introduce any principle of chemical order among the actual forms of minerals, would well deserve attention. At first sight, nothing can appear more anomalous than the forms which occur. We have, indeed, one broad fact, which has an encouraging aspect, the tessular forms in which the pure metals crystallize. The highest degree of chemical and of geometrical simplicity coincide: irregularity disappears precisely where it is excluded by the consideration above stated, that the symmetry of chemical composition must determine the symmetry of crystalline form9.

But if we go on to any other class of crystalline forms, we soon find ourselves lost in our attempts to 90 follow any thread of order. We have indeed many large groups connected by obvious analogies; as the rhombohedral carbonates of lime, magnesia, iron, manganese;—the prismatic carbonates and sulphates of lime, baryta, strontia, lead. But even in these, we cannot form any plausible hypothesis of the arrangement of the elements; and in other cases to which we naturally turn, we can find nothing but confusion. For instance, if we examine the oxides of metals:—those of iron are rhombohedral and tessular; those of copper, tessular; those of tin, of titanium, of manganese, square pyramidal; those of antimony, prismatic; and we have other forms for other substances.

It may be added, that if we take account of the optical properties which, as we have already stated, have constant relations to the crystalline forms, the confusion is still further increased; for the optical dimensions vary in amount, though not in symmetry, where chemistry can trace no difference of composition.

9. We will not quit the subject, however, without noticing the much more promising aspect which it has assumed by the detection of such groups as are referred to in the last article; or in other words, by Mitscherlich’s discovery of Isomorphism. According to that discovery, there are various elements which may take the place of each other in crystalline bodies, either without any alteration of the crystalline form, or at most with only a slight alteration of its dimensions. Such a group of elements we have in the earths lime and magnesia, the protoxides of iron and manganese: for the carbonates of all these bases occur crystallized in forms of the rhombohedral system, the characteristic angle being nearly the same in all. Now lime and magnesia, by the discoveries of modern chemistry, are really oxides of metals; and therefore all these carbonates have a similar chemical constitution, while they have also a similar crystalline form. Whether or no we can devise any arrangement of molecules by which this connexion of the chemical and the geometrical property can be represented, we cannot help 91 considering the connexion as an extremely important fact in the constitution of bodies; and such facts are more likely than any other to give us some intelligible view of the relations of the ultimate parts of bodies. The same may be said of all the other isomorphous or plesiomorphous groups10. For instance, we have a number of minerals which belong to the same system of crystallization, but in which the chemical composition appears at first sight to be very various: namely, spinelle, pleonaste, gahnite, franklinite, chromic iron oxide, magnetic iron oxide: but Abich has shown that all these may be reduced to a common chemical formula;—they are bioxides of one set of bases, combined with trioxides of another set. Perhaps some mathematician may be able to devise some geometrical arrangement of such a group of elements which may possess the properties of the tessular system. Hypothetical arrangements of atoms, thus expressing both the chemical and the crystalline symmetry which we know to belong to the substance, would be valuable steps in analytical science; and when they had been duly verified, the hypotheses might easily be divested of their atomic character.

Thus, as we have already said, mineralogy, understood in its wider sense, as the counterpart of chemistry, has for one of its main objects to discover those Relations of the Elements of bodies which have reference to Space. In this research, the foundation of all sound speculation is the kind and degree of Symmetry of form which we find in definite chemical compounds: and the problem at present before the inquirer is, to devise such arrangements of molecules as shall answer the conditions alike of Chemistry and of Crystallography.

We now proceed to the Classificatory Sciences, of which Mineralogy is one, though hitherto by far the least successful.