The Origin of the Trouble. Nowadays whenever enthusiasts meet together to discuss theoretical physics the talk sooner or later turns in a certain direction. You leave them conversing on their special problems or the latest discoveries; but return after an hour and it is any odds that they will have reached an all-engrossing topic—the desperate state of their ignorance. This is not a pose. It is not even scientific modesty, because the attitude is often one of naïve surprise that Nature should have hidden her fundamental secret successfully from such powerful intellects as ours. It is simply that we have turned a corner in the path of progress and our ignorance stands revealed before us, appalling and insistent. There is something radically wrong with the present fundamental conceptions of physics and we do not see how to set it right.
The cause of all this trouble is a little thing called which crops up continually in a wide range of experiments. In one sense we know just what is, because there are a variety of ways of measuring it; is That will (rightly) suggest to you that is something very small; but the most important information is contained in the concluding phrase erg-seconds. The erg is the unit of energy and the second is the unit of time; so that we learn that is of the nature of energy multiplied by time.
Now in practical life it does not often occur to us to multiply energy by time. We often divide energy by time. For example, the motorist divides the output of energy of his engine by time and so obtains the horse-power. Conversely an electric supply company multiplies the horse-power or kilowatts by the number of hours of consumption and sends in its bill accordingly. But to multiply by hours again would seem a very odd sort of thing to do.
But it does not seem quite so strange when we look at it in the absolute four-dimensional world. Quantities such as energy, which we think of as existing at an instant, belong to three-dimensional space, and they need to be multiplied by a duration to give them a thickness before they can be put into the four-dimensional world. Consider a portion of space, say Great Britain; we should describe the amount of humanity in it as 40 million men. But consider a portion of space-time, say Great Britain between 1915 and 1925; we must describe the amount of humanity in it as 400 million man-years. To describe the human content of the world from a space-time point of view we have to take a unit which is limited not only in space but in time. Similarly if some other kind of content of space is described as so many ergs, the corresponding content of a region of space-time will be described as so many erg-seconds.
We call this quantity in the four-dimensional world which is the analogue or adaptation of energy in the three-dimensional world by the technical name action. The name does not seem to have any special appropriateness, but we have to accept it. Erg-seconds or action belongs to Minkowski’s world which is common to all observers, and so it is absolute. It is one of the very few absolute quantities noticed in pre-relativity physics. Except for action and entropy (which belongs to an entirely different class of physical conceptions) all the quantities prominent in pre-relativity physics refer to the three-dimensional sections which are different for different observers.
Long before the theory of relativity showed us that action was likely to have a special importance in the scheme of Nature on account of its absoluteness, long before the particular piece of action h began to turn up in experiments, the investigators of theoretical dynamics were making great use of action. It was especially the work of Sir William Hamilton which brought it to the fore; and since then very extensive theoretical developments of dynamics have been made on this basis. I need only refer to the standard treatise on Analytical Dynamics by your own (Edinburgh) Professor[31], which fairly reeks of it. It was not difficult to appreciate the fundamental importance and significance of the main principle; but it must be confessed that to the non-specialist the interest of the more elaborate developments did not seem very obvious—except as an ingenious way of making easy things difficult. In the end the instinct which led to these researches has justified itself emphatically. To follow any of the progress in the quantum theory of the atom since about 1917, it is necessary to have plunged rather deeply into the Hamiltonian theory of dynamics. It is remarkable that just as Einstein found ready prepared by the mathematicians the Tensor Calculus which he needed for developing his great theory of gravitation, so the quantum physicists found ready for them an extensive action-theory of dynamics without which they could not have made headway.
But neither the absolute importance of action in the four-dimensional world, nor its earlier prominence in Hamiltonian dynamics, prepares us for the discovery that a particular lump of it can have a special importance. And yet a lump of standard size is continually turning up experimentally. It is all very well to say that we must think of action as atomic and regard this lump as the atom of action. We cannot do it. We have been trying hard for the last ten years. Our present picture of the world shows action in a form quite incompatible with this kind of atomic structure, and the picture will have to be redrawn. There must in fact be a radical change in the fundamental conceptions on which our scheme of physics is founded; the problem is to discover the particular change required. Since 1925 new ideas have been brought into the subject which seem to make the deadlock less complete, and give us an inkling of the nature of the revolution that must come; but there has been no general solution of the difficulty. The new ideas will be the subject of the next chapter. Here it seems best to limit ourselves to the standpoint of 1925, except at the very end of the chapter, where we prepare for the transition.
