Flores Rosæ rubræ; Red Rose Petals, Rose Leaves, True Provins Roses; F. Pétales de Roses rouges, Roses de Provins; G. Essigrosenblätter.
Botanical Origin—Rosa gallica L., a low-growing bush, with a creeping rhizome throwing up numerous stems. The wild form with single flowers occurs here and there in the warmer parts of Europe,[986] including Central and Southern Russia, and Greece; also in Asia Minor, Armenia, Kurdistan, and the Caucasus. But the plant passes into so many varieties, and has from a remote period been so widely cultivated, that its distribution cannot be ascertained with any exactness. As a garden plant it exists under a multitude of forms.
History—The use in medicine of the rose dates from a very remote period. Theophrastus[987] speaks of roses being of many kinds, including some with double flowers which were the most fragrant; and he also alludes to their use in the healing art. Succeeding writers of every age down to a recent period have discussed the virtues of the rose,[988] which however is scarcely now admitted to possess any special medicinal property.
One of the varieties of R. gallica is the Provins Rose, so called from having been long cultivated at Provins, a small town about 60 miles south-east of Paris, where it is said to have been introduced from the East by Thibaut VI., Count of Champagne, on his return from the Crusades, a.d. 1241. But it appears that he went then to Navarre and in later times never resided in the Champagne. Be this as it may, Provins became much celebrated not only for its dried rose petals, but also for the conserve, syrup and honey of roses made from them,—compositions which were regarded in the light of valuable medicines.[989]
It is recorded that when, in a.d. 1310, Philippe de Marigny, archbishop of Sens, made a solemn entry into Provins, he was presented by the notables of the town with wine, spices, and Conserve of Roses; and presents of dried roses and of the conserve were not considered beneath the notice of Catherine de Medicis, and of Henry IV.[990]
We find that Charles Estienne, in 1536, mentions both the Rosæ purpureæ odoratissimæ, which he says are called Provinciales, and those known to the druggists as incarnatæ,—the latter we presume a pale rose.[991] Rosæ rubeæ are named as an ingredient of various compound medicines by Valerius Cordus.[992]
Production—The flowers are gathered while in bud and just before expansion, and the petals are cut off near the base, leaving the paler claws attached to the calyx. They are then carefully and rapidly dried by the heat of a stove, and having been gently sifted to remove loose stamens, are ready for sale. In some districts the petals are dried entire, but the drug thus produced is not so nice.
In England, the Red Rose is cultivated at Mitcham, though now only to the extent of about 10 acres. It is also grown for druggists’ use in Oxfordshire and Derbyshire. At Mitcham, it is now called Damask Rose, which is by no means a correct name. The English dried roses command a high price.
There is a much more extensive cultivation of this rose on the continent at Wassenaar and Noordwijk in Holland; in the vicinity of Hamburg and Nuremberg in Germany, and in the villages round Paris and Lyons. Roses are still, we believe, grown for medicinal use at Provins, but are no longer held in great esteem.
There appears to be a considerable production of dried roses in Persia, judging from the fact that in the year 1871-72, 1163 cwt. were exported from the Persian Gulf to Bombay.[993]
Description—The petals adhere together loosely in the form of little cones, or are more or less crumpled and separate. When well preserved, they are crisp and dry, with a velvety surface of an intense purplish crimson, a delicious rosy odour, and a mildly astringent taste. The white basal portion of the petals should be nearly absent. For making the confection, the petals are required in a fresh state.
Chemical Composition—Red rose petals impart to ether, without losing their colour, a soft yellow substance, which is a mixture of a solid fat and Quercitrin. Filhol has shown (1864) that it is the latter body, and not tannic acid, of which the petals contain but a trace, that produces the dark greenish precipitate with ferric salts. The same chemist found in the petals 20 per cent. (?) of glucose which, together with colouring matter and gallic acid, is extracted by alcohol after exhaustion by ether. According to Rochleder (1867), the gallic acid in red roses is accompanied by querci-tannic acid.
The colouring matter which is so striking a constituent of the petals, is according to Senier an acid, which appears to form crystallizable salts with potassium and sodium.[994] An infusion of the petals is pale red, but becomes immediately of a deep and brilliant crimson if we add to it an acid, such as sulphuric, hydrochloric, acetic, oxalic, or tartaric. An alkali changes the pale red, or the deep crimson in the case of the acidulated infusion, to bright green.
Uses—An infusion of red rose petals, acidulated with sulphuric acid and slightly sweetened, is a very common and agreeable vehicle for some other medicines. The confection made by beating up the petals with sugar, is also in use.
Flores Rosæ pallidæ v. incarnatæ; Provence Rose, Cabbage Rose; F. Pétales de Roses pâles; G. Centifolienrosen.
Botanical Origin—Rosa centifolia L.—This rose grows in a wild state and with single flowers in the eastern part of the Caucasus.[995] Cultivated and with flowers more or less double, it is found under an infinity of varieties in all the temperate regions of the globe. The particular variety which is grown in England for medicinal use, is known in English gardens as the Cabbage Rose, but other varieties are cultivated for similar purposes on the Continent.
R. centifolia L. is very closely allied to R. gallica L.; though Boissier maintains the two species, there are other botanists who regard them as but one. The rose cultivated at Puteaux near Paris for druggists’ use, and hence called Rose de Puteaux, is the Rosa bifera of Redouté, placed by De Candolle though doubtfully under R. damascena.
History—We are unable to trace the history of the particular variety of rose under notice. That it is not of recent origin, seems evident from its occurrence chiefly in old gardens. The Rosa pallida of the older English writers on drugs[996] was called Damask Rose, but that name is now applied at Mitcham to Rosa gallica L., which has very deep-coloured flowers.
Production—The Cabbage Rose is cultivated in England to a very small extent, rose water, which is made from its flowers, being procurable of better quality and at a lower cost in other countries, especially in the south of France. At Mitcham, whence the London druggists have long been supplied, there are now (1873) only about 8 acres planted with this rose, but a supply is also derived from the market gardens of Putney, Hammersmith and Fulham.
Description—The Cabbage Rose is supplied to the druggists in the fresh state, full blown, and picked off close below the calyx. A complete description is scarcely required: we need only say that it is a large and very double rose, of a beautiful pink colour and of delicious odour. The calyx is covered with short setæ tipped with a fragrant, brown, viscid secretion. The petals are thin and delicate (not thick and leathery as in the Tea Roses), and turn brown on drying.
In making rose water, it is the custom in some laboratories to strip the petals from the calyx and to reject the latter; in others, the roses are distilled entire, and so far as we have observed, with equally good result.
Chemical Composition—In a chemical point of view, the petals of R. centifolia agree with those of R. gallica, even as to the colouring matter. Enz in 1867 obtained from the former, malic and tartaric acid, tannin, fat, resin, and sugar.
In the distillation of large quantities of the flowers, a little essential oil is obtained. It is a butyraceous substance, of weak rose-like, but not very agreeable odour. It contains a large proportion of inodorous stearoptene. For further particulars see remarks under the head Attar of Rose.
Uses—Cabbage roses are now scarcely employed in pharmacy for any other purpose than making rose water. A syrup used to be prepared from them, which was esteemed a mild laxative.
Attar or Otto[997] of Rose, Rose Oil; F. Essence de Roses; G. Rosenöl.
Botanical Origin—Rosa damascena Miller, var.—This is the rose cultivated in Turkey for the production of attar of rose; it is a tall shrub with semi-double, light-red (rarely white) flowers, of moderate size, produced several on a branch, though not in clusters. Living specimens sent by Baur[998] which flowered at Tübingen, were examined by H. von Mohl and named as above.[999]
R. damascena is unknown in a wild state. Koch[1000] asserts that it was brought in remote times to Southern Italy, whence it spread northward. In the opinion of Baker[1001] Rosa damascena is to be referred to Rosa gallica (see p. 259 above); it must be granted that the Rose mentioned in footnote 2, as grown with one of us, approaches very much to Rosa gallica.
History—Much as roses were prized by the ancients, no preparation such as rose water or attar of rose was obtained from them. The liquid that bore the name of Rose Oil (ῤόδινον ἔλαιον) is stated by Dioscorides[1002] to be a fatty oil in which roses have been steeped. In Europe a similar preparation was in use down to the last century, Oleum rosarum, rosatum or rosaceum, signifying an infusion of roses in olive oil in the London Pharmacopœia of 1721.