The Atom of Action. Remembering that action has two ingredients, namely, energy and time, we must look about in Nature for a definite quantity of energy with which there is associated some definite period of time. That is the way in which without artificial section a particular lump of action can be separated from the rest of the action which fills the universe. For example, the energy of constitution of an electron is a definite and known quantity; it is an aggregation of energy which occurs naturally in all parts of the universe. But there is no particular duration of time associated with it that we are aware of, and so it does not suggest to us any particular lump of action. We must turn to a form of energy which has a definite and discoverable period of time associated with it, such as a train of light-waves; these carry with them a unit of time, namely, the period of their vibration. The yellow light from sodium consists of aethereal vibrations of period 510 billions to the second. At first sight we seem to be faced with the converse difficulty; we have now our definite period of time; but how are we to cut up into natural units the energy coming from a sodium flame? We should, of course, single out the light proceeding from a single atom, but this will not break up into units unless the atom emits light discontinuously.
It turns out that the atom does emit light discontinuously. It sends out a long train of waves and then stops. It has to be restarted by some kind of stimulation before it emits again. We do not perceive this intermittence in an ordinary beam of light, because there are myriads of atoms engaged in the production.
The amount of energy coming away from the sodium atom during any one of these discontinuous emissions is found to be . This energy is, as we have seen, marked by a distinctive period . We have thus the two ingredients necessary for a natural lump of action. Multiply them together, and we obtain . That is the quantity .
The remarkable law of Nature is that we are continually getting the same numerical results. We may take another source of light—hydrogen, calcium, or any other atom. The energy will be a different number of ergs; the period will be a different number of seconds; but the product will be the same number of erg-seconds. The same applies to X-rays, to gamma rays and to other forms of radiation. It applies to light absorbed by an atom as well as to light emitted, the absorption being discontinuous also. Evidently is a kind of atom—something which coheres as one unit in the processes of radiation; it is not an atom of matter but an atom or, as we usually call it, a quantum of the more elusive entity action. Whereas there are 92 different kinds of material atoms there is only one quantum of action—the same whatever the material it is associated with. I say the same without reservation. You might perhaps think that there must be some qualitative difference between the quantum of red light and the quantum of blue light, although both contain the same number of erg-seconds; but the apparent difference is only relative to a frame of space and time and does not concern the absolute lump of action. By approaching the light-source at high speed we change the red light to blue light in accordance with Doppler’s principle; the energy of the waves is also changed by being referred to a new frame of reference. A sodium flame and a hydrogen flame are throwing out at us the same lumps of action, only these lumps are rather differently orientated with respect to the Now lines which we have drawn across the four-dimensional world. If we change our motion so as to alter the direction of the Now lines, we can see the lumps of sodium origin under the same orientation in which we formerly saw the lumps of hydrogen origin and recognise that they are actually the same.
We noticed in chapter IV that the shuffling of energy can become complete, so that a definite state is reached known as thermodynamical equilibrium; and we remarked that this is only possible if indivisible units are being shuffled. If the cards can be torn into smaller and smaller pieces without limit there is no end to the process of shuffling. The indivisible units in the shuffling of energy are the quanta. By radiation absorption and scattering energy is shuffled among the different receptacles in matter and aether, but only a whole quantum passes at each step. It was in fact this definiteness of thermodynamical equilibrium which first put Prof. Max Planck on the track of the quantum; and the magnitude of was first calculated by analysis of the observed composition of the radiation in the final state of randomness. Progress of the theory in its adolescent stage was largely due to Einstein so far as concerns the general principles and to Bohr as regards its connection with atomic structure.
The paradoxical nature of the quantum is that although it is indivisible it does not hang together. We examined first a case in which a quantity of energy was obviously cohering together, viz. an electron, but we did not find ; then we turned our attention to a case in which the energy was obviously dissolving away through space, viz. light-waves, and immediately appeared. The atom of action seems to have no coherence in space; it has a unity which overleaps space. How can such a unity be made to appear in our picture of a world extended through space and time?