The first allusion to the distillation of roses we have met with, is in the writings of Joannes Actuarius,[1003] who was physician to the Greek emperors at Constantinople towards the close of the 13th century. Rose water was distilled at an early date in Persia; and Nisibin, a town north-west of Mosul, was famous for it in the 14th century.[1004]
Kämpfer speaks[1005] with admiration of the roses he saw at Shiraz (1683-4), and says that the water distilled from them is exported to other parts of Persia, as well as to all India; and he adds as a singular fact, that there separates from it a certain fat-like butter, called Ættr gyl, of the most exquisite odour, and more valuable even than gold. The commerce to India, though much declining, still exists; and in the year 1872-73, 20,100 gallons of rose water, valued at 35,178 rupees (£3,517), were imported into Bombay from the Persian Gulf.[1006] Rose oil itself is no longer exported from Persia, as it still used to be from Shiraz in the time of Niebuhr (1778).
Rose water was much used in Europe during the middle ages, both in cookery and at the table. In some parts of France, vassals were compelled to furnish to their lords so many bushels of roses, which were consumed in the distillation of rose water.[1007]
The fact that a butyraceous oil of delicious fragrance is separable from rose water, was noticed by Geronimo Rossi[1008] of Ravenna in 1582 (or in 1574?) and by Giovanni Battista Porta[1009] of Naples in 1589; the latter in his work on distillation says—“Omnium difficillime extractionis est rosarum oleum atque in minima quantitate sed suavissimi odoris.”[1010] The oil was also known to the apothecaries of Germany in the beginning of the 17th century, and is quoted in official drug-tariffs of that time.[1011] Angelus Sala, about 1620, in describing the distillation of the oil speaks of it as being of “ ... candicante pinguedine instar Spermatis Ceti.” In Pomet’s time (1694) it was sold in Paris, though, on account of its high price, only in very small quantity. The mention of it by Homberg[1012] in 1700, and in a memoir by Aublet[1013] (1775) respecting the distillation of roses in the Isle of France, shows that the French perfumers of the last century were not unacquainted with true rose oil, but that it was a rare and very costly article.
The history of the discovery of the essence in India, is the subject of an interesting and learned pamphlet by Langlès,[1014] published in 1804. He tells us on the authority of oriental writers, how on the occasion of the marriage of the Mogul emperor Jehan Ghir with Nur-jehan, a.d. 1612, a canal in the garden of the palace was filled with rose water, and that the princess observing a certain scum on the surface, caused it to be collected and found it of admirable fragrance, on which account it received the name of Atar-jehanghiri, i.e. perfume of Jehan Ghir. In later times, Polier[1015] has shown that rose oil is prepared in India by simple distillation of the flowers with water. But this Indian oil has never been imported into Europe as an article of trade.
As already stated, the supplies at present come from European Turkey; but at what period the cultivation of the rose and manufacture of its oil were then introduced, is a question on which we are quite in the dark. There is no mention of attar in the account given by Savary[1016] in 1750 of the trade of Constantinople and Smyrna, but in the first years of the present century some rose oil was obtained in the Island of Chios as well as in Persia.[1017]
In English commerce, attar of rose was scarcely known until the commencement of the present century. It was first included in the British tariff in 1809, when the duty levied on it was 10s. per ounce. In 1813 the duty was raised to 11s. 10½d.; in 1819 it was 6s., and in 1828, 2s. per ounce. In 1832 it was lowered to 1s. 4d. per lb., in 1842 to 1s. and in 1860 it was altogether removed.[1018]
On searching a file of the London Price Current, the first mention of “Otto of Rose” is in 1813, from which year it is regularly quoted. The price (in bond) from 1813 to 1815, varied from £3 to £5 5s. per ounce. The earliest notice of an importation is under date 1-8 July, 1813, when duty was paid on 232 ounces, shipped from Smyrna.
Production—The chief locality for attar of rose, and that by which European commerce is almost exclusively supplied, is a small tract of country on the southern side of the Balkan mountains, the “Tekne” of Kazanlik or Kisanlik, an undulated plain famous for its beauty, as picturesquely sketched by Kanitz[1019] and many other travellers. The principal seat of the trade is the town of Kizanlik, in the valley of the Tunja. The other important districts are those of Philippopli, Eski Zaghra, Yeni Zaghra, Tchirpan, Giopca, Karadsuh-Dagh, Kojun-Tepe, Pazandsik. North of the Balkans, there is only Travina to be mentioned as likewise producing attar. All these places with Kizanlik were estimated in 1859 to include 140 villages, having 2,500 stills.
The rose is cultivated by peasants in gardens and open fields, in which it is planted in rows as hedges, 3 to 4 feet high. The best localities are those occupying southern or south-eastern slopes. Plantations in high mountainous situations generally yield less, and the oil is of a quality that easily congeals. The flowers attain perfection in April and May, and are gathered before sunrise; those not wanted for immediate use are spread out in cellars, but are always used for distilling the same day. The apparatus is a copper still of the simplest description, connected with a straight tin tube, cooled by being passed through a tub fed by a stream of water. The largest establishment, “Fabrika,” at Kizanlik has 14 such stills. The charge for a still is 25 to 50 lb. of roses, from which the calyces are not removed. The first runnings are returned to the still; the second portion, which is received in glass flasks, is kept at a temperature not lower than 15° C. for a day or two, by which time most of the oil, bright and fluid, will have risen to the surface. From this, it is skimmed off by means of a small tin funnel having a fine orifice, and provided with a long handle. There are usually several stills together.
The produce is extremely variable. According to Baur,[1020] whose interesting account of attar of rose is that of an eye-witness, it may be said to average 0·04 per cent. Another authority estimates the average yield as 0·037 per cent.
The harvest during the five years 1867-71 was reckoned to average somewhat below 400,000 meticals,[1021] or 4226 lb. avoirdupois; that of 1873, which was good, was estimated at 500,000 meticals, value about £70,000.[1022]
Roses are cultivated to a considerable extent about Grasse, Cannes and Nice in the south of France; and besides much rose water, which is largely exported to England, a little oil is produced. The latter, which commands a high price, fuses less easily than the Turkish.
There is a large cultivation of the rose for the purpose of making rose water and attar, at Ghazipur on the Ganges, Lahore, Amritsar and other places in India, but the produce is wholly consumed in the country. The species thus cultivated is stated by Brandis[1023] to be R. damascena. Medinet Fayum, south-west of Cairo, supplies the great demand of Egypt for rose vinegar and rose water.
Tunis has also some celebrity for similar products, which however do not reach Europe. A recent traveller[1024] states that the rose grown there, and from which attar is obtained, is Rosa canina L., which is extremely fragrant; 30 lb. of the flowers afford about 1½ drachms, worth 15s. When at Genoa, in 1874, one of us (F.) had the opportunity of ascertaining that excellent oil of rose is occasionally imported there from Tunis.
The butyraceous oil which may be collected in distilling roses in England for rose water is of no value as a perfume.
Description—Oil of rose is a light yellow liquid, of sp. gr. 0·87 to 0·89. By a reduction of temperature, it concretes owing to the separation of light, brilliant, platy crystals of a stearoptene, the proportion of which differs with the country in which the roses have been grown, the state of the weather during which the flowers were gathered, and other circumstances less well ascertained. The oil produced in the Balkans solidifies, according to Baur, at from 11 to 16° C. In some experiments made by one of us[1025] in 1859, the fusing point of true Turkish attar was found to vary from 16 to 18°; that of a sample from India was 20° C.; of oil distilled in the south of France, 21 to 23°, of an oil produced in Paris, 29°; of oil obtained in distilling roses for rose water in London, 30 to 32° C.
From these data, it appears that a cool northern climate is not conducive to the production of a highly odorous oil; and even in Bulgaria experience shows that the oil of the mountain districts holds a larger proportion of stearoptene than that of the lowlands.
Turkish oil of rose is stated by Baur to deviate a ray of polarized light 4° to the right, when examined in a column of 100 mm. The oil from English roses which we examined exhibited no rotation.