Conflict with the Wave-Theory of Light. The pursuit of the quantum leads to many surprises; but probably none is more outrageous to our preconceptions than the regathering of light and other radiant energy into -units, when all the classical pictures show it to be dispersing more and more. Consider the light-waves which are the result of a single emission by a single atom on the star Sirius. These bear away a certain amount of energy endowed with a certain period, and the product of the two is . The period is carried by the waves without change, but the energy spreads out in an ever-widening circle. Eight years and nine months after the emission the wave-front is due to reach the earth. A few minutes before the arrival some person takes it into his head to go out and admire the glories of the heavens and—in short—to stick his eye in the way. The light-waves when they started could have had no notion what they were going to hit; for all they knew they were bound on a journey through endless space, as most of their colleagues were. Their energy would seem to be dissipated beyond recovery over a sphere of 50 billion miles’ radius. And yet if that energy is ever to enter matter again, if it is to work those chemical changes in the retina which give rise to the sensation of light, it must enter as a single quantum of action . Just must enter or none at all. Just as the emitting atom regardless of all laws of classical physics is determined that whatever goes out of it shall be just , so the receiving atom is determined that whatever comes into it shall be just . Not all the light-waves pass by without entering the eye; for somehow we are able to see Sirius. How is it managed? Do the ripples striking the eye send a message round to the back part of the wave, saying, “We have found an eye. Let’s all crowd into it!”
Attempts to account for this phenomenon follow two main devices which we may describe as the “collection-box” theory and the “sweepstake” theory, respectively. Making no effort to translate them into scientific language, they amount to this: In the first the atom holds a collection-box into which each arriving group of waves pays a very small contribution; when the amount in the box reaches a whole quantum, it enters the atom. In the second the atom uses the small fraction of a quantum offered to it to buy a ticket in a sweepstake in which the prizes are whole quanta; some of the atoms will win whole quanta which they can absorb, and it is these winning atoms in our retina which tell us of the existence of Sirius.
The collection-box explanation is not tenable. As Jeans once said, not only does the quantum theory forbid us to kill two birds with one stone; it will not even let us kill one bird with two stones. I cannot go fully into the reasons against this theory, but may illustrate one or two of the difficulties. One serious difficulty would arise from the half-filled collection-boxes. We shall see this more easily if, instead of atoms, we consider molecules which also absorb only full quanta. A molecule might begin to collect the various kinds of light which it can absorb, but before it has collected a quantum of any one kind it takes part in a chemical reaction. New compounds are formed which no longer absorb the old kinds of light; they have entirely different absorption spectra. They would have to start afresh to collect the corresponding kinds of light. What is to be done with the old accumulations now useless, since they can never be completed? One thing is certain; they are not tipped out into the aether when the chemical change occurs.
A phenomenon which seems directly opposed to any kind of collection-box explanation is the photoelectric effect. When light shines on metallic films of sodium, potassium, rubidium, etc., free electrons are discharged from the film. They fly away at high speed, and it is possible to measure experimentally their speed or energy. Undoubtedly it is the incident light which provides the energy of these explosions, but the phenomenon is governed by a remarkable rule. Firstly, the speed of the electrons is not increased by using more powerful light. Concentration of the light produces more explosions but not more powerful explosions. Secondly, the speed is increased by using bluer light, i.e. light of shorter period. For example, the feeble light reaching us from Sirius will cause more powerful ejections of electrons than full sunlight, because Sirius is bluer than the sun; the remoteness of Sirius does not weaken the ejections though it reduces their number.
This is a straightforward quantum phenomenon. Every electron flying out of the metal has picked up just one quantum from the incident light. Since the -rule associates the greater energy with the shorter vibration period, bluer light gives the more intense energy. Experiments show that (after deducting a constant “threshold” energy used up in extricating the electron from the film) each electron comes out with a kinetic energy equal to the energy of the quantum of incident light.
The film can be prepared in the dark; but on exposure to feeble light electrons immediately begin to fly out before any of the collection-boxes could have been filled by fair means. Nor can we appeal to any trigger action of the light releasing an electron already loaded up with energy for its journey; it is the nature of the light which settles the amount of the load. The light calls the tune, therefore the light must pay the piper. Only classical theory does not provide light with a pocket to pay from.
It is always difficult to make a fence of objections so thorough as to rule out all progress along a certain line of explanation. But even if it is still possible to wriggle on, there comes a time when one begins to perceive that the evasions are far-fetched. If we have any instinct that can recognise a fundamental law of Nature when it sees one, that instinct tells us that the interaction of radiation and matter in single quanta is something lying at the root of world-structure and not a casual detail in the mechanism of the atom. Accordingly we turn to the “sweepstake” theory, which sees in this phenomenon a starting-point for a radical revision of the classical conceptions.
Suppose that the light-waves are of such intensity that, according to the usual reckoning of their energy, one-millionth of a quantum is brought within range of each atom. The unexpected phenomenon is that instead of each atom absorbing one-millionth of a quantum, one atom out of every million absorbs a whole quantum. That whole quanta are absorbed is shown by the photoelectric experiments already described, since each of the issuing electrons has managed to secure the energy of a whole quantum.
It would seem that what the light-waves were really bearing within reach of each atom was not a millionth of a quantum but a millionth chance of securing a whole quantum. The wave-theory of light pictures and describes something evenly distributed over the whole wave-front which has usually been identified with energy. Owing to well-established phenomena such as interference and diffraction it seems impossible to deny this uniformity, but we must give it another interpretation; it is a uniform chance of energy. Following the rather old-fashioned definition of energy as “capacity for doing work” the waves carry over their whole front a uniform chance of doing work. It is the propagation of a chance which the wave-theory studies.
Different views may be held as to how the prize-drawing is conducted on the sweepstake theory. Some hold that the lucky part of the wave-front is already marked before the atom is reached. In addition to the propagation of uniform waves the propagation of a photon or “ray of luck” is involved. This seems to me out of keeping with the general trend of the modern quantum theory; and although most authorities now take this view, which is said to be indicated definitely by certain experiments, I do not place much reliance on the stability of this opinion.
Theory of the Atom. We return now to further experimental knowledge of quanta. The mysterious quantity crops up inside the atom as well as outside it. Let us take the simplest of all atoms, namely, the hydrogen atom. This consists of a proton and an electron, that is to say a unit charge of positive electricity and a unit charge of negative electricity. The proton carries nearly all the mass of the atom and remains rock-like at the centre, whilst the nimble electron moves round in a circular or elliptic orbit under the inverse-square law of attraction between them. The system is thus very like a sun and a planet. But whereas in the solar system the planet’s orbit may be of any size and any eccentricity, the electron’s orbit is restricted to a definite series of sizes and shapes. There is nothing in the classical theory of electromagnetism to impose such a restriction; but the restriction exists, and the law imposing it has been discovered. It arises because the atom is arranging to make something in its interior equal to . The intermediate orbits are excluded because they would involve fractions of , and cannot be divided.
But there is one relaxation. When wave-energy is sent out from or taken into the atom, the amount and period must correspond exactly to . But as regards its internal arrangements the atom has no objection to , , , etc.; it only insists that fractions shall be excluded. That is why there are many alternative orbits for the electron corresponding to different integral multipliers of . We call these multipliers quantum numbers, and speak of 1-quantum orbits, 2-quantum orbits, etc. I will not enter here into the exact definition of what it is that has to be an exact multiple of ; but it is something which, viewed in the four-dimensional world, is at once seen to be action though this may not be so apparent when we view it in the ordinary way in three-dimensional sections. Also several features of the atom are regulated independently by this rule, and accordingly there are several quantum numbers—one for each feature; but to avoid technical complication I shall refer only to the quantum numbers belonging to one leading feature.
According to this picture of the atom, which is due to Niels Bohr, the only possible change of state is the transfer of an electron from one quantum orbit to another. Such a jump must occur whenever light is absorbed or emitted. Suppose then that an electron which has been travelling in one of the higher orbits jumps down into an orbit of less energy. The atom will then have a certain amount of surplus energy that must be got rid of. The lump of energy is fixed, and it remains to settle the period of vibration that it shall have when it changes into aether-waves. It seems incredible that the atom should get hold of the aether and shake it in any other period than one of those in which it is itself vibrating. Yet it is the experimental fact that, when the atom by radiating sets the aether in vibration, the periods of its electronic circulation are ignored and the period of the aether-waves is settled not by any picturable mechanism but by the seemingly artificial -rule. It would seem that the atom carelessly throws overboard a lump of energy which, as it glides into the aether, moulds itself into a quantum of action by taking on the period required to make the product of energy and period equal to . If this unmechanical process of emission seems contrary to our preconceptions, the exactly converse process of absorption is even more so. Here the atom has to look out for a lump of energy of the exact amount required to raise an electron to the higher orbit. It can only extract such a lump from aether-waves of particular period—not a period which has resonance with the structure of the atom, but the period which makes the energy into an exact quantum.