Chemical Composition—Rose oil is a mixture of a liquid constituent containing oxygen, to which it owes its perfume, and the solid hydrocarbon or stearoptene already mentioned, which is entirely destitute of odour. The proportion which these bodies bear to each other is extremely variable. From the Turkish oil, it may be obtained to the extent of 18 per cent., and from French and English to 35, 42, 60 or even 68 per cent.
Though the stearoptene can be entirely freed from the oxygenated oil, no method is known for the complete isolation of the latter. As obtained by Gladstone[1026], it had a sp. gr. of 0·881 and a boiling point of 216° C.
With regard to the stearoptene of rose oil, the analyses of Théodore de Saussure (1820) and Blanchet (1833) long since showed its composition to accord with the formula CₙH₂ₙ. The experiments of one of us[1027] confirm this striking fact, which assigns to the stearoptene in question a very exceptional place among the hydrocarbons of volatile oils, all of which are less rich in hydrogen.
Rose stearoptene separates when attar of roses is mixed with alcohol. We have isolated it also from oil obtained from Mitcham roses, by diluting the oil with a little chloroform and precipitating with glacial acetic acid or spirit of wine, the process being several times repeated. The stearoptene was lastly maintained for some days at 100° C.; thus obtained, it is inodorous, but when heated evolves an offensive smell like that of heated wax or fat. At 32·5° it melts; at 150° vapour is evolved; at 272° C. it begins to boil, soon after which it turns brown and then blackish. Stains of the stearoptene on paper do not disappear by the heat of the water-bath and the relapse of some days.
If cautiously melted by the warmth of the sun, the stearoptene forms on cooling microscopic crystals of very peculiar shape. Most of them have the form of truncated hexahedral pyramids, not however belonging to the rhombohedric system, as the angles are evidently not equal; many of them are oddly curved, thus §. Examined under the polarizing microscope, these crystals from their refractive power make a brilliant object.
Rose stearoptene is a very stable body, yet by boiling it for some days with fuming nitric acid, it is slowly dissolved, and converted into various acids of the homologous series of fatty acids, and into oxalic acid. Among the former, we detected butyric and valerianic. The chief product is however succinic acid, which we obtained in pure crystals, showing all the well-known reactions.
The same products are obtained even much easier by treating paraffin with nitric acid; it yields however less of succinic acid. The general behaviour and appearance of paraffin is in fact nearly the same as that of rose stearoptene. But what is called paraffin, is a series of extremely similar hydrocarbons, answering to the general formula CₙH₍₂ₙ₊₂₎ (n being equal to more than 16), the separation of which has not yet been thoroughly effected. The fusion point of the different kinds of paraffin generally ranges from 42 to 60° C., yet one sort from the bituminous shale of Autun, prepared and examined by Laurent,[1028] melts at 33° C., and in this respect agrees with our stearoptene. It is therefore possible that the latter actually belongs to the paraffin series.
We have not ascertained the correctness of Baur’s strange experiments (1872, Jahresbericht der Pharm. p. 460), by which he believes to have converted the liquid part of rose oil into the stearoptene by means of a current of hydrogen.
Commerce—Formerly attar of rose came into commerce by way of Austria; it is now shipped from Constantinople. From the interior, it is transported in flattened round tin bottles called kunkumas, holding from 1 to 10 lb., which are sewed up in white woollen cloth. These sometimes reach this country, but more commonly the attar is transferred at Constantinople to small white glass bottles, ornamented with gilding, imported from Germany.
Uses—Attar of rose is of no medicinal importance, but serves occasionally as a scent for ointments. Rose water is sometimes made with it, but is not so good as that distilled from the flowers. Attar is much used in perfumery, but still more in the scenting of snuff.
Adulteration—No drug is more subject than attar of rose to adulteration, which is principally effected by the addition of the volatile oil of an Indian grass, Andropogon Schœnanthus L. This oil, which is called in Turkish Idris yàghi, and also Entershah, and is more or less known to Europeans as Geranium Oil, is imported into Turkey for this express purpose, and even submitted to a sort of purification before being used.[1029] It was formerly added to the attar only in Constantinople, but now the mixing takes place at the seat of the manufacture. It is said that in many places the roses are absolutely sprinkled with it before being placed in the still. As grass oil does not solidify by cold, its admixture with rose oil renders the latter less disposed to crystallize. Hence arises a preference among the dealers in Turkey for attar of the mountain districts, which, having a good proportion of stearoptene, will bear the larger dilution with grass oil without its tendency to crystallize becoming suspiciously small. Thus, in the circular of a commercial house in Constantinople, dated from Kizanlik, occur the phrases—“Extra strong oil,”—“Good strong congealing oil,”—“Strong good freezing oil;”—while the 3rd quality of attar is spoken of as a “not congealing oil.” The same circular states the belief of the writers, that in the season in which they wrote, “not a single metical of unadulterated oil” would be sent away.