As the adjustment between the energy of the orbit jump and the period of the light carrying away that energy so as to give the constant quantity is perhaps the most striking evidence of the dominance of the quantum, it will be worth while to explain how the energy of an orbit jump in an atom can be measured. It is possible to impart to a single electron a known amount of energy by making it travel along an electric field with a measured drop of potential. If this projectile hits an atom it may cause one of the electrons circulating in the atom to jump to an upper orbit, but, of course, only if its energy is sufficient to supply that required for the jump; if the electron has too little energy it can do nothing and must pass on with its energy intact. Let us fire a stream of electrons all endowed with the same known energy into the midst of a group of atoms. If the energy is below that corresponding to an orbit jump, the stream will pass through without interference other than ordinary scattering. Now gradually increase the energy of the electrons; quite suddenly we find that the electrons are leaving a great deal of their energy behind. That means that the critical energy has been reached and orbit jumps are being excited. Thus we have a means of measuring the critical energy which is just that of the jump—the difference of energy of the two states of the atom. This method of measurement has the advantage that it does not involve any knowledge of the constant , so that there is no fear of a vicious circle when we use the measured energies to test the rule.[32] Incidentally this experiment provides another argument against the collection-box theory. Small contributions of energy are not thankfully received, and electrons which offer anything less than the full contribution for a jump are not allowed to make any payment at all.
Relation of Classical Laws to Quantum Laws. To follow up the verification and successful application of the quantum laws would lead to a detailed survey of the greater part of modern physics—specific heats, magnetism, X-rays, radioactivity, and so on. We must leave this and return to a general consideration of the relation between classical laws and quantum laws. For at least fifteen years we have used classical laws and quantum laws alongside one another notwithstanding the irreconcilability of their conceptions. In the model atom the electrons are supposed to traverse their orbits under the classical laws of electrodynamics; but they jump from one orbit to another in a way entirely inconsistent with those laws. The energies of the orbits in hydrogen are calculated by classical laws; but one of the purposes of the calculation is to verify the association of energy and period in the unit , which is contrary to classical laws of radiation. The whole procedure is glaringly contradictory but conspicuously successful.
In my observatory there is a telescope which condenses the light of a star on a film of sodium in a photoelectric cell. I rely on the classical theory to conduct the light through the lenses and focus it in the cell; then I switch on to the quantum theory to make the light fetch out electrons from the sodium film to be collected in an electrometer. If I happen to transpose the two theories, the quantum theory convinces me that the light will never get concentrated in the cell and the classical theory shows that it is powerless to extract the electrons if it does get in. I have no logical reason for not using the theories this way round; only experience teaches me that I must not. Sir William Bragg was not overstating the case when he said that we use the classical theory on Mondays, Wednesday and Fridays, and the quantum theory on Tuesdays, Thursdays and Saturdays. Perhaps that ought to make us feel a little sympathetic towards the man whose philosophy of the universe takes one form on weekdays and another form on Sundays.
In the last century—and I think also in this—there must have been many scientific men who kept their science and religion in watertight compartments. One set of beliefs held good in the laboratory and another set of beliefs in church, and no serious effort was made to harmonise them. The attitude is defensible. To discuss the compatibility of the beliefs would lead the scientist into regions of thought in which he was inexpert; and any answer he might reach would be undeserving of strong confidence. Better admit that there was some truth both in science and religion; and if they must fight, let it be elsewhere than in the brain of a hard-working scientist. If we have ever scorned this attitude, Nemesis has overtaken us. For ten years we have had to divide modern science into two compartments; we have one set of beliefs in the classical compartment and another set of beliefs in the quantum compartment. Unfortunately our compartments are not watertight.
We must, of course, look forward to an ultimate reconstruction of our conceptions of the physical world which will embrace both the classical laws and the quantum laws in harmonious association. There are still some who think that the reconciliation will be effected by a development of classical conceptions. But the physicists of what I may call “the Copenhagen school” believe that the reconstruction has to start at the other end, and that in the quantum phenomena we are getting down to a more intimate contact with Nature’s way of working than in the coarse-grained experience which has furnished the classical laws. The classical school having become convinced of the existence of these uniform lumps of action, speculates on the manufacture of the chopper necessary to carve off uniform lumps; the Copenhagen school on the other hand sees in these phenomena the insubstantial pageant of space, time and matter crumbling into grains of action. I do not think that the Copenhagen school has been mainly influenced by the immense difficulty of constructing a satisfactory chopper out of classical material; its view arises especially from a study of the meeting point of quantum and classical laws.
The classical laws are the limit to which the quantum laws tend when states of very high quantum number are concerned.
This is the famous Correspondence Principle enunciated by Bohr. It was at first a conjecture based on rather slight hints; but as our knowledge of quantum laws has grown, it has been found that when we apply them to states of very high quantum number they converge to the classical laws, and predict just what the classical laws would predict.
For an example, take a hydrogen atom with its electron in a circular orbit of very high quantum number, that is to say far away from the proton. On Monday, Wednesday and Friday it is governed by classical laws. These say that it must emit a feeble radiation continuously, of strength determined by the acceleration it is undergoing and of period agreeing with its own period of revolution. Owing to the gradual loss of energy it will spiral down towards the proton. On Tuesday, Thursday and Saturday it is governed by quantum laws and jumps from one orbit to another. There is a quantum law that I have not mentioned which prescribes that (for circular orbits only) the jump must always be to the circular orbit next lower, so that the electron comes steadily down the series of steps without skipping any. Another law prescribes the average time between each jump and therefore the average time between the successive emissions of light. The small lumps of energy cast away at each step form light-waves of period determined by the rule.
“Preposterous! You cannot seriously mean that the electron does different things on different days of the week!”
But did I say that it does different things? I used different words to describe its doings. I run down the stairs on Tuesday and slide down the banisters on Wednesday; but if the staircase consists of innumerable infinitesimal steps, there is no essential difference in my mode of progress on the two days. And so it makes no difference whether the electron steps from one orbit to the next lower or comes down in a spiral when the number of steps is innumerably great. The succession of lumps of energy cast overboard merges into a continuous outflow. If you had the formulae before you, you would find that the period of the light and the strength of radiation are the same whether calculated by the Monday or the Tuesday method—but only when the quantum number is infinitely great. The disagreement is not very serious when the number is moderately large; but for small quantum numbers the atom cannot sit on the fence. It has to decide between Monday (classical) and Tuesday (quantum) rules. It chooses Tuesday rules.
If, as we believe, this example is typical, it indicates one direction which the reconstruction of ideas must take. We must not try to build up from classical conceptions, because the classical laws only become true and the conceptions concerned in them only become defined in the limiting case when the quantum numbers of the system are very large. We must start from new conceptions appropriate to low as well as to high numbered states; out of these the classical conceptions should emerge, first indistinctly, then definitely, as the number of the state increases, and the classical laws become more and more nearly true. I cannot foretell the result of this remodelling, but presumably room must be found for a conception of “states”, the unity of a state replacing the kind of tie expressed by classical forces. For low numbered states the current vocabulary of physics is inappropriate; at the moment we can scarcely avoid using it, but the present contradictoriness of our theories arises from this misuse. For such states space and time do not exist—at least I can see no reason to believe that they do. But it must be supposed that when high numbered states are considered there will be found in the new scheme approximate counterparts of the space and time of current conception—something ready to merge into space and time when the state numbers are infinite. And simultaneously the interactions described by transitions of states will merge into classical forces exerted across space and time. So that in the limit the classical description becomes an available alternative. Now in practical experience we have generally had to deal with systems whose ties are comparatively loose and correspond to very high quantum numbers; consequently our first survey of the world has stumbled across the classical laws and our present conceptions of the world consist of those entities which only take definite shape for high quantum numbers. But in the interior of the atom and molecule, in the phenomena of radiation, and probably also in the constitution of very dense stars such as the Companion of Sirius, the state numbers are not high enough to admit this treatment. These phenomena are now forcing us back to the more fundamental conceptions out of which the classical conceptions (sufficient for the other types of phenomena) ought to emerge as one extreme limit.
For an example I will borrow a quantum conception from the next chapter. It may not be destined to survive in the present rapid evolution of ideas, but at any rate it will illustrate my point. In Bohr’s semi-classical model of the hydrogen atom there is an electron describing a circular or elliptic orbit. This is only a model; the real atom contains nothing of the sort. The real atom contains something which it has not entered into the mind of man to conceive, which has, however, been described symbolically by Schrödinger. This “something” is spread about in a manner by no means comparable to an electron describing an orbit. Now excite the atom into successively higher and higher quantum states. In the Bohr model the electron leaps into higher and higher orbits. In the real atom Schrödinger’s “something” begins to draw itself more and more together until it begins sketchily to outline the Bohr orbit and even imitates a condensation running round. Go on to still higher quantum numbers, and Schrödinger’s symbol now represents a compact body moving round in the same orbit and the same period as the electron in Bohr’s model, and moreover radiating according to the classical laws of an electron. And so when the quantum number reaches infinity, and the atom bursts, a genuine classical electron flies out. The electron, as it leaves the atom, crystallises out of Schrödinger’s mist like a genie emerging from his bottle.
[31] Prof. E. T. Whittaker.
[32] Since the rule is now well established the energies of different states of the atoms are usually calculated by its aid; to use these to test the rule would be a vicious circle.