The chief criteria, according to Baur, for the purity of rose oil are:—1. Temperature at which crystallization takes place: a good oil should congeal well in five minutes at a temperature of 12·5° C. 2. Manner of crystallizing.—The crystals should be light, feathery, shining plates, filling the whole liquid. Spermaceti, which has been sometimes used to replace the stearoptene, is liable to settle down in a solid cake, and is easily recognizable. Furthermore, it melts at 50° C. and so do most varieties of paraffin. The microscopic crystals of the latter are somewhat similar to those of rose stearoptene, yet they may be distinguished by an attentive comparative examination.
Cynosbata; Fruit of the Dog-rose, Hips; F. Fruits de Cynorrhodon; G. Hagebutten.
Botanical Origin—Rosa canina L., a bush often 10 to 12 feet high, found in hedges and thickets throughout Europe except Lapland and Finland, and reaching the Canary Islands, Northern Africa, Persia and Siberia; universally dispersed throughout the British Islands.[1030]
History—The fruits of the wild rose, including other species besides R. canina L., have a scanty, orange, acid, edible pulp, on account of which they were collected in ancient times when garden fruits were few and scarce. Galen[1031] mentions them as gathered by country people in his day, as they still are in Europe. Gerarde in the 16th century remarks that the fruit when ripe—“maketh most pleasant meats and banqueting dishes, as tarts and such like.“ Though the pulp of hips preserved with sugar which is here alluded to, is no longer brought to table, at least in this country,[1032] it retains a place in pharmacy as a useful ingredient of pill-masses and electuaries.
Description—The fruit of a rose consists of the bottle-shaped calyx, become dilated and succulent by growth, and sometimes crowned with 5 leafy segments, enclosing numerous dry carpels or achenes, containing each one exalbuminous seed. The fruit of R. canina called a hip, is ovoid, about ¾ of an inch long, with a smooth, red, shining surface. It is of a dense, fleshy texture, becoming on maturity, especially after frost, soft and pulpy, the pulp within the shining skin being of an orange colour, and of an agreeable sweetish subacid taste. The large interior cavity contains numerous hard achenes, which, as well as the walls of the former, are covered with strong short hairs.
For medicinal use, the only part required is the soft orange pulp, which is separated by rubbing it through a hair sieve.
Microscopic Structure—The epidermis of the fruit is made up of tabular cells containing red granules, which are much more abundant in the pulp. The latter, as usual in many ripe fruits, consists of isolated cells no longer forming a coherent tissue. Besides these cells, there occur small fibro-vascular bundles. Some of the cells enclose tufted crystals of oxalate of calcium; most of them however are loaded with red granules, either globular or somewhat elongated. They assume a bluish hue on addition of perchloride of iron, and are turned blackish by iodine. The later colouration reminds one of that assumed by starch granules under similar circumstances; yet on addition of a very dilute solution of iodine, the granules always exhibit a blackish, not a blue tint, so that they are not to be considered as starch granules. The hairs of the pulp are formed of a single, thick-walled cell, straight or sometimes a little crooked.
Chemical Composition—The pulp examined by Biltz (1824) was found to afford nearly 3 per cent. of citric acid, 7·7 of malic acid, besides citrates, malates and mineral salts, 25 per cent. of gum, and 30 of uncrystallizable sugar.
Uses—Hips are employed solely on account of their pulp, which mixed with twice its weight of sugar, constitutes the Confectio Rosæ caninæ of pharmacy.
Quince Seeds, Quince Pips; F. Semences ou Pepins de Coings; G. Quittensamen.
Botanical Origin—Pirus Cydonia L. (Cydonia vulgaris Pers.), the quince tree, is supposed to be a true native of Western Asia, from the Caucasian provinces of Russia to the Hindu Kush range in Northern India. But it is now apparently wild also in many of the countries which surround the Mediterranean basin.
In a cultivated state, it flourishes throughout temperate Europe, but is far more productive in southern than in northern regions. Quinces ripen in the south of England, but not in Scotland, nor in St. Petersburg, or in Christiana.
History—The quince was held in high esteem by the ancients, who considered it an emblem of happiness and fertility; and, as such, it was dedicated to Venus, whose temples it was used to decorate. Some antiquarians maintain that quinces were the Golden Apples of the Hesperides. The name Cydonia alludes to the town of Kydon, now Canea, in Creta; in the Talmud quinces are called Cretan apples.
Porcius Cato in his graphic description of the management of a Roman farmhouse, alludes to the storing of quinces both cultivated and wild; and there is much other evidence to prove that from an early period the quince was abundantly grown throughout Italy. Charlemagne, a.d. 812, enjoined its cultivation in central Europe.[1033] At what period it was introduced into Britain is not evident, but we have observed that Baked Quinces are mentioned among the viands served at the famous installation feast of Nevill, archbishop of York in 1466.[1034]
The use of mucilage of quince seeds has come to us through the Arabians; it is still met with in Turkestan.
Description—The quince is a handsome fruit of a golden yellow, in shape and size resembling a pear. It has a very agreeable and powerful smell, but an austere, astringent taste, so that it is not eatable in the raw state. In structure, it differs from an apple or a pear in having many seeds in each cell, instead of only two.
The fruit is, like an apple, 5-celled, with each cell containing a double row of closely-packed seeds, 8 to 14 in number, cohering by a soft mucilaginous membrane with which each is surrounded. By drying, they become hard, but remain agglutinated as in the cell. The seeds have an ovoid or obconic form, rather flattened and 3-sided by mutual pressure. From the hilum at the lower pointed end, the raphe passes as a straight ridge to the opposite extremity, which is slightly beaked and marked with a scar indicating the chalaza. The edge opposite the raphe is more or less arched according to the position of the individual seed in the cell. The testa encloses two thick, veined cotyledons, having a straight radicle directed towards the hilum.
Quince seeds have a mahogany-brown colour, and when unbroken a simply mucilaginous taste. But the kernels have the odour and taste of bitter almonds, and evolve hydrocyanic acid when comminuted and mixed with water.
Microscopic Structure—The epidermis of the seed consists of one row of cylindrical cells, the walls of which swell up in the presence of water and are dissolved, so as to yield an abundance of mucilage. This process can easily be observed, if thin sections of the seed are examined under glycerine, which acts on them but slowly.
Chemical Composition—The mucilage of the epidermis is present in such quantity, that the seed easily coagulates forty times its weight of water. By complete exhaustion, the seeds afford about 20 per cent. of dry mucilage, containing considerable quantities of calcium salts and albuminous matter, of which it is not easily deprived. When treated with nitric acid, it yields oxalic acid. After a short treatment with strong sulphuric acid it is coloured blue by iodine. Tollens and Kirchner (1874) assign to it the formula C₁₈H₂₈O₁₄, regarding it as a compound of gum, C₁₂H₂₀O₁₀, and cellulose, C₆H₁₀O₅, less one molecule of water.
Quince mucilage has but little adhesive power, and is not thickened by borax. That portion of it which is really in a state of solution and which may be separated by filtration, is precipitable by metallic salts or by alcohol. The latter precipitate after it has been dried is no longer dissolved by water either cold or warm. Quince mucilage is, on the whole, to be regarded as a soluble modification of cellulose.
The seeds on distillation with water afford a little hydrocyanic acid, and, probably, bitter almond oil.
Commerce—Quince seeds reach England from Hamburg; and are frequently quoted in Hamburg price-currents as Russian; they are also brought from the south of France and from the Cape of Good Hope. They are largely imported into India from the Persian Gulf, and by land from Afghanistan.
Uses—A decoction of quince seeds is occasionally used as a demulcent external application in skin complaints. It is also sometimes added to eye-lotions. Quince seeds are in general use among the natives of India as a demulcent tonic and restorative. They have been found useful by Europeans in dysentery